Comparing the ion affinity of two ionophores: Theoretical study of alkali earth metal ion–nano tubular cyclic peptide complexes

2016 ◽  
Vol 214 ◽  
pp. 101-110 ◽  
Author(s):  
Alireza Najafi Chermahini ◽  
Zahra Jafari Chermahini
Materials ◽  
2021 ◽  
Vol 14 (18) ◽  
pp. 5270
Author(s):  
Sung Soo Park ◽  
Sang-Wook Chu ◽  
Liyi Shi ◽  
Shuai Yuan ◽  
Chang-Sik Ha

Crystalline walled SBA-15 with large pore size were prepared using alkali and alkali earth metal ions (Na+, Li+, K+ and Ca2+). For this work, the ratios of alkali metal ions (Si/metal ion) ranged from 2.1 to 80, while the temperatures tested ranged from 500 to 700 °C. The SBA-15 prepared with Si/Na+ ratios ranging from 2.1 to 40 at 700 °C exhibited both cristobalite and quartz SiO2 structures in pore walls. When the Na+ amount increased (i.e., Si/Na increased from 80 to 40), the pore size was increased remarkably but the surface area and pore volume of the metal ion-based SBA-15 were decreased. When the SBA-15 prepared with Li+, K+ and Ca2+ ions (Si/metal ion = 40) was thermally treated at 700 °C, the crystalline SiO2 of quartz structure with large pore diameter (i.e., 802.5 Å) was observed for Ca+2 ion-based SBA-15, while no crystalline SiO2 structures were observed in pore walls for both the K+ and Li+ ions treated SBA-15. The crystalline SiO2 structures may be formed by the rearrangement of silica matrix when alkali or alkali earth metal ions are inserted into silica matrix at elevated temperature.


Chemosphere ◽  
2020 ◽  
Vol 250 ◽  
pp. 126211 ◽  
Author(s):  
Chunlan Ni ◽  
Jingtao Hou ◽  
Lei Li ◽  
Yuanzhi Li ◽  
Mingxia Wang ◽  
...  

2019 ◽  
Vol 123 (32) ◽  
pp. 19340-19346
Author(s):  
Shivam Kansara ◽  
Sanjeev K. Gupta ◽  
Yogesh Sonvane ◽  
Maja Varga Pajtler ◽  
Rajeev Ahuja

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