Fate of polycyclic aromatic hydrocarbons in the Pacific sector of the Arctic Ocean based on a level III fugacity environmental multimedia model

2021 ◽  
Vol 166 ◽  
pp. 112195
Author(s):  
Guangshui Na ◽  
Jiandong Ye ◽  
Ruijing Li ◽  
Hui Gao ◽  
Shuaichen Jin ◽  
...  
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Arctic Ocean ◽  
Aromatic Hydrocarbons ◽  
The Arctic ◽  
Multimedia Model ◽  
The Pacific ◽  
The Arctic Ocean ◽  
Polycyclic Aromatic

scholarly journals Polycyclic aromatic hydrocarbons in ocean sediments from the North Pacific to the Arctic Ocean

2017 ◽  
Vol 227 ◽  
pp. 498-504 ◽  
Author(s):  
Yuxin Ma ◽  
Crispin J. Halsall ◽  
Zhiyong Xie ◽  
Danijela Koetke ◽  
Wenying Mi ◽  
...  
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Arctic Ocean ◽  
Aromatic Hydrocarbons ◽  
North Pacific ◽  
The Arctic ◽  
The North ◽  
The Arctic Ocean ◽  
Polycyclic Aromatic ◽  
The North Pacific

scholarly journals Chemical Composition of Aerosol over the Arctic Ocean from Summer ARctic EXpedition (AREX) 2011–2012 Cruises: Ions, Amines, Elemental Carbon, Organic Matter, Polycyclic Aromatic Hydrocarbons, n-Alkanes, Metals, and Rare Earth Elements

Atmosphere ◽  
2019 ◽  
Vol 10 (2) ◽  
pp. 54 ◽  
Author(s):  
Luca Ferrero ◽  
Giorgia Sangiorgi ◽  
Maria Perrone ◽  
Cristiana Rizzi ◽  
Marco Cataldi ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Organic Matter ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Rare Earth ◽  
Chemical Composition ◽  
Aromatic Hydrocarbons ◽  
Elemental Carbon ◽  
The Arctic ◽  
The Arctic Ocean ◽  
Polycyclic Aromatic

During the summers of 2011 and 2012, two scientific cruises were carried out over the Arctic Ocean aiming at the determination of the aerosol chemical composition in this pristine environment. First, mass spectrometry was applied to study the concentration and gas/particle partitioning of polycyclic aromatic hydrocarbons (PAHs) and n-alkanes. Experimental and modelled data of phase partitioning were compared: results demonstrated an equilibrium between gas and particle phase for PAHs, while n-alkanes showed a particle-oriented partitioning, due to the local marine origin of them, confirmed by the extremely low value of their carbon preference index. Moreover, the inorganic and organic ions (carboxylic acids and amines) concentrations, together with those of elemental carbon (EC) and organic matter (OM), were analyzed: 63% of aerosol was composed of ionic compounds (>90% from sea-salt) and the OM content was very high (30.5%; close to 29.0% of Cl−) in agreement with n-alkanes’ marine signature. Furthermore, the amines’ (dimethylamine, trimethylamine, diethylamine) concentrations were 3.98 ± 1.21, 1.70 ± 0.82, and 1.06 ± 0.56 p.p.t.v., respectively, fully in keeping with concentration values used in the CLOUD (Cosmics Leaving OUtdoor Droplet)-chamber experiments to simulate the ambient nucleation rate in a H2SO4-DMA-H2O system, showing the amines’ importance in polar regions to promote new particle formation. Finally, high resolution mass spectrometry was applied to determine trace elements, including Rare Earth Elements (REEs), highlighting the dominant natural versus anthropic inputs for trace metals (e.g., Fe, Mn, Ti vs. As, Cd, Ni) and possible signatures of such anthropic activity.

scholarly journals Distribution, fluxes and balance of particulate organic carbon in the Arctic ocean

2019 ◽  
Vol 59 (4) ◽  
pp. 544-552
Author(s):  
A. A. Vetrov ◽  
E. A. Romankevich
Keyword(s):  
Organic Carbon ◽  
Arctic Ocean ◽  
Particulate Organic Carbon ◽  
The Arctic ◽  
Climate Data ◽  
Arctic Seas ◽  
The Pacific ◽  
The Arctic Ocean ◽  
Main Component ◽  
Depth Horizon

Particulate organic carbon (POC) is one of main component of carbon cycle in the Ocean. In this study an attempt to construct a picture of the distribution and fluxes of POC in the Arctic Ocean adjusting for interchange with the Pacific and Atlantic Oceans has been made. The specificity of this construction is associated with an irregular distribution of POC measurements and complicated structure and hydrodynamics of the waters masses. To overcome these difficulties, Multiple Linear Regression technic (MLR) was performed to test the significant relation between POC, temperature, salinity, as well depth, horizon, latitude and offshore distance. The mapping of POC distribution and its fluxes was carrying out at 38 horizons from 5 to 4150 m (resolution 1°×1°). Data on temperature, salinity, meridional and zonal components of current velocities were obtained from ORA S4 database (Integrated Climate Data Center, http://icdc.cen.uni-hamburg.de/las). The import-export of POC between the Arctic, Atlantic and Pacific Oceans as well as between Arctic Seas was precomputed by summer fluxes. The import of POC in the Arctic Ocean is estimated to be 38±8Tg Cyr-1, and the export is -9.5±4.4Tg Cyr-1.

scholarly journals Modelling the effect of boundary scavenging on Thorium and Protactinium profiles in the ocean

2009 ◽  
Vol 6 (4) ◽  
pp. 7853-7896 ◽  
Author(s):  
M. Roy-Barman
Keyword(s):  
Arctic Ocean ◽  
Water Column ◽  
Open Ocean ◽  
The Arctic ◽  
Transport Parameters ◽  
Lateral Transport ◽  
Transport Reaction ◽  
The Pacific ◽  
The Arctic Ocean ◽  
Boundary Scavenging

Abstract. The "boundary scavenging" box model is a cornerstone of our understanding of the particle-reactive radionuclide fluxes between the open ocean and the ocean margins. However, it does not describe the radionuclide profiles in the water column. Here, I present the transport-reaction equations for radionuclides transported vertically by reversible scavenging on settling particles and laterally by horizontal currents between the margin and the open ocean. Analytical solutions of these equations are compared with existing data. In the Pacific Ocean, the model produces "almost" linear 230Th profiles (as observed in the data) despite lateral transport. However, omitting lateral transport biased the 230Th based particle flux estimates by as much as 50%. 231Pa profiles are well reproduced in the whole water column of the Pacific Margin and from the surface down to 3000 m in the Pacific subtropical gyre. Enhanced bottom scavenging or inflow of 231Pa-poor equatorial water may account for the model-data discrepancy below 3000 m. The lithogenic 232Th is modelled using the same transport parameters as 230Th but a different source function. The main source of 232Th scavenged in the open Pacific is advection from the ocean margin, whereas a net flux of 230Th produced in the open Pacific is advected and scavenged at the margin, illustrating boundary exchange. In the Arctic Ocean, the model reproduces 230Th measured profiles that the uni-dimensional scavenging model or the scavenging-ventilation model failed to explain. Moreover, if lateral transport is ignored, the 230Th based particle settling speed may by underestimated by a factor 4 at the Arctic Ocean margin. The very low scavenging rate in the open Arctic Ocean combined with the enhanced scavenging at the margin accounts for the lack of high 231Pa/230Th ratio in arctic sediments.

scholarly journals Sources and environmental fate of pyrogenic polycyclic aromatic hydrocarbons (PAHs) in the Arctic

2019 ◽  
Vol 5 ◽  
pp. 128-142 ◽  
Author(s):  
Jennifer E. Balmer ◽  
Hayley Hung ◽  
Yong Yu ◽  
Robert J. Letcher ◽  
Derek C.G. Muir
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Environmental Fate ◽  
The Arctic ◽  
Polycyclic Aromatic

scholarly journals The Mass Balance of the Sea Ice of the Arctic Ocean

1973 ◽  
Vol 12 (65) ◽  
pp. 173-185 ◽  
Author(s):  
R. M. Koerner
Keyword(s):  
Arctic Ocean ◽  
Ablation Rate ◽  
The Arctic ◽  
First Year ◽  
The North ◽  
Ice Accumulation ◽  
The Pacific ◽  
The Arctic Ocean ◽  
Ridged Ice ◽  
Ice Production

AbstractFrom data taken on the British Trans-Arctic Expedition it is calculated that 9% of the Arctic Ocean surface between the North Pole and Spitsbergen was hummocked or ridged ice, 17% was unridged ice less than a year old, 73% was unridged old ice and 0.6% was ice-free. The mode of 250 thickness measurements taken through level areas of old floes along the entire traverse lies between 2.25 and 2.75 m. The mean end-of-winter thickness of the ice is calculated to be 4.6 m in the Pacific Gyral and 3.9 m in the Trans-Polar Drift Stream. From measurements of the percentage coverage and thickness of the various ice forms, it is calculated that the total annual ice accumulation in the Arctic Ocean is equivalent to a continuous layer of ice 1.1 m thick. 47% of this accumulation occurs in ice-free areas and under ice less than 1 year old. 20% of the total ice production is either directly or indirectly related to ridging or hummocking. An ice-ablation rate of 500 kg m−2 measured on a level area of a multi-year floe is compared with the rate on deformed and ponded ice. Greatest melting occurs on new hummocks and least on old smooth hummocks. The annual balance of ice older than 1 year but younger than multi-year ice is calculated from a knowledge of ice-drift patterns and the percentage coverage of first-year ice. The same calculations give a mean-maximum drift period of 5 years for ice in the Trans-Polar Drift Stream and 16 years in the Pacific Gyral. It is calculated that for the period February 1968 to May 1969 the annual ice export was 5 580 km3.

The Frozen Ocean

PMLA ◽  
2010 ◽  
Vol 125 (3) ◽  
pp. 693-702 ◽  
Author(s):  
Adriana Craciun
Keyword(s):  
Eighteenth Century ◽  
Arctic Ocean ◽  
Native People ◽  
The Arctic ◽  
The Pacific ◽  
The Arctic Ocean

We'll get crushed by the ocean but it will not get us wet.—Isaac Brock, “Invisible” (2007)“There is no Sea With Which Our Age is So Imperfectly Acquainted as the Frozen Ocean,” Wrote the Eighteenth-Century Russian hydrographer Gavriil Sarychev, “and no empire which has more powerful motives and resources for extending its information, in this quarter, than Russia” (iii). Russia's Great Northern Expedition of the 1730s and later expeditions, like Sarychev's in 1785, mapped the shores of the Arctic Ocean across continental Asia, an impressive feat by any century's standards. Meanwhile, the American shores of the Arctic Ocean remained entirely unknown to the European empires (England, France, Spain) most interested in passing to and from the Pacific and Atlantic oceans via the Northwest and Northeast passages. Alexander MacKenzie, Samuel Hearne, and John Franklin, each traveling with native people, walked thousands of miles to reach the Frozen Ocean, leaving in their wake the occasional human disaster and an unimpeachable record of publishing successes, like MacKenzie's Voyages from Montreal to the Frozen Ocean (1801) and Franklin's Narrative of a Journey to the Shores of the Polar Sea (1824).

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