Laboratory-accelerated ageing tests have been conducted to examine the depletion of antioxidants from high-density polyethylene (HDPE) geomembranes as a result of their exposure to various environments. Samples of 2.0 mm thick geomembrane were exposed to air, water, and municipal solid waste (MSW) leachate at temperatures of 22, 40, 55, 70, and 85°C. At various time intervals, samples were collected and the oxidative induction time (OIT) was evaluated. The results indicated that the antioxidants are depleted at rates 1.6 to 2.4 times faster for samples in water than for air-exposed samples. For samples in leachate, the depletion is about 4 times faster than that in air and 1.63.2 times faster than that in water. Using these rates, it is estimated that if the geomembrane examined were used as an MSW landfill primary liner, it would take at least 40 years to deplete the antioxidants from the geomembrane at a temperature of 33°C and over 150 years at a temperature of 13°C.Key words: ageing, antioxidants, durability, oxidative induction time, HDPE geomembrane, antioxidant depletion time.