Z-scheme induced g-C3N4 /WS2 heterojunction photocatalyst with improved electron mobility for enhanced solar photocatalysis

Solar Energy ◽  
2021 ◽  
Vol 228 ◽  
pp. 53-67
Author(s):  
Ahmad Nawaz ◽  
Shaghayegh Goudarzi ◽  
Pichiah Saravanan ◽  
Hadis Zarrin
Author(s):  
Veena Vijayan ◽  
Suguna Yesodharan ◽  
E. P. Yesodharan

Solar photocatalysis as a potential green technology for the removal of traces of the dye pollutant Indigo carmine (IC) from water is investigated using ZnO as the catalyst. Degradation/decolorization alone does not result in complete decontamination as seen from the significant Chemical Oxygen Demand (COD) of water even after the parent compound has disappeared completely. The degradation proceeds through many intermediates which also get mineralized eventually but slowly. Oxalic acid is identified as a stable slow mineralizing degradation product which itself is formed from other transient intermediates. Effect of various parameters such as catalyst dosage, concentration of the dye, pH, temperature, presence of contaminant salts etc. on the degradation is investigated and quantified. Oxidants such as S2O82- and H2O2 have only moderate influence on the degradation. The degradation follows variable kinetics depending on the concentration of the substrate. The reaction proceeds very slowly in the absence of O2 indicating the importance of reactive oxygen species and hydroxyl free radicals in photocatalysis. H2O2 formed insitu in the system undergoes concurrent decomposition resulting in stabilization in its concentration. The study demonstrates that solar photocatalysis can be used as a viable tool for the purification of water contaminated with traces of IC.


2011 ◽  
Vol 64 (12) ◽  
pp. 1587 ◽  
Author(s):  
Ahmad Irfan ◽  
Abdullah G. Al-Sehemi ◽  
Shabbir Muhammad ◽  
Jingping Zhang

Theoretically calculated mobility has revealed that BDT is a hole transfer material, which is in good agreement with experimental investigations. The BDT, NHBDT, and OBDT are predicted to be hole transfer materials in the C2/c space group. Comparatively, hole mobility of BHBDT is 7 times while electron mobility is 20 times higher than the BDT. The packing effect for BDT and designed crystals was investigated by various space groups. Generally, mobility increases in BDT and its analogues by changing the packing from space group C2/c to space groups P1 or . In the designed ambipolar material, BHBDT hole mobility has been predicted 0.774 and 3.460 cm2 Vs–1 in space groups P1 and , which is 10 times and 48 times higher than BDT (0.075 and 0.072 cm2 Vs–1 in space groups P1 and ), respectively. Moreover, the BDT behaves as an electron transfer material by changing the packing from the C2/c space group to P1 and .


Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4439
Author(s):  
Shui-Yang Lien ◽  
Yu-Hao Chen ◽  
Wen-Ray Chen ◽  
Chuan-Hsi Liu ◽  
Chien-Jung Huang

In this study, adding CsPbI3 quantum dots to organic perovskite methylamine lead triiodide (CH3NH3PbI3) to form a doped perovskite film filmed by different temperatures was found to effectively reduce the formation of unsaturated metal Pb. Doping a small amount of CsPbI3 quantum dots could enhance thermal stability and improve surface defects. The electron mobility of the doped film was 2.5 times higher than the pristine film. This was a major breakthrough for inorganic quantum dot doped organic perovskite thin films.


2021 ◽  
Vol 129 (10) ◽  
pp. 105701
Author(s):  
I. Stenger ◽  
M.-A. Pinault-Thaury ◽  
N. Temahuki ◽  
R. Gillet ◽  
S. Temgoua ◽  
...  

2021 ◽  
pp. 108050
Author(s):  
Maria Glória Caño de Andrade ◽  
Luis Felipe de Oliveira Bergamim ◽  
Braz Baptista Júnior ◽  
Carlos Roberto Nogueira ◽  
Fábio Alex da Silva ◽  
...  

2021 ◽  
Vol 33 (10) ◽  
pp. 2170075
Author(s):  
Ze‐Fan Yao ◽  
Yu‐Qing Zheng ◽  
Jin‐Hu Dou ◽  
Yang Lu ◽  
Yi‐Fan Ding ◽  
...  

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