Crystallographic features of the Al3Nb, Nb2Al and Nb(Ni1−XAlX)2 phases in a directionally solidified ternary eutectic microstructure

2019 ◽  
Vol 147 ◽  
pp. 303-310 ◽  
Author(s):  
Eder S.N. Lopes ◽  
Mariana R. Dal Bó ◽  
Victor C. Opini ◽  
Mariana G. de Mello ◽  
Carlos T. Rios ◽  
...  
Author(s):  
Maressa Gandolfi ◽  
Marcella Gautê Xavier ◽  
Leonardo Fernandes Gomes ◽  
Rodrigo Valenzuela Reyes ◽  
Amauri Garcia ◽  
...  

This work explored and contrasted the effect of microstructure on the tensile properties of AlSi10Mg alloys generated by transient directional solidification depending on variations in cooling rate and Magnesium (Mg) content (i.e., 0.45 and 1wt.% Mg), with a focus on understanding the dendritic growth and phases constitution. Optical and Scanning electron (SEM) microscopies, CALPHAD and thermal analysis were used to describe the microstructure, forming phases and resulting tensile properties. The findings showed that the experimental evolution of the primary dendritic spacing is very similar when both directionally solidified (DS) Al-10wt.% Si-0.45wt.% Mg and Al-10wt.% Si-1wt.% Mg alloys samples are compared. The secondary dendritic spacing was lower for the alloy with more Mg, especially considering the range of high growth velocities. Moreover, a greater fraction of (Al+Si+Mg2Si) ternary eutectic islands surrounding the -Al dendritic matrix was noted for the alloy with 1wt.% Mg. As a result of primary dendritic spacings greater than 180 m related to lower cooling rates, slightly higher tensile properties were attained for the Al-10wt.% Si-0.45wt.% Mg alloy. In contrast, combining dendritic refining (< 150 m) and larger Mg2Si fraction, fast solidified DS Al-10wt.% Si-1wt.% Mg samples exhibited higher tensile strength and elongation. The control of cooling rate and fineness of the dendritic array provided a new insight related to the addition of Mg in slightly higher levels than conventional ones, capable of achieving a better balance of tensile properties in AlSi10Mg alloys.


Author(s):  
Iurii Bogomol ◽  
Petro Loboda

The processing techniques, microstructures, and mechanical properties of directionally solidified eutectic ceramics are reviewed. It is considered the main methods for preparing of eutectic ceramics and the relationships between thermal gradient, growth rate, and microstructure parameters. Some principles of coupled eutectic growth, main types of eutectic microstructure and the relationship between the eutectic microstructure and the mechanical properties of directionally solidified eutectics at ambient and high temperatures are briefly described. The mechanical behavior and main toughening mechanisms of these materials in a wide temperature range are discussed. It is shown that the strength at high temperatures mainly depends on the plasticity of the phase components. By analyzing the dislocation structure, the occurrence of strain hardening in single crystalline phases during high-temperature deformation is revealed. The creep resistance of eutectic composites is superior to that of the sintered samples due to the absence of glassy phases at the interfaces, and the strain has to be accommodated by plastic deformation within the domains rather than by interfacial sliding. The microstructural and chemical stability of the directionally solidified eutectic ceramics at high temperatures are discussed. The aligned eutectic microstructures show limited phase coarsening up to the eutectic point and excellent chemical resistance. Directionally solidified eutectics, especially oxides, revealed an excellent oxidation resistance at elevated temperatures. It is shown sufficient potential of these materials for high-temperature applications.


2008 ◽  
Vol 16 (1) ◽  
pp. 88-95 ◽  
Author(s):  
Kyosuke Kishida ◽  
Yuji Yamaguchi ◽  
Katsushi Tanaka ◽  
Haruyuki Inui ◽  
Sho Tokui ◽  
...  

2015 ◽  
Vol 1760 ◽  
Author(s):  
Hirotaka Matsunoshita ◽  
Kosuke Fujiwara ◽  
Yuta Sasai ◽  
Yuichiro Kondo ◽  
Kyosuke Kishida ◽  
...  

ABSTRACTMicrostructures and mechanical properties of directionally solidified (DS) MoSi2 / Mo5Si3 / Mo5Si3C ternary eutectic composites were investigated. Ternary eutectic microstructure of a script-lamellar type that is characterized by rod-shaped Mo5Si3 and Mo5Si3C phases extending along the growth direction in the MoSi2 single crystalline matrix was developed simply by directional solidification at a growth rate of 10 mm/h. Compression tests along $[{\rm{1}}\mathop 1\limits^- 0]_{MoSi_2 }$ nearly parallel to the growth direction revealed that the DS ternary eutectic composites were plastically deformed above 1000 °C. Yield stresses of the DS ternary eutectic composites were much higher than those of binary composites mainly because of a smaller average thickness of MoSi2 matrix.


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