Evaporated thin films of tetrathiafulvalene derivatives and their charge-transfer complexes

1998 ◽  
Vol 335 (1-2) ◽  
pp. 209-213 ◽  
Author(s):  
M Kilitziraki ◽  
A.J Moore ◽  
M.C Petty ◽  
M.R Bryce
2017 ◽  
Vol 19 (29) ◽  
pp. 18845-18853 ◽  
Author(s):  
Ken Kato ◽  
Shogo Hagi ◽  
Masumi Hinoshita ◽  
Eiji Shikoh ◽  
Yoshio Teki

Thin films of weak charge-transfer complexes (pyrene/dimethylpyromellidiimide or pyrene/pyromellitic dianhydride) were investigated by time-resolve ESR, photoconductivity, and magneto-photoconductance measurements.


2016 ◽  
Vol 4 (25) ◽  
pp. 5981-5987 ◽  
Author(s):  
Toshiki Higashino ◽  
Masaki Dogishi ◽  
Tomofumi Kadoya ◽  
Ryonosuke Sato ◽  
Tadashi Kawamoto ◽  
...  

Novel mixed stack charge-transfer complexes (DMeO-BTBT)(Fn-TCNQ) show air-stable n-channel transistor performance in the thin films and single crystals.


2021 ◽  
pp. 132625
Author(s):  
Jingwei Sun ◽  
Shengchen Yang ◽  
Jiali Wu ◽  
Xixi He ◽  
Yujian Zhang ◽  
...  

1991 ◽  
Vol 228 ◽  
Author(s):  
Andrew Skumanich

ABSTRACTUsing the sensitive absorption technique of Photothermal Deflection Spectroscopy (PI1S) it is possible to detect subtle spectral features in the absorption spectra of polymeric thin films that cannot be detected by other means. This paper describes observations of weak charge-transfer complex (CIC) formation and also light-induced changes in various organic films. The filns studied were those commonly used as charge transport materials in organic photoconductors, comprised of a small transport molecule and a polymer binder. The optically measured CTC bands can be used to establish single electron energy levels of the constituents. Reproducible photo-induced changes are manifest both in the strong UV transitions as well as in the “sub-gap” absorption and appear to be correlated with the photo-chemical stability of the constituents. The light-fatigue has both a reversible as well as irreversible component.


1997 ◽  
Vol 90 (3) ◽  
pp. 407-413
Author(s):  
MARC KELEMEN ◽  
CHRISTOPH WACHTER ◽  
HUBERT WINTER ◽  
ELMAR DORMANN ◽  
RUDOLF GOMPPER ◽  
...  

2018 ◽  
Author(s):  
Kun Wang ◽  
Andrea Vezzoli ◽  
Iain Grace ◽  
Maeve McLaughlin ◽  
Richard Nichols ◽  
...  

We have used scanning tunneling microscopy to create and study single molecule junctions with thioether-terminated oligothiophene molecules. We find that the conductance of these junctions increases upon formation of charge transfer complexes of the molecules with tetracyanoethene, and that the extent of the conductance increase is greater the longer is the oligothiophene, i.e. the lower is the conductance of the uncomplexed molecule in the junction. We use non-equilibrium Green's function transport calculations to explore the reasons for this theoretically, and find that new resonances appear in the transmission function, pinned close to the Fermi energy of the contacts, as a consequence of the charge transfer interaction. This is an example of a room temperature quantum interference effect, which in this case boosts junction conductance in contrast to earlier observations of QI that result in diminished conductance.<br>


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