Hydrophobic, ultra-low refractive index films prepared by sol-gel process

2016 ◽  
Vol 184 ◽  
pp. 305-307 ◽  
Author(s):  
Ye Yuan ◽  
Genghua Yan ◽  
Shaozhe Liu ◽  
Xiaodi Lu ◽  
Ruijiang Hong
e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Won Jung Kim ◽  
Tae Young Kim ◽  
Chin Su Park ◽  
Jong Eun Kim ◽  
Tae Hee Lee ◽  
...  

AbstractIn this study, we designed a two-layer hybrid Anti-Reflection/Anti-Static (AR/AS) thin film. Two kinds of UV-curable fluorinated compounds were synthesized as low refractive index materials, and a TiO2 sol combined with a conducting polymer, poly(3,4-ethylenedioxythiophene) was made by the sol-gel process for use as a high refractive index material as well as a conducting layer. In order to determine the most optimized AR/AS system, the spectral properties were simulated with the refractive index of each layer. According to the simulated results, a high refractive index layer was deposited on the hard coated poly(ethylene terephthalate) (PET) substrate by the spin coating technique, and a low refractive index layer was spin coated on the low refractive index layer. The reflectance and transmittance were measured by UV-VIS-NIR spectroscopy. It was found that the measured reflectance and the maximum transmittance of the AR/AS film were 0.71 %R at a wavelength of 550 nm and 93 %T in the wavelength range between 400 and 700 nm, respectively. The surface resistance of the AR/AS film was 108.6 ohms.


2000 ◽  
Vol 660 ◽  
Author(s):  
H. Yokogawa ◽  
K. Kawano ◽  
M. Yokoyama ◽  
T. Tsutsui ◽  
M. Yahiro ◽  
...  

ABSTRACTSilica aerogels prepared by sol-gel methods with supercritical drying process have transparency and extremely low refractive index which is not available in any other materials. This extraordinary refractivity is expected to present some new features as an optical material. Ordinarily, coupling-out efficiency of surface-emissive light sources has been assumed to be low. It is due to the losses organized from internal reflection of emitted light at the air-glass interface and dissipation during wave-guiding propagation within the substrate.However, when material that has extremely low refractive index is inserted between a thin luminescence layer and glass substrate, almost all the light from the luminescence layer can efficiently couple out to air passing through the glass substrate. In this report, we introduce a silica aerogel film as a low refractive index material for surface-emissive devices, such as photoluminescent and electroluminescent device. In the experiments, the photoluminescence intensity of Alq3 through the silica aerogel layer was twice as large as that of the glass substrate without the silica aerogel film. Moreover, we formed a new substrate which contained a transparent electrode on the silica aerogel film. Using this substrate, we fabricated the OLED and observed the disappearance of wave-guiding propagation within the glass substrate.


1997 ◽  
Vol 474 ◽  
Author(s):  
Junmo Koo ◽  
Changho Lee ◽  
Kwangsoo No ◽  
Byeong-Soo Bae

ABSTRACTLead lanthanum titanate thin films have been prepared on MgO and sapphire substrates by sol-gel method. XRD analyses confirm that the PLT films fabricated on MgO(lOO) and c-plane sapphire substrates grow preferentially with (100) and (111) orientations, respectively. The PLT films with a high La content have a low refractive index due to the decrease of the refractive index anisotropy. The propagation losses in PLT films measured, using He-Ne laser light and the prism coupling method decrease as the La content increases. This is due to the reduction of the refractive index anisotropy and the surface scattering by the surface roughness as a function of La content in the film.


2012 ◽  
Vol 271-272 ◽  
pp. 247-250
Author(s):  
Rui Min Jin ◽  
Zhi Duan Cai ◽  
Li Min Cang ◽  
Tao Yan

Based on TEOS system and sol-gel process, together with catalysts, Antireflective coating films prepared by sol—gel on glass substrate have been processed by rapid thermal annealing (RTA). the refractive index and thinkness of SiO2 film is exactly controlled. The films are characterized by ellipsometer and SEM respectively. The quantum states in these processions are found and discussed.


RSC Advances ◽  
2014 ◽  
Vol 4 (27) ◽  
pp. 13909-13918 ◽  
Author(s):  
Xibing Zhan ◽  
Qingyu Xing ◽  
Huijuan Liu ◽  
Junying Zhang ◽  
Jue Cheng ◽  
...  

This paper presents a facile route to prepare a series of high refractive index and homogeneous hybrid resins with titanium in the backbone by a non-hydrolytic sol–gel process.


1992 ◽  
Vol 147-148 ◽  
pp. 606-613 ◽  
Author(s):  
Masayuki Yamane ◽  
Minoru Inami

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