Electrochemical impedance and X-ray photoelectron spectroscopic studies of the inhibition of mild steel corrosion in acids by cyclohexylamine

1997 ◽  
Vol 42 (4) ◽  
pp. 605-615 ◽  
Author(s):  
P. Li ◽  
J.Y. Lin ◽  
K.L. Tan ◽  
J.Y. Lee
Keyword(s):  
Mild Steel ◽  
Electrochemical Impedance ◽  
Steel Corrosion ◽  
Spectroscopic Studies ◽  
X Ray ◽  
Mild Steel Corrosion

RHIZOPHORA APICULATA AS ECO-FRIENDLY INHIBITOR AGAINST MILD STEEL CORROSION IN 1 M HCL

2017 ◽  
Vol 24 (Supp01) ◽  
pp. 1850013 ◽  
Author(s):  
MOHAMMAD ALI ASAAD ◽  
MOHAMMAD ISMAIL ◽  
PANDIAN BOTHI RAJA ◽  
NUR HAFIZAH A. KHALID
Keyword(s):  
Mild Steel ◽  
Mixed Type ◽  
Adsorption Mechanism ◽  
Electrochemical Impedance ◽  
Steel Corrosion ◽  
Gravimetric Measurement ◽  
X Ray ◽  
Rhizophora Apiculata ◽  
Mild Steel Corrosion ◽  
Langmuir Isotherm Model

The inhibitive characteristics of aqueous extracts from mangrove (Rhizophora apiculata) bark and leaf on the corrosion of mild steel (MS) coupon in 1 M HCl were examined by means of the gravimetric measurement (weight loss), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques. The MS surface morphologie were investigated using field emission scanning electron microscopy (FESEM) with Energy Dispersive X-Ray Analysis (EDX) at 120[Formula: see text]h in the presence and absence of green inhibitors in corrosive medium. Respective inhibition efficiencies of 68.1% and 59.0% were obtained when exposed to 10% v/v Rhizophora apiculata solution for 72[Formula: see text]h. Examination of the adsorption behavior of the solutions indicated the Langmuir isotherm model as being the most likely relevant adsorption mechanism. In addition, polarization measurements showed that both bark and leaves extract inhibitors act via mixed type inhibition.

scholarly journals Inhibiting Effects of Rabeprazole Sulfide on the Corrosion of Mild Steel in Acidic Chloride Solution

2013 ◽  
Vol 2013 ◽  
pp. 1-9 ◽  
Author(s):  
M. K. Pavithra ◽  
T. V. Venkatesha ◽  
M. K. Punith Kumar
Keyword(s):  
Mild Steel ◽  
Electrochemical Impedance ◽  
Steel Corrosion ◽  
Protection Efficiency ◽  
Langmuir Adsorption ◽  
Kinetic And Thermodynamic Parameters ◽  
Mild Steel Corrosion ◽  
Acidic Chloride Solution ◽  
Acidic Chloride ◽  
Mixed Type Inhibitor

The corrosion inhibition effect of Rabeprazole sulfide (RS) on mild steel in 1 M hydrochloric acid (HCl) was investigated using weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and chronoamperometric measurements. Protection efficiency of RS increases with the concentration and decreases with the rise in temperature. Adsorption of RS on mild steel surface in 1 M HCl follows Langmuir adsorption isotherm. The kinetic and thermodynamic parameters governing the adsorption process were calculated and discussed. The polarization results suggest that RS performed as an excellent mixed-type inhibitor for mild steel corrosion in 1 M HCl.

scholarly journals Mitigation of Mild Steel Corrosion in Acidic Solution Using Inhibitor

2011 ◽  
Vol 8 (s1) ◽  
pp. S53-S60 ◽  
Author(s):  
M. Vishnudevan
Keyword(s):  
Mild Steel ◽  
Sodium Benzoate ◽  
Inhibition Efficiency ◽  
Acidic Solution ◽  
Electrochemical Impedance ◽  
Steel Corrosion ◽  
Trisodium Citrate ◽  
Tafel Polarization ◽  
Mild Steel Corrosion ◽  
Maximum Inhibition

The inhibition efficiency of mild steel corrosion in HCl acidic solution containing various concentrations of mixed inhibitors were evaluated by conducting Tafel polarization and electrochemical impedance studies. The mixed inhibitors used in this present investigation were trisodium citrate and sodium benzoate. In this present investigation 0.01 N to 0.1 N concentrations of HCl was used at 30°C. Sodium benzoate present in the mixed inhibitive system enhanced the inhibition efficiency through chemisorptions. The maximum inhibition efficiency ( 95.4%) was obtained for the mixed inhibitive system containing 0.05 M citrate and 0.5 M benzoate in 0.1 N HCl.

scholarly journals The Inhibition of Mild Steel Corrosion in Sulfuric Acid by New Dapsone Derivatives

2014 ◽  
Vol 10 (3) ◽  
pp. 2388-2402 ◽  
Author(s):  
M.P. Chakravarthy ◽  
Dr. K. N. Mohana ◽  
C.B. Pradeep Kumar
Keyword(s):  
Mild Steel ◽  
Corrosion Inhibitors ◽  
Electrochemical Impedance ◽  
Steel Corrosion ◽  
Tafel Polarization ◽  
New Class ◽  
Mild Steel Corrosion ◽  
Langmuir Isotherm Model ◽  
Polarization Studies ◽  
Corrosion Inhibition Efficiency

Dapsone derivatives Viz., 4, 4’-sulfonylbis(N-((1H-pyrrol-2-yl)methylene)aniline) (SBPMA) and 2-dimethylamino-5-[(4-{4-[(4-dimethylamino-benzylidene)-amino]-benzenesulfonyl}-phenylimino)-methyl]-benzene (DBBPB), a new class of corrosion inhibitors have been synthesized and their corrosion inhibition efficiency on mild steel in 0.5 M H2SO4 was investigated by mass loss,  Tafel polarization and AC impedance measurements. Potentiodynamic polarization studies showed that, these compounds behave as mixed type of corrosion inhibitors. The adsorption process was found to obey Langmuir isotherm model. Electrochemical impedance spectroscopy (EIS) studies revealed that polarization resistance (RP) increases and double layer capacitance (Cdl) decreases as the concentration of the inhibitors increases. Various thermodynamic parameters for the adsorption of inhibitors on mild steel were computed and discussed. FTIR, EDX and SEM analyses were performed to study the film persistency of the inhibitors.

scholarly journals EFFECT OF ANION GROUPS ON CORROSION INHIBITION BEHAVIOURS OF VIETNAM ORANGE PEEL ESSENTIAL OIL FOR MILD STEEL IN THE ACIDIC MEDIA

2018 ◽  
Vol 55 (5B) ◽  
pp. 103
Author(s):  
Bui Thi Thanh Huyen
Keyword(s):  
Essential Oil ◽  
Mild Steel ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Orange Peel ◽  
Steel Corrosion ◽  
Inhibition Mechanism ◽  
Acidic Media ◽  
Mild Steel Corrosion ◽  
Potentiodynamic Electrochemical Impedance Spectroscopy

This paper deals with the effect of anion groups (SO42- and Cl-) on inhibition behaviours of Vietnam orange peel essential oil (OPE) for corrosion process of mild steel in acidic media. The electrochemical techniques (potentiodynamic, electrochemical impedance spectroscopy (EIS)), weight loss and scanning electron microscopy (SEM) analyses are used in this study. The results show that anion groups do not affect the inhibition mechanism of OPE. The OPE ­behaves as mixed inhibitor for mild steel corrosion in both 1N HCl and H2SO4 acid. The inhibition efficiency of OPE in 1N HCl is greater than that in 1N H2SO4 which implies that the adsorption of the inhibitor is influenced by the nature of anions in acidic solutions. Moreover, the OPE inhibits both general and pitting corrosion for mild steel in the acidic media. 

Inhibition of Steel Corrosion in Sulfuric Acid Solution by 1,10-Phenanthroline, para-Aminobenzoate and their Corresponding Manganese Complex

2019 ◽  
Vol 233 (11) ◽  
pp. 1553-1569 ◽  
Author(s):  
Rola N. Tabesh ◽  
Ashraf Moustafa Abdel-Gaber ◽  
Hassan H. Hammud ◽  
Rami Al-Oweini
Keyword(s):  
Mild Steel ◽  
Corrosion Inhibition ◽  
Electrochemical Impedance ◽  
Activation Parameters ◽  
Steel Corrosion ◽  
Inhibition Mechanism ◽  
Acidic Solutions ◽  
Mild Steel Corrosion ◽  
Uv Visible ◽  
Adsorptive Properties

Abstract The ligands 1,10-phenanthroline, (P) and para-aminobenzoate, (B); as well as their corresponding MnPB complex [bis-(dimanganese di-μ-paraaminobenzoate dichloro diphenanthroline)] have been investigated as inhibitors of mild steel corrosion in H2SO4 (0.5 M) solutions via potentiodynamic and electrochemical impedance spectroscopy techniques. Stability of the prepared complex was examined by UV-visible spectroscopy. The corrosion inhibition, thermodynamics, and adsorptive properties obtained have shown that MnPB complex has remarkable effects in the acidic solutions. Theoretical fitting of different adsorption isotherms such as Langmuir, Flory–Huggins, and the kinetic-thermodynamic models were tested and the thermodynamic activation parameters were calculated. The data revealed that the corrosion inhibition mechanism of mild steel in acidic solutions by the MnPB complex goes via physicochemical adsorption.

Comparative study of 1,2,3-triazole derivatives as corrosion inhibitors of mild steel in sulphuric acid solution

2019 ◽  
Vol 66 (5) ◽  
pp. 544-555 ◽  
Author(s):  
Ilham Elazhary ◽  
My Rachid Laamari ◽  
Aziz Boutouil ◽  
Lahoucine Bahsis ◽  
Mohammadine El Haddad ◽  
...  
Keyword(s):  
Mild Steel ◽  
Electrochemical Impedance ◽  
Steel Corrosion ◽  
Sulphuric Acid Solution ◽  
Frontier Molecular Orbital ◽  
Effect Of Temperature ◽  
Orbital Theory ◽  
Content Type ◽  
Mild Steel Corrosion ◽  
The Difference

Purpose This paper aims to study the corrosion inhibition of Methyl 2-(benzamido)-2-(4-phenyl-1H-1,2,3-triazol-1-yl) acetate (MBPTA) and Methyl 2-(benzamido)-2-(4-p-tolyl-1H-1,2,3-triazol-1-yl) acetate (MBTTA) in 1 M H2SO4 solution at 25 °C. Design/methodology/approach The authors have used weight loss measurements, electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, FT-IR, quantum chemical calculations and scanning electron microscopy (SEM) techniques. Findings The polarization measurements indicate that both compounds are mixed type inhibitors, and that MBTTA is more effective than MBPTA. The effect of temperature on the corrosion behavior using optimal concentration of MBTTA and MBPTA was studied in the temperature range 298-328 K. SEM was used to examine the morphology of the metal surface. Thermodynamic parameters were calculated and discussed. Monte Carlo simulations were applied to lookup for the most stalls configuration and adsorption energy for the interaction of inhibitors on Fe (1 1 1) interface. The difference in inhibition efficiencies between the two organic inhibitors can be clearly explained in terms of frontier molecular orbital theory. Originality/value The authors report on the comparative inhibiting effect of two new 1,4-disubstituted 1,2,3-triazoles, namely Methyl 2-(benzamido)-2-(4-phenyl-1H-1,2,3-triazol-1-yl) acetate (MBPTA) and Methyl 2-(benzamido)-2-(4-p-tolyl-1H-1, 2, 3-triazol-1-yl) acetate (MBTTA) on mild steel corrosion in 1 M H2SO4 solution.

Inhibition effect of E and Z conformations of 2-pyridinealdazine on mild steel corrosion in phosphoric acid

2017 ◽  
Vol 64 (1) ◽  
pp. 23-35 ◽  
Author(s):  
Mohammed Elalaoui Belghiti ◽  
Ayssar Nahlé ◽  
Abdeslam Ansari ◽  
Yasser Karzazi ◽  
S. Tighadouini ◽  
...  
Keyword(s):  
Weight Loss ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Mild Steel ◽  
Electrochemical Impedance ◽  
Steel Corrosion ◽  
Content Type ◽  
Inhibition Effect ◽  
Tafel Polarization ◽  
Mild Steel Corrosion

Purpose This paper aims to study the inhibition effect of 2-pyridinealdazine on the corrosion of mild steel in an acidic medium. The inhibition effect was studied using weight loss, electrochemical impedance spectroscopy, and Tafel polarization measurements. Design/methodology/approach Weight loss measurements, potentiodynamic tests, electrochemical impedance spectroscopy, X-ray diffraction and spectral and conformational isomers analysis of A (E-PAA) and B (Z-PAA) were performed were investigated. Findings 2-pyridinealdazine (PAA) acts as a good inhibitor for the corrosion of steel in 2.0 M H3PO4. The inhibition efficiency increases with an increase in inhibitor concentration but decreases with an increase in temperature. Originality/value This paper is intended to be added to the family of azines which are highly efficient inhibitors and can be used in the area of corrosion prevention and control.

scholarly journals Aspartic Acid as Corrosion Inhibitor of Mild Steel Corrosion Using Weight Loss, Acidimetry and EIS Measurement

2018 ◽  
Vol 15 (2) ◽  
pp. 6262-6274
Author(s):  
Sylvester Obaike Adejo ◽  
Stephen Gbaoron Yiase ◽  
Joseph Aondoaver Gbertyo ◽  
Emmanuel Onah Ojah
Keyword(s):  
Weight Loss ◽  
Adsorption Isotherm ◽  
Mild Steel ◽  
Aspartic Acid ◽  
Electrochemical Impedance ◽  
Steel Corrosion ◽  
Isotherm Models ◽  
Chemical Adsorption ◽  
Free Energy Of Adsorption ◽  
Mild Steel Corrosion

Corrosion inhibition characteristics of aspartic acid on  mild steel corrosion in 0.5 M H2SO4 was investigated using weight loss, acidimetry, and electrochemical impedance spectroscopy (EIS). Analysis of the metal surface morphology, uninhibited and inhibited, was carried out through scanned electron microscope. The results showed that the inhibition efficiency increased with increase in inhibitors concentration and rise in temperature for all methods used. The highest v efficiency of  32.36 %, 66.26 % and 80.40 % were obtained for weight loss, acidimetry and EIS, respectively. The low value of efficiency for weight loss compared to other methods should signify the limitation for the method. The increase in efficiency with rise in temperature is a feature of chemical adsorption, which was confoirmed by the value of parameter b of the Adejo-Ekwenchi adsorption isotherm (AEI) model. Values of free energy of adsorption, ?Gads were all negative for all the methods, which means the adsorption processes were spontaneous. The heats of adsorption, Qads values were all positive, implying that the processes were endothermic. Values of activation energy were fairly constant, which is an evident to support the proposed chemical adsorption mechanism. The negative sign in the values of entropy of adsorption, ?Sads is an indication  that the activated complex in the rate-determining step was associative. The data obtained was tested with several isotherms, but found to best fit into the El-Awady, Freundlich and Tempkin adsorption isotherm models.

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