A detail study of the microstructure of methyl benzoate/methanol mixture proved by IR spectra, excess infrared wavenumber, and physicochemical properties

2020 ◽  
Vol 302 ◽  
pp. 112521 ◽  
Author(s):  
Xiao Feng ◽  
Tingting Chen ◽  
Yuqiao Yin ◽  
Yingjie Xu
2009 ◽  
Vol 08 (01n02) ◽  
pp. 191-195 ◽  
Author(s):  
VIMAL KUMAR SHARMA ◽  
ISHA MUTREJA ◽  
SUSMITA MITRA

The gill mucosa is a convenient route for the administration of DNA vaccine to fish and other aquatic organisms. Nanocarriers have been considered for delivery; however, a suitable formulation is required. To devise an appropriate carrier, we have synthesized chitosan nanoparticles entrapping pDNA at N/P ratios of 1:1 and 2.5:1, using ionic gelation and microemulsion (μE) methods. For nanoparticle characterization, the size, morphology, zetapotential, and IR spectra were determined. The efficiency of pDNA entrapment was established by gel retardation assay. On the basis of the investigations, the loaded nanoparticles synthesized by μE method appear to have the required characteristics for effective delivery by this route.


2019 ◽  
Vol 818 ◽  
pp. 12-15
Author(s):  
Wancheng Sittikijyothin ◽  
Khanaphit Khumduang ◽  
Keonakhone Khounvilay ◽  
Rattanaphol Mongkholrattanasit

Cassia fistula gum was purified and modified by isopropanol precipitation and carboxymethylation process respectively. The physicochemical property of both purified and modified gums were evaluated and compared to their crude gum. The mannose to galactose (M/G) ratio of purified gum was altered by purification process. While, the carboxymethyl groups were formed via carboxymethylation for modified gum, indicated by IR spectra. As expected, the physicochemical properties of both purified and modified gums were better than crude gum.


2021 ◽  
Vol 13 (08) ◽  
pp. 40-47
Author(s):  
Teyyub Allahverdi oğlu İsmayılov ◽  
◽  
Sevinc Səlim qızı Süleymanova ◽  
Sevda Bəxtiyar qızı Əsədova ◽  
◽  
...  

Amides were synthesized in 1:1 and 1:2 molar ratios of amber and oxalic acid with monoethanolamine. IR-spectra of the obtained substances were drawn, the structures were determined and confirmed, physicochemical properties were studied. 10% aqueous solutions of these substances were prepared, physicochemical properties were determined and bactericidal properties were studied. Bactericidal efficacy of amber acid N-mono­ethanolamide was 82.9% at 25 mg/l of concentration, 88% at 50 mg/l and 95% at 100 mg/l of concentrations. Bactericidal efficacy of amber acid N1, N2 - bis-monoethanolamide was 69% at 25 mg/l of concentration, 83.2% at 50 mg/l and 90% at 100 mg/l of concentrations. The bactericidal effect of oxalic acid has also been studied N-mono­ethanolamide was 82% at 25 mg/l of concentration, 91% at 50 mg/l and 97% at 100 mg/l of concentrations. Bactericidal efficacy of amber acid N1, N2 - bis-monoethanolamide was 85% at 25 mg/l of concentration, 94% at 50 mg/l and 97.6 at 100 mg/l of concentrations. Key words: amber acid, oxalic acid, bactericidal efficacy, N-monoethanolamide, N1,N -bis-monoethanolamide


Author(s):  
A. Legrouri

The industrial importance of metal catalysts supported on reducible oxides has stimulated considerable interest during the last few years. This presentation reports on the study of the physicochemical properties of metallic rhodium supported on vanadium pentoxide (Rh/V2O5). Electron optical methods, in conjunction with other techniques, were used to characterise the catalyst before its use in the hydrogenolysis of butane; a reaction for which Rh metal is known to be among the most active catalysts.V2O5 powder was prepared by thermal decomposition of high purity ammonium metavanadate in air at 400 °C for 2 hours. Previous studies of the microstructure of this compound, by HREM, SEM and gas adsorption, showed it to be non— porous with a very low surface area of 6m2/g3. The metal loading of the catalyst used was lwt%Rh on V2Q5. It was prepared by wet impregnating the support with an aqueous solution of RhCI3.3H2O.


1966 ◽  
Vol 16 (03/04) ◽  
pp. 526-540 ◽  
Author(s):  
E. A Beck ◽  
D. P Jackson

SummaryThe effects of trypsin and plasmin on the functional and physicochemical properties of purified human fibrinogen were observed at various stages of proteolysis. Concentrations of plasmin and trypsin that produced fibrinogenolysis at comparable rates as measured in a pH stat produced, at similar rates, loss of precipitability of fibrinogen by heat and ammonium sulphate and alterations in electrophoretic mobility on starch gel. Trypsin produced a more rapid loss of clottability of fibrinogen and a more rapid appearance of inhibitors of the thrombin-fibrinogen clotting system than did plasmin. Consistent differences were noted between the effects of trypsin and plasmin on the immunoelectrophoretic properties of fibrinogen during the early stages of proteolysis.These results are consistent with the hypothesis that trypsin initially reacts with the same peptide bonds of fibrinogen that are split by thrombin, but these same bonds do not appear to be split initially by plasmin. Measurement of the various functional and physico-chemical changes produced by the action of trypsin and plasmin on fibrinogen can be used to recognize various stages of proteolysis.


2020 ◽  
pp. 181-191
Author(s):  
M. Tkachenko ◽  
N. Borys ◽  
Ye. Kovalenko

The research aims to establish the eff ectiveness of granular chalk use produced by «Slavuta-Calcium» Ltd. under growing Poliska–90 winter wheat variety, changing the physicochemical properties of grey forest soil and the wheat productivity. It also aims to establish optimal dosis of «Slavuta-Calcium» granular chalk as the meliorant and mineral fertilizer for grey forest soil in the system of winter wheat fertilization. In the temporary fi eld studies, various doses of nutrients N60–90–120P30–45–60K60–90–120 combined with «Slavuta–Calcium» granular chalk in a dose of Ca230–460–690 kg/ha of the active substance were studied against the background of secondary plowing of rotation products – soybean biomass that averaged 2.34 t/ha. Granular chalk is a modern complex highly eff ective meliorant with the content of Ca – 37.7 and Mg – 0.2 %, the mass fraction of carbonates (CaCO3 + MgCO3) makes at least 95 %. It is characterized by a high level of solubility when interacting with moisture in soil. It has a form of white granules, the mass fraction of 4.0–6.0 mm in size granules makes not less than 90 % and the one of 1.0 mm in size makes less than 5 %. Reactivity – 97 %. The granular chalk is advisable to apply on acidic soils, as a highly concentrated calcium-magnesium fertilizer, with the former as the dominant fertilizer, to optimize the physicochemical properties of the soil, as well as the plant nutrition system, in particular, increasing the availability of an element for assimilation by plants and as long-term ameliorants. The eff ectiveness of the use of mineral fertilizers, in particular acidic nitrogen on highly and medium acidic soils, after chemical reclamation is increased by 30–50 %, and slightly acidic by 15–20 %. The increase in productivity of crops from the combined eff ects of nutrients and chalk granulated is usually higher than when separately applied. The eff ectiveness of the integrated action of these elements is manifested in the growth of plant productivity and the quality of the resulting products, as well as the optimization of physical chemical properties and soil buff ering in the long term. In order to optimize the physicochemical properties of the arable layer of gray forest soil and the productive nutrition of agricultural crops, winter wheat, in particular, biogenic elements should be used in doses N60-90-120P30-45- 60K60-90-120 with granulated chalk «Slavuta-Calcium» in doses of Ca230-460-690 kg/ha of active substance. Granulated chalk obtained as a result of industrial grinding of solid sedimentary carbonate rocks of natural origin, subsequently under the infl uence of the granulation process of the starting material contains Ca and Mg carbonates of at least 95 %, dense granules which facilitates convenient mechanized application, as well as chalk suitable for accurate metered application on the quest map. Key words: granular chalk, gray forest soil, chemical reclamation, crop productivity.


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