Of the necessity of knowledge of the natural pedo-geochemical background content in the evaluation of the contamination of soils by trace elements

2001 ◽  
Vol 264 (1-2) ◽  
pp. 127-139 ◽  
Author(s):  
Denis Baize ◽  
Thibault Sterckeman
2019 ◽  
Vol 42 (5) ◽  
pp. 1235-1254
Author(s):  
Jemal Ahmed

Abstract This paper reports the results of trace elements geochemistry from Tigray national state, northwestern Ethiopia. The area is part of the Arabian-Nubian Shield, where the dominant exposure is low-grade metamorphic rocks and has a long history of liver-related diseases. The increase in the number of liver-related disease patients of the area has been an environmental health issue of national concern. The aim of the study is to determine the level of trace element concentrations and distributions in water and stream sediments of the area and identify the possible sources in relation to human health. Water, stream sediment and rocks samples (20 water, 20 stream sediments, and 6 rock samples) were collected in March 2011 and analyzed for major and trace element contents using ICP-MS, ICP-OES, ion Chromatography, and XRF methods. Bromine, aluminum, fluorine, arsenic, and nitrate values exceed the WHO maximum acceptable concentration (MAC) for drinking purpose. Bromine ranges from 0.11 to 1.48 mg/l show higher values in all samples, and fluorine ranges from 0.21 to 16.49 mg/l show higher values in 20% of the samples. Other trace elements are aluminum—30%, arsenic—10%, and nitrate (NO3)—10%, and they are examples of elements which have above MAC for drinking water. Selenium deficiency may be the other problematic element in the area for which its deficiency is associated with liver damage and heart muscle disorder. The concentration of cobalt and chromium exceeded world geochemical background value in average shale at most sample stations indicated that these stations were in potential risk.


Environments ◽  
2022 ◽  
Vol 9 (1) ◽  
pp. 11
Author(s):  
Clarisse Mourinha ◽  
Patrícia Palma ◽  
Carlos Alexandre ◽  
Nuno Cruz ◽  
Sónia Morais Rodrigues ◽  
...  

Both sectors of the Iberian Pyrite Belt, Portuguese and Spanish, have been exploited since ancient times, but more intensively during and after the second half of the 19th century. Large volumes of polymetallic sulfide ore were extracted in open pits or in underground works, processed without environmental concerns, and the generated waste rocks and tailings were simply deposited in the area. Many of these mining sites were abandoned for years under the action of erosive agents, leading to the spread of trace elements and the contamination of soils, waters and sediments. Some of these mine sites have been submitted to rehabilitation actions, mostly using constructive techniques to dig and contain the contaminated tailings and other waste materials, but the remaining soil still needs to be treated with the best available techniques to recover its ecosystem functions. Besides the degraded physical structure and poor nutritional status of these soils, they have common characteristics, as a consequence of the pyrite oxidation and acid drainage produced, such as a high concentration of trace elements and low pH, which must be considered in the remediation plans. This manuscript aims to review the results from studies which have already covered these topics in the Iberian Pyrite Belt, especially in its Portuguese sector, considering: (i) soils’ physicochemical characteristics; (ii) potentially toxic trace elements’ concentration; and (iii) sustainable remediation technologies to cope with this type of soil contamination. Phytostabilization, after the amelioration of the soil’s properties with organic and inorganic amendments, was investigated at the lab and field scale by several authors, and their results were also considered.


Author(s):  
Izabela BOJAKOWSKA ◽  
Przemysław DOBEK ◽  
Jaroslaw KUCHARZYK

In the samples of sediment accumulated in the reservoir Zadębie and ground from the its bottom the contents of the As, Ba, Cr, Cd, Co, Cu, Hg, Mo, Ni, Sn, Sr, V, Zn and Ca, Fe, Mg, Mn, S, P, and TOC were determined. The content of mineral oil, 17 PAHs compounds, 7 PCB congeners and 20 organochlorine pesticides were determined as well. Sediment accumulated in the reservoir is characterized by very low contents of trace elements similar to the geochemical background values. Slightly increased content of Ba, Zn, Cu, Cr, Pb and Hg were observed in the northern part of the basin. There was a significant increase in the content of mineral oils and PAHs in sediments accumulated compared to their content in the bedding layer. Among the analyzed organochlorine compounds were detected only isomer of α-HCH and p,p′-DDT and its metabolites.


Water ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2364
Author(s):  
Nickolai Shadrin ◽  
Natalia Mirzoeva ◽  
Natalia Kravchenko ◽  
Oksana Miroshnichenko ◽  
Nataliya Tereshchenko ◽  
...  

Knowledge of trace elements content and their behavior in aquatic ecosystems is important for their sustainable use. There is a lack of such data for saline and, especially, hypersaline lakes and lagoons. Concentrations of more than 20 elements were evaluated in bottom sediments of 15 saline/hypersaline lakes and Lagoon Sivash in Crimea. An average salinity varied from 4 to 335 g/L in studied water bodies. The concentration of the trace elements varied from lake to lake. The highest variability was recorded for Cd, from 4.13 mg/kg to below the detectable level (CV = 1.463), and for Se, from 5.52 to 0.05 mg/kg (CV = 1.053). The lowest variability demonstrated by Cr, from 368 to 17 mg/kg (CV = 0.463), and by V, from 67.8 to 1.7 mg/kg (CV = 0.481). According to the found content of studied elements, all lakes were separated into three groups, and Lagoon Sivash was not included in these clusters. Salinity affected the concentration of some elements in bottom sediments, and this effect was not linear or unidirectional. In some cases, the action of other factors, often unknown, masked the effect of salinity. The geochemical background affects the structure and functioning of aquatic ecosystems, but the state of these ecosystems can significantly modify this background. An understanding of the differences in the elemental composition of bottom sediments in different lakes is possible only based on an integrated consideration of the interaction of all landscape, intra-ecosystem, and anthropogenic processes and factors that can influence this.


Minerals ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1210
Author(s):  
Vera Strakhovenko ◽  
Ekaterina Ovdina ◽  
Georgy Malov ◽  
Nadezhda Yermolaeva ◽  
Eugeniya Zarubina

The processes of the migration and concentration of trace elements during sedimentation in small continental lakes in various landscape zones of the south of Western Siberia have been studied. We provide a quantitative assessment of the concentration levels and changes in the regional geochemical background of Cd, Hg, Sb, Zn, and Pb in sapropel deposits over the past 200 years. It was shown that complex natural processes determined by a combination of azonal factors play a fundamental role in the formation of the geochemical and mineral compositions of the bottom sediments of small lakes in various landscape zones in the south of Western Siberia. These consist of: the formation of sedimentary material in the lake catchment depending on the relief, geology, soil, and vegetation cover, as well as anthropogenic influences; the formation of authigenic organic and mineral matter as a result of biological, biochemical, and physicochemical processes; and the deposition of a complex mixture of allochthonous and autochthonous matter at the bottom of a lake, which flows under conditions of prolonged ice formation (anaerobic conditions).


2020 ◽  
Vol 8 (9) ◽  
pp. 1187-1195
Author(s):  
Muhune Kitule Simon ◽  
◽  
Mbayo Kitambala Marsi ◽  
Tshisand Tshibwid Patrick ◽  
Muyumba Nonga Welcome ◽  
...  

The Contamination of soils near the road Lubumbashi-Kipushi was investigated. Analysis of cadmium, copper, lead, and zinc contents, as well as pH-water samples, yielded average MTEs with a decreasing profile concerningthe distance from the road with pH values ​​around 7.5. At the surface, copper gave the highest value (14459 mg/kg) of all MTE studied near the road at 0.5m and the lowest value (2271 mg/kg) at 20m of the road. Cadmium did not vary statistically but gave the lowest value (54.5 mg/kg) of all MTE at 20m from the road with a high value of 478 mg/kg at 2.5m from the road. Compared to sampling sites, statistical averages for these three variables (Cu, Pb, and Zn) showed a change in copper content with a high value of 13675 mg/kg at site 4 and a low value of 4771 mg/kg at site 3. Cadmium did not give a significant variation from sites. In-depth, the elements displayed the same behavior as on the surface. This was the case of copper, which had an average concentration of 14751 mg/kg at a distance of 0.5m close to the road and its smallest value was 2151 mg/kg at 50m. The pH did not show any significant variations. The correlation between the parameters studied showed that Cu, Cd, and Pb contents were bound, but they were independent of pH while Zn was bound to pH.


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