Surface modification of inorganic nanoparticles for development of organic–inorganic nanocomposites—A review

2013 ◽  
Vol 38 (8) ◽  
pp. 1232-1261 ◽  
Author(s):  
Sarita Kango ◽  
Susheel Kalia ◽  
Annamaria Celli ◽  
James Njuguna ◽  
Youssef Habibi ◽  
...  
2011 ◽  
Vol 1312 ◽  
Author(s):  
Andrew J. Duncan ◽  
Andrew B. Schoch ◽  
Christopher S. Gold ◽  
Joseph L. Lenhart ◽  
Frederick L. Beyer

ABSTRACTRealization of property enhancements inherent to the presence of nanoparticles continues to be a challenge for the production of bulk nanocomposite materials with commercially available techniques. This study combines twin-screw compounding with surface modification of SiO2 nanoparticles to enable targeted dispersion in a SEBS block copolymer. Production of these composites with high levels of well-dispersed particulates aims to leverage aggregation for production of hierarchical structure. The aggregation state of the particles as well as the level of order in the block copolymer morphology was determined through USAXS and TEM. Particles coated with ligands miscible with the end-blocks of the BCP (minority component) increased dispersion at all loading levels observed up to 10 vol%. Ligands employed to increase miscibility of the nanoparticle with the mid-block (majority component) resulted in large aggregates for all loadings without disturbance of the BCP morphology.


Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7902
Author(s):  
Qinfu Zhao ◽  
Xinqian Liu ◽  
Stephen Veldhuis ◽  
Igor Zhitomirsky

Polyvinylidene fluoride (PVDF) is an advanced functional polymer which exhibits excellent chemical and thermal stability, and good mechanical, piezoelectric and ferroelectic properties. This work opens a new strategy for the fabrication of nanocomposites, combining the functional properties of PVDF and advanced inorganic nanomaterials. Electrophoretic deposition (EPD) has been developed for the fabrication of films containing PVDF and nanoparticles of TiO2, MnO2 and NiFe2O4. An important finding was the feasibility of EPD of electrically neutral PVDF and inorganic nanoparticles using caffeic acid (CA) and catechol violet (CV) as co-dispersants. The experiments revealed strong adsorption of CA and CV on PVDF and inorganic nanoparticles, which involved different mechanisms and facilitated particle dispersion, charging and deposition. The analysis of the deposition yield data, chemical structure of the dispersants and the microstructure and composition of the films provided an insight into the adsorption and dispersion mechanisms and the influence of deposition conditions on the deposition rate, film microstructure and composition. PVDF films provided the corrosion protection of stainless steel. Overcoming the limitations of other techniques, this investigation demonstrates a conceptually new approach for the fabrication of PVDF-NiFe2O4 films, which showed superparamagnetic properties. The approach developed in this investigation offers versatile strategies for the EPD of advanced organic-inorganic nanocomposites.


2018 ◽  
Vol 6 (4) ◽  
pp. 726-745 ◽  
Author(s):  
Mingxia Jiao ◽  
Peisen Zhang ◽  
Junli Meng ◽  
Yingying Li ◽  
Chunyan Liu ◽  
...  

This review summarizes the recent advancements in preparation, surface modification, functionalization, and in vivo imaging applications of biocompatible inorganic nanoparticles.


Author(s):  
R. A. Sperling ◽  
W. J. Parak

Inorganic colloidal nanoparticles are very small, nanoscale objects with inorganic cores that are dispersed in a solvent. Depending on the material they consist of, nanoparticles can possess a number of different properties such as high electron density and strong optical absorption (e.g. metal particles, in particular Au), photoluminescence in the form of fluorescence (semiconductor quantum dots, e.g. CdSe or CdTe) or phosphorescence (doped oxide materials, e.g. Y 2 O 3 ), or magnetic moment (e.g. iron oxide or cobalt nanoparticles). Prerequisite for every possible application is the proper surface functionalization of such nanoparticles, which determines their interaction with the environment. These interactions ultimately affect the colloidal stability of the particles, and may yield to a controlled assembly or to the delivery of nanoparticles to a target, e.g. by appropriate functional molecules on the particle surface. This work aims to review different strategies of surface modification and functionalization of inorganic colloidal nanoparticles with a special focus on the material systems gold and semiconductor nanoparticles, such as CdSe/ZnS. However, the discussed strategies are often of general nature and apply in the same way to nanoparticles of other materials.


Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2237
Author(s):  
Zhiang Fu ◽  
Xiaoying Gu ◽  
Lingmin Hu ◽  
Yongjin Li ◽  
Jingye Li

Polymer grafted inorganic nanoparticles attract significant attention, but pose challenges because of the complexity. In this work, a facile strategy to the graft polymer onto the surface of nanoparticles have been introduced. The vinyl functionalized SiO2 nanoparticles (NPs) were first prepared by the surface modification of the unmodified SiO2 using γ-methacryloxy propyl-trimethoxylsilane. The NPs were then mixed with polyvinylidene fluoride (PVDF), which was followed by the Co-60 Gamma radiation at room temperature. PVDF molecular chains were chemically grafted onto the surface of SiO2 nanoparticles by the linking of the double bond on the NPs. The graft ratio of PVDF on SiO2 NPs surface can be precisely controlled by adjusting the absorbed dose and reactant feed ratio (maximum graft ratio was 31.3 wt%). The strategy is simple and it should be applied to the surface modification of many other nanoparticles. The prepared PVDF-grafted SiO2 NPs were then dispersed in the PVDF matrix to make the nanocomposites. It was found that the modified NPs can be precisely dispersed into the PVDF matrix, as compared with pristine silica. The filling content of modifications SiO2 NPs on the PVDF nanocomposites is almost doubled than the pristine SiO2 counterpart. Accordingly, the mechanical property of the nanocomposites is significantly improved.


2021 ◽  
Vol 22 (10) ◽  
pp. 5287
Author(s):  
Khaled AbouAitah ◽  
Urszula Piotrowska ◽  
Jacek Wojnarowicz ◽  
Anna Swiderska-Sroda ◽  
Ahmed H. H. El-Desoky ◽  
...  

Hybrid nanostructures can be developed with inorganic nanoparticles (NPs) such as zinc oxide (ZnO) and natural antibacterials. ZnO NPs can also exert antibacterial effects, and we used them here to examine their dual action in combination with a natural antibacterial agent, protocatechuic acid (PCA). To produce hybrid nanoformulations, we functionalized ZnO NPs with four types of silane organic molecules and successfully linked them to PCA. Physicochemical assessment confirmed PCA content up to ~18% in hybrid nanoformulations, with a PCA entrapment efficiency of ~72%, indicating successful connection. We then investigated the in vitro release kinetics and antibacterial effects of the hybrid against Staphylococcus aureus. PCA release from hybrid nanoformulations varied with silane surface modification. Within 98 h, only 8% of the total encapsulated PCA was released, suggesting sustained long-term release. We used nanoformulation solutions collected at days 3, 5, and 7 by disc diffusion or log reduction to evaluate their antibacterial effect against S. aureus. The hybrid nanoformulation showed efficient antibacterial and bactericidal effects that also depended on the surface modification and at a lower minimum inhibition concentration compared with the separate components. A hybrid nanoformulation of the PCA prodrug and ZnO NPs offers effective sustained-release inhibition of S. aureus growth.


Sign in / Sign up

Export Citation Format

Share Document