scholarly journals Optical properties of an organic-inorganic hybrid film made of regenerated cellulose doped with light-scattering TiO2 particles

2022 ◽  
Vol 123 ◽  
pp. 111882
Author(s):  
Maija Vuoriluoto ◽  
Ari Hokkanen ◽  
Tapio Mäkelä ◽  
Ali Harlin ◽  
Hannes Orelma
Keyword(s):  
Optical Properties ◽  
Light Scattering ◽  
Hybrid Film ◽  
Regenerated Cellulose ◽  
Inorganic Hybrid ◽  
Tio2 Particles

scholarly journals Light-Scattering Simulations from Spherical Bimetallic Core–Shell Nanoparticles

Micromachines ◽  
2021 ◽  
Vol 12 (4) ◽  
pp. 359
Author(s):  
Francesco Ruffino
Keyword(s):  
Optical Properties ◽  
Light Scattering ◽  
Bimetallic Nanoparticles ◽  
Dominant Role ◽  
Scattered Light ◽  
Specific Interaction ◽  
Surface Enhanced Raman Spectroscopy ◽  
Localized Surface Plasmon ◽  
Core Shell ◽  
The Core

Bimetallic nanoparticles show novel electronic, optical, catalytic or photocatalytic properties different from those of monometallic nanoparticles and arising from the combination of the properties related to the presence of two individual metals but also from the synergy between the two metals. In this regard, bimetallic nanoparticles find applications in several technological areas ranging from energy production and storage to sensing. Often, these applications are based on optical properties of the bimetallic nanoparticles, for example, in plasmonic solar cells or in surface-enhanced Raman spectroscopy-based sensors. Hence, in these applications, the specific interaction between the bimetallic nanoparticles and the electromagnetic radiation plays the dominant role: properties as localized surface plasmon resonances and light-scattering efficiency are determined by the structure and shape of the bimetallic nanoparticles. In particular, for example, concerning core-shell bimetallic nanoparticles, the optical properties are strongly affected by the core/shell sizes ratio. On the basis of these considerations, in the present work, the Mie theory is used to analyze the light-scattering properties of bimetallic core–shell spherical nanoparticles (Au/Ag, AuPd, AuPt, CuAg, PdPt). By changing the core and shell sizes, calculations of the intensity of scattered light from these nanoparticles are reported in polar diagrams, and a comparison between the resulting scattering efficiencies is carried out so as to set a general framework useful to design light-scattering-based devices for desired applications.

An Ion-Induced Low-Oil-Adhesion Organic/Inorganic Hybrid Film for Stable Superoleophobicity in Seawater

2012 ◽  
Vol 25 (4) ◽  
pp. 606-611 ◽  
Author(s):  
Li-Ping Xu ◽  
Jing Zhao ◽  
Bin Su ◽  
Xueli Liu ◽  
Jitao Peng ◽  
...  
Keyword(s):  
Hybrid Film ◽  
Inorganic Hybrid

Optical properties of organic–inorganic hybrid thin films containing polysilane segments prepared from polysilane–methacrylate copolymers

2000 ◽  
Vol 611 (1-2) ◽  
pp. 40-44 ◽  
Author(s):  
Shinya Mimura ◽  
Hiroyoshi Naito ◽  
Yoshihiko Kanemitsu ◽  
Kimihiro Matsukawa ◽  
Hiroshi Inoue
Keyword(s):  
Thin Films ◽  
Optical Properties ◽  
Inorganic Hybrid ◽  
Methacrylate Copolymers ◽  
Hybrid Thin Films

Organic–inorganic hybrid lead halide perovskites for optoelectronic and electronic applications

2016 ◽  
Vol 45 (3) ◽  
pp. 655-689 ◽  
Author(s):  
Yixin Zhao ◽  
Kai Zhu
Keyword(s):  
Thin Film ◽  
Optical Properties ◽  
Recent Progress ◽  
Research Issues ◽  
Inorganic Hybrid ◽  
Halide Perovskites ◽  
Film Synthesis ◽  
Lead Halide

This article reviews recent progress on hybrid perovskites including crystal/thin-film synthesis, structural/chemical/electro-optical properties, (opto)electronic applications, and research issues/challenges.

First global assessment of modelled aerosol hygroscopicity in the context of other aerosol optical properties

2021 ◽  
Author(s):  
Maria Ángeles Burgos Simón ◽  
Elisabeth Andrews ◽  
Gloria Titos ◽  
Angela Benedetti ◽  
Huisheng Bian ◽  
...  
Keyword(s):  
Optical Properties ◽  
Light Scattering ◽  
Relative Humidity ◽  
Water Uptake ◽  
Chem Phys ◽  
Earth System ◽  
Aerosol Optical Properties ◽  
System Models ◽  
Earth System Models

<p>The particle hygroscopic growth impacts the optical properties of aerosols and, in turn, affects the aerosol-radiation interaction and calculation of the Earth’s radiative balance. The dependence of particle light scattering on relative humidity (RH) can be described by the scattering enhancement factor f(RH), defined as the ratio between the particle light scattering coefficient at a given RH divided by its dry value.</p><p>The first effort of the AeroCom Phase III – INSITU experiment was to develop an observational dataset of scattering enhancement values at 26 sites to study the uptake of water by atmospheric aerosols, and evaluate f(RH) globally (Burgos et al., 2019). Model outputs from 10 Earth System Models (CAM, CAM-ATRAS, CAM-Oslo, GEOS-Chem, GEOS-GOCART, MERRAero, TM5, OsloCTM3, IFS-AER, and ECMWF) were then evaluated against this in-situ dataset. Building on these results, we investigate f(RH) in the context of other aerosol optical and chemical properties, making use of the same 10 Earth System Models (ESMs) and in-situ measurements as in Burgos et al. (2020) and Titos et al. (2021).</p><p>Given the difficulties of deploying and maintaining instrumentation for long-term, accurate and comprehensive f(RH) observations, it is desirable to find an observational proxy for f(RH). This observation-based proxy would also need to be reproduced in modelling space. Our aim here is to evaluate how ESMs currently represent the relationship between f(RH), scattering Ångström exponent (SAE), and single scattering albedo (SSA). This work helps to identify current challenges in modelling water-uptake by aerosols and their impact on aerosol optical properties within Earth system models.</p><p>We start by analyzing the behavior of SSA with RH, finding the expected increase with RH for all site types and models. Then, we analyze the three variables together (f(RH)-SSA-SAE relationship). Results show that hygroscopic particles tend to be bigger and scatter more than non-hygroscopic small particles, though variability within models is noticeable. This relationship can be further studied by relating SAE to model chemistry, by selecting those grid points dominated by a single chemical component (mass mixing ratios > 90%). Finally, we analyze model performance at three specific sites representing different aerosol types: Arctic, marine and rural. At these sites, the model data can be exactly temporally and spatially collocated with the observations, which should help to identify the models which exhibit better agreement with measurements and for which aerosol type.</p><p> </p><p>Burgos, M.A. et al.: A global view on the effect of water uptake on aerosol particle light scattering. Sci Data 6, 157. https://doi.org/10.1038/s41597-019-0158-7, 2019.</p><p>Burgos, M.A. et al.: A global model–measurement evaluation of particle light scattering coefficients at elevated relative humidity, Atmos. Chem. Phys., 20, 10231–10258, https://doi.org/10.5194/acp-20-10231-2020, 2020.</p><p>Titos, G. et al.: A global study of hygroscopicity-driven light scattering enhancement in the context of other in-situ aerosol optical properties, Atmos. Chem. Phys. Discuss. [preprint], https://doi.org/10.5194/acp-2020-1250, in review, 2020.</p>

scholarly journals Coupling of the microphysical and optical properties of an Arctic nimbostratus cloud during the ASTAR 2004 experiment: Implications for light-scattering modeling

2010 ◽  
Vol 115 (D23) ◽  
Author(s):  
Olivier Jourdan ◽  
Guillaume Mioche ◽  
Timothy J. Garrett ◽  
Alfons Schwarzenböck ◽  
Jérôme Vidot ◽  
...  
Keyword(s):  
Optical Properties ◽  
Light Scattering

scholarly journals Aerosol light-scattering enhancement due to water uptake during the TCAP campaign

2014 ◽  
Vol 14 (13) ◽  
pp. 7031-7043 ◽  
Author(s):  
G. Titos ◽  
A. Jefferson ◽  
P. J. Sheridan ◽  
E. Andrews ◽  
H. Lyamani ◽  
...  
Keyword(s):  
Optical Properties ◽  
Light Scattering ◽  
Climate Models ◽  
Single Scattering ◽  
Mean Value ◽  
Department Of Energy ◽  
Cape Cod ◽  
Hygroscopic Growth ◽  
Aerosol Optical Properties ◽  
Aerosol Parameters

Abstract. Aerosol optical properties were measured by the DOE/ARM (US Department of Energy Atmospheric Radiation Measurements) Program Mobile Facility during the Two-Column Aerosol Project (TCAP) campaign deployed at Cape Cod, Massachusetts, for a 1-year period (from summer 2012 to summer 2013). Measured optical properties included aerosol light-absorption coefficient (σap) at low relative humidity (RH) and aerosol light-scattering coefficient (σsp) at low and at RH values varying from 30 to 85%, approximately. Calculated variables included the single scattering albedo (SSA), the scattering Ångström exponent (SAE) and the scattering enhancement factor (f(RH)). Over the period of measurement, f(RH = 80%) had a mean value of 1.9 ± 0.3 and 1.8 ± 0.4 in the PM10 and PM1 fractions, respectively. Higher f(RH = 80%) values were observed for wind directions from 0 to 180° (marine sector) together with high SSA and low SAE values. The wind sector from 225 to 315° was identified as an anthropogenically influenced sector, and it was characterized by smaller, darker and less hygroscopic aerosols. For the marine sector, f(RH = 80%) was 2.2 compared with a value of 1.8 obtained for the anthropogenically influenced sector. The air-mass backward trajectory analysis agreed well with the wind sector analysis. It shows low cluster to cluster variability except for air masses coming from the Atlantic Ocean that showed higher hygroscopicity. Knowledge of the effect of RH on aerosol optical properties is of great importance for climate forcing calculations and for comparison of in situ measurements with satellite and remote sensing retrievals. In this sense, predictive capability of f(RH) for use in climate models would be enhanced if other aerosol parameters could be used as proxies to estimate hygroscopic growth. Toward this goal, we propose an exponential equation that successfully estimates aerosol hygroscopicity as a function of SSA at Cape Cod. Further work is needed to determine if the equation obtained is valid in other environments.

scholarly journals Orientation dependence of optical activity in light scattering by nanoparticle clusters

2022 ◽  
Author(s):  
Atefeh Fazel Najafabadi ◽  
Baptiste Auguié
Keyword(s):  
Optical Properties ◽  
Light Scattering ◽  
Optical Activity ◽  
Incident Light ◽  
Spatial Arrangement ◽  
Orientation Dependence ◽  
Nanoparticle Clusters

The optical properties of nanoparticle clusters vary with the spatial arrangement of the constituent particles, but also the overall orientation of the cluster with respect to the incident light. This...

scholarly journals OPTICAL PROPERTIES OF LASER-COLOURING MARKED STAINLESS STEEL

2021 ◽  
Vol 3 ◽  
pp. 242-244
Author(s):  
Pavels Narica ◽  
Svetlana Pan’kova ◽  
Vladimir Solovyev ◽  
Alexander Vanin ◽  
Mikhail Yanikov
Keyword(s):  
Stainless Steel ◽  
Optical Properties ◽  
Light Scattering ◽  
Dielectric Permittivity ◽  
Laser Scanning ◽  
Incidence Angle ◽  
Sample Surface ◽  
Laser Scanning Microscopy ◽  
Optical Measurements ◽  
Complex Dielectric Permittivity

Laser colour-marking method often displace conventional marking techniques. Complicated technology of laser-induced periodic surface structure creation on stainless steel samples allows changing their surface morphology and optical properties, which were studied in this work by atomic force microscopy (AFM), laser scanning microscopy, reflectance spectroscopy and ellipsometry. Reflectance spectra of the samples demonstrate reflectance maxima correlate with the visible colours of the samples and with the extrema in the non-monotonic spectral dependences of the derivative of real part of complex dielectric permittivity extracted from the ellipsometric data. Thus, the most intensive light scattering takes place when the real part of complex dielectric permittivity falls down quickly with changing wavelength. We did not observe any “azimuth anisotropy” in our optical measurements at constant incidence angle: the spectra were the same independently of the light incidence plane orientation (parallel or perpendicular to the previous laser light spot scanning direction). We suppose that this selective resonance-like light scattering is due to the sample surface inhomogeneity, which is the result of previous laser treatment. This assumption agrees with estimations based on laser microscope and AFM images as well as with predictions of Mie theory. Thus, the colours of the samples under study are due to the light scattering by randomly distributed surface species with different sizes. 

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