scholarly journals Comparison of preconcentration methods of the colloidal phase of a uranium-containing soil suspension

Talanta ◽  
2020 ◽  
Vol 208 ◽  
pp. 120383 ◽  
Author(s):  
Emmanuelle Maria ◽  
Pierre Crançon ◽  
Philippe Le Coustumer ◽  
Maxime Bridoux ◽  
Gaëtane Lespes
Keyword(s):  
2021 ◽  
Vol 223 ◽  
pp. 112591
Author(s):  
Chengli Zhang ◽  
Yuchen Lei ◽  
Jing Qian ◽  
Yixin Qiao ◽  
Jingchao Liu ◽  
...  

1987 ◽  
Vol 67 (2) ◽  
pp. 409-414 ◽  
Author(s):  
KARL C. IVARSON ◽  
LAURE M. BENZING-PURDIE

Synthetic melanoidins, unlabeled and U–14C labeled, mixed with sand, inoculated with a soil suspension and incubated in Warburg vessels for 30 d, decomposed slowly. Reactants (amino acids, sugars and NH4 salts) involved in melanoidin formation had no influence on rate of degradation, nor did the pH at which the melanoidins were synthesized. However, temperature of synthesis affected the rate; an increase led to a decrease in biodegradability paralleled by both increase in C:N ratio and unsaturation. At lower temperatures species of Penicillium, Cladosporium and Paecilomyces were the dominant fungi degrading the polymers, while at higher temperatures only Penicillium species were present. Key words: Melanoidins, decomposition by soil microbes


1998 ◽  
Vol 64 (10) ◽  
pp. 3846-3853 ◽  
Author(s):  
A. J. Termorshuizen ◽  
J. R. Davis ◽  
G. Gort ◽  
D. C. Harris ◽  
O. C. Huisman ◽  
...  

ABSTRACT In a comparison of different methods for estimatingVerticillium dahliae in soil, 14 soil samples were analyzed in a blinded fashion by 13 research groups in seven countries, using their preferred methods. One group analyzed only four samples. Twelve soil samples were naturally infested, and two had known numbers of microsclerotia of V. dahliae added to them. In addition, a control was included to determine whether transport had an effect on the results. Results differed considerably among the research groups. There was a 118-fold difference between the groups with the lowest and highest mean estimates. Results of the other groups were evenly distributed between these extremes. In general, methods based on plating dry soil samples gave higher numbers of V. dahliae than did plating of an aqueous soil suspension. Recovery of V. dahliae from samples with added microsclerotia varied from 0 to 59%. Most of the variability within each analysis was at the petri dish level. The results indicate the necessity to check the performance of detection assays regularly by comparing recoveries with other laboratories, using a common set of soil samples. We conclude that wet plating assays are less accurate than dry plating assays.


Soil Science ◽  
1988 ◽  
Vol 146 (4) ◽  
pp. 221-231 ◽  
Author(s):  
J. J. T. I. BOESTEN ◽  
L. J. T. VAN DER PAS

2020 ◽  
Vol 20 (4) ◽  
pp. 399-407
Author(s):  
Yuriy Vodyanitskii ◽  
Tatiana Minkina

Laboratory-dried specimens yield distorted information about the state of hydromorphic soil. Changes in the gas medium, humidity, temperature, aggregation capacity and illumination have an irreversible impact on the dried and powdered soil specimen. Properties of the dried hydromorphic soil can be altered significantly. Most altered are (1) the colour of the hydromorphic soils, (2) the рН value, and (3) the content of mobile trace metal (TM) compounds after drying the wet soil. Colour change (browning) of the hydromorphic soil is related to the oxidation of Fe(II). In a highly ferruginous soil, the browning is rapid and visible even to the naked eye. In the weakly ferruginous gley, the colour change is invisible to the naked eye, but instrumental field measurements reveal a slow and slight yellowing of the dried gley. In dried soils, laboratory рН values determined in soil suspension differ from the values determined in soil solution at the same time. The process of drying provokes a significant decrease in the content of mobile TM compounds, resulting in the illusion of less soil contamination than the real situation during hydromorphic soil humidification. When studying hydromorphic soils, it is desirable to accomplish the maximum possible field measurements. Laboratory analyses should only be carried out for specimens stored under dark conditions since they retain the initial humidity, temperature and gas composition.


2001 ◽  
Vol 84 (5) ◽  
pp. 1407-1412 ◽  
Author(s):  
Daniela Perret ◽  
Alessandra Gentili ◽  
Stefano Marchese ◽  
Aldo Marino ◽  
Federica Bruno

Abstract A simple method is described for the simultaneous determination of residues of 2 carbamate herbicides (phenmedipham and desmedipham) and related metabolites (m-aminophenol, aniline, and m-toluidine) in soil. The analytes are extracted from spiked soils with methanol. The solvent/soil suspension is centrifuged, and the supernatant is directly injected, without any further cleanup, into a reversed-phase liquid chromatography/mass spectrometry apparatus equipped with a TurboIonSpray interface. The method was tested on 5 soils having different physicochemical properties. Recoveries from the soil types, spiked over the range of 50–200 ppb, were essentially quantitative for each analyte. The detection limits of the method are ≤25 ng/g.


2020 ◽  
Author(s):  
Wolfgang Durner ◽  
Alina Miller ◽  
Madita Gisecke ◽  
Sascha C. Iden

<p>The integral suspension pressure method (ISP) uses pressure measurements in a soil suspension to derive the particle size distribution (PSD) in the silt range in high resolution. The sedimentation process is mathematically simulated and the simulated suspension pressure at a fixed depth in the sedimentation cylinder is fitted to an observed time series. The PSD is determined by numerically solving the inverse problem. The methodology is implemented in a commercial apparatus named PARIO that is produced by METER AG, Munich.</p><p>Practical experiments with PARIO indicated that the accuracy of the method to determine the clay fraction was not as high as expected from theory, which may partly be caused by the error propagation from the independently determined sand fractions. Durner and Iden (2019) thus proposed an extension of the experimental protocol called ISP<sup>+</sup>, which makes the inverse problem better-posed and allows shorter experimental time. After a sedimentation time of few hours, a part of the suspension is drained laterally from the sedimentation cylinder through an outlet, collected and oven-dried. The resulting dry mass of the soil particles is integrated into the objective function of the inverse problem. This markedly reduces the uncertainty of the identified PSD towards the finest particles. We present experimental results from PARIO measurements evaluated by the ISP<sup>+</sup> method and illustrate the new experimental design and the improvement of accuracy for the clay fraction.</p><p>Reference: Durner, W., & Iden, S. C. (2019, January). ISP+: improving the Integral Suspension Pressure method by an independent measurement of clay content. In Geophysical Research Abstracts (Vol. 21).</p>


1996 ◽  
Vol 42 (4) ◽  
pp. 867-879 ◽  
Author(s):  
Tomoyuki Makino ◽  
Yoshiaki Takahashi ◽  
Yasuhiro Sakurai ◽  
Masami Nanzyo

1923 ◽  
Vol 13 (3) ◽  
pp. 321-332 ◽  
Author(s):  
A. F. Joseph ◽  
F. J. Martin

(1) The colorimetric method is unsuited to the examination of heavy, alkaline soils owing to the turbidity of the suspension.(2) Where the nature of the suspension permits of colorimetric determinations being made, they agree with those obtained electrometrically: with the latter method practically identical results are obtained using soil-water mixtures or moderately clear extracts.(3) No disturbing effect is likely to be introduced by amounts of nitrate up to 500 parts per million of soil.(4) Owing to the effect on the pH of a soil suspension caused by varying the proportion of water and time of extraction, these conditions should be fixed for routine work. We have found 1 hour's extraction with 5 parts of water satisfactory.(5) On account of the amphoteric or buffer nature of clay, soil shifts the reaction of acids and alkalis in the direction of neutrality.(6) The effect of sodium salts on a soil is to displace aluminium and so reduce alkalinity: the residual soil after leaching is found to be more alkaline.(7) The effect of drying alkaline soil is to cause the pH of the extract to be lower than that obtained from the undried soil. If however the time of extraction is prolonged, the differences disappear almost entirely.


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