Heat and Mass Transfer Limitations and Catalyst Deactivation Effects in Olefin Polymerization for Gas Phase and Slurry Reactors

Author(s):  
S. Floyd ◽  
G.E. Mann ◽  
W.H. Ray
1987 ◽  
Vol 109 (2) ◽  
pp. 89-93 ◽  
Author(s):  
P. Gandhidasan ◽  
M. Rifat Ullah ◽  
C. F. Kettleborough

Heat and mass transfer analysis between a desiccant-air contact system in a packed tower has been studied in application to air dehumidification employing liquid desiccant, namely calcium chloride. Ceramic 2 in. Raschig rings are used as the packing material. To predict the tower performance, a steady-state model which considers the heat and mass transfer resistances of the gas phase and the mass transfer resistance of the liquid phase is developed. The governing equations are solved on a digital computer to simulate the performance of the tower. The various parameters such as the effect of liquid concentration and temperature, air temperature and humidity and the rates of flow of air and liquid affecting the tower performance have been discussed.


2011 ◽  
Vol 20 (2) ◽  
pp. 192-200 ◽  
Author(s):  
M. M. Grigoryeva ◽  
G. V. Kuznetsov ◽  
P. A. Strizhak

Author(s):  
Jian-Hong Liu ◽  
Fu-Min Shang ◽  
Nikolay Efimov

Abstract Numerical simulation was performed to establishing a two-dimensional pulsating heat pipe model, to investigate the flow and heat transfer characteristics in the pulsating heat pipe by using the Mixture and Euler models, which were unsteady models of vapor-liquid two-phase, based on the control-volume numerical procedure utilizing the semi-implicit method. Through comparing and analyzing the volume fraction and velocity magnitude of gas phase to decide which model was more suitable for numerical simulation of the pulsating heat pipe in heat and mass transfer research. It was showed there had gas phase forming in stable circulation flow in the heating section, the adiabatic section using the Mixture and Euler models respectively, and they were all in a fluctuating state at 10s, besides, the pulsating heat pipe had been starting up at 1s and stabilizing at 5s, it was all found that small bubbles in the heat pipe coalescing into large bubbles and gradually forming into liquid plugs and gas columns from the contours of volume fraction of the gas phase; through comparing the contours of gas phase velocity, it could be seen that there had further stably oscillating flow and relatively stabler gas-liquid two-phase running speed in the pulsating heat pipe used the Mixture model, the result was consistent with the conclusion of the paper[11] extremely, from this it could conclude that the Mixture model could be better simulate the vaporization-condensation process in the pulsating heat pipe, which could provide an effective theoretical support for further understanding and studying the phase change heat and mass transfer mechanism of the pulsating heat pipe.


Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7754
Author(s):  
Jianwen Zhang ◽  
Yahui Zhao ◽  
Yan Li ◽  
Fan Zhang

The corrosion failure of the high-pressure heat exchanger in a petrochemical enterprise was simulated. A multiphase flow and heat and mass transfer simulation shows that the vortex core with a higher gas phase content and lower temperature is the region of easy crystallization, located on both sides of the center of the tube. The crystallization process occurs in the gas phase. As the reaction progresses, the crystallization range spreads from the tube wall to the center of the tube bundle, and the inner diameter of the tube bundle decreases continuously. In Fluent, a user-defined function, based on the ammonium chloride crystallization reaction, is loaded. The results show that crystallization first occurs in the tube bundles on both sides of the center of the tube and that the corrosion is aggravated by the erosion wall surface of crystal particles at the elbow, which is consistent with the actual corrosion failure location.


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