Solubility and Diffusivity of CO2 and N2 in Polymers and Polymer Swelling, Glass Transition, Melting, and Crystallization at High Pressure. A Critical Review and Perspectives on Experimental Methods, Data, and Modeling

Author(s):  
Erdogan Kiran ◽  
Joseph A. Sarver ◽  
John C. Hassler
2017 ◽  
Vol 2017 ◽  
pp. 1-15
Author(s):  
Salah Al-Enezi

This paper examines the effect of high-pressure carbon dioxide on the foaming process in polystyrene near the glass transition temperature and the foaming was studied using cylindrical high-pressure view cell with two optical windows. This technique has potential applications in the shape foaming of polymers at lower temperatures, dye impregnation, and the foaming of polystyrene. Three sets of experiments were carried out at operating temperatures of 50, 70, and 100°C, each over a range of pressures from 24 to 120 bar. Foaming was not observed when the polymer was initially at conditions below Tg but was observed above Tg. The nucleation appeared to occur randomly leading to subsequent bubble growth from these sites, with maximum radius of 0.02–0.83 mm. Three models were applied on the foaming experimental data. Variable diffusivity and viscosity model (Model C) was applied to assess the experimental data with the WLF equation. The model shows very good agreement by using realistic parameter values. The expansion occurs by diffusion of a dissolved gas from the supersaturated polymer envelope into the bubble.


2007 ◽  
Vol 25 (1) ◽  
pp. 53 ◽  
Author(s):  
David R. Rohindra ◽  
Jagjit R. Khurma

Solution cast blends of poly(e-caprolactone) [PCL] and poly(vinyl formal) [PVF] from dichloromethane was investigated for miscibility by Differential Scanning Calorimetry [DSC], Fourier Transform Infrared Spectroscopy [FTIR] and optical microscopy. Melting (Tm) and crystallization (Tc) temperatures were for the PCL fraction while the glass transition temperature (Tg) was for PVF fraction in the blends. Blends with 20 wt% and less PCL showed a depression in Tm and Tc. Depression in Tc indicated that during the non-isothermal crystallization process, the presence of PVF decreased the PCL segments migrating to the crystallite-melt interface thus reducing the nucleation rate, growth rate and the thickness of the lamella resulting in a depressed Tm. Crystallinity (Xc) decreased gradually with decreasing content of PCL in the blend and was due to the dilution of PCL by PVF. A depressed Tg was observed for 10 wt% PCL blend and remained the same for all other blend compositions. These observations suggested that this blend system has very low degree of miscibility. The degree of miscibility increased at low polyester concentration. FTIR spectra of the blends with low polyester concentrations showed changes in the C=O, O-H and C-O-C regions in the blended PVF and PCL spectra. Optical microscopy showed phase separation in the melt and in the PCL spherulites.


Author(s):  
Chris Alexander

The design of offshore subsea pipelines is facing new challenges as the pipeline industry is moving into environments requiring high pressure design. Conventional pipeline design codes such as ASME B31.4 and B31.8 establish pressure limits based on percentage of the pipe material’s minimum specified yield strength. While this has traditionally worked for relatively thin-walled pipe at moderate pressures, there are concerns that full utilization of the material’s capacity is not being realized when designing for high pressure conditions. Additionally, there are concerns regarding the ability to achieve high quality manufacturing and consistently fabricate welds in thick-wall pipes. This paper presents details on a testing program that incorporated full-scale burst testing to qualify the design pressure for an 18-inch × 0.75-inch, Grade X65 subsea gas pipeline using the methodology of API RP 1111. A lower bound burst pressure was established based on the recorded burst pressures to which a design margin of 0.72 was applied to determine a design pressure. Had the pipeline been conventionally-designed using ASME B31.8, the design pressure would have been 3,900 psi. However, using the experimentally-based design option in API RP 1111 the resulting design pressure was 4,448 psi. This results in a net increase in the design pressure of 14 percent. When one considers either the potential cost savings in material requirements at construction or the additional throughput associated with higher design pressures for a given pipeline system, it is not difficult to demonstrate the economic benefits derived in performing a more rigorous material qualification and limit state design process based on experimental methods as presented in API RP 1111.


Molecules ◽  
2020 ◽  
Vol 25 (17) ◽  
pp. 3807
Author(s):  
Kervin O. Evans ◽  
Christopher Skory ◽  
David L. Compton ◽  
Ryan Cormier ◽  
Gregory L. Côté ◽  
...  

α-Glucans that were enzymatically synthesized from sucrose using glucansucrase cloned from Leuconostoc mesenteroides NRRL B-1118 were found to have a glass transition temperature of approximately 80 °C. Using high-pressure homogenization (~70 MPa), the α-glucans were converted into nanoparticles of ~120 nm in diameter with a surface potential of ~−3 mV. Fluorescence measurements using 1,6-diphenyl-1,3,5-hexatriene (DPH) indicate that the α-glucan nanoparticles have a hydrophobic core that remains intact from 10 to 85 °C. α-Glucan nanoparticles were found to be stable for over 220 days and able to form at three pH levels. Accelerated exposure measurements demonstrated that the α-glucan nanoparticles can endure exposure to elevated temperatures up to 60 °C for 6 h intervals.


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