scholarly journals Analysis of Multiphase Flow and Heat and Mass Transfer for Ammonium Chloride Crystallization of the High-Pressure Heat Exchanger in Hydrogenation Unit

Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7754
Author(s):  
Jianwen Zhang ◽  
Yahui Zhao ◽  
Yan Li ◽  
Fan Zhang
Keyword(s):  
Mass Transfer ◽  
High Pressure ◽  
Heat Exchanger ◽  
Multiphase Flow ◽  
Gas Phase ◽  
Heat And Mass Transfer ◽  
Ammonium Chloride ◽  
Tube Bundle ◽  
Corrosion Failure ◽  
Petrochemical Enterprise

The corrosion failure of the high-pressure heat exchanger in a petrochemical enterprise was simulated. A multiphase flow and heat and mass transfer simulation shows that the vortex core with a higher gas phase content and lower temperature is the region of easy crystallization, located on both sides of the center of the tube. The crystallization process occurs in the gas phase. As the reaction progresses, the crystallization range spreads from the tube wall to the center of the tube bundle, and the inner diameter of the tube bundle decreases continuously. In Fluent, a user-defined function, based on the ammonium chloride crystallization reaction, is loaded. The results show that crystallization first occurs in the tube bundles on both sides of the center of the tube and that the corrosion is aggravated by the erosion wall surface of crystal particles at the elbow, which is consistent with the actual corrosion failure location.

scholarly journals Crystallization Behavior of Ammonium Chloride in High-Pressure Heat Exchanger of Hydrotreating Unit

2021 ◽  
Vol 2021 ◽  
pp. 1-15
Author(s):  
Jianwen Zhang ◽  
Fan Zhang ◽  
Yan Li ◽  
Yahui Zhao ◽  
Gang Sheng
Keyword(s):  
Mass Transfer ◽  
High Pressure ◽  
Heat Exchanger ◽  
Ammonium Chloride ◽  
Volume Fraction ◽  
Flow Direction ◽  
Corrosion Cracking ◽  
Inlet Temperature ◽  
Corrosion Failure ◽  
Chloride Deposition

In view of the corrosion failure of a high-pressure heat exchanger in a diesel hydrogenation unit, the formation mechanism of ammonium chloride in a multiphase flow system is investigated in this article. Numerical simulation is carried out by user defined function (UDF) on the process of adding source of mass transfer in computational fluid dynamics (CFD) solvers. The distribution characteristics of ammonium chloride are illustrated by the parameters including crystallization temperature of ammonium chloride, volume fraction of ammonium chloride, and mass transfer rates of NH3 and HCl, and the causes of corrosion cracking in the U-shaped bend of the heat exchanger are discussed. The results show that there is a great risk of ammonium chloride deposition in the heat exchanger from 4.5 m away from the outlet of the second pass. The crystallization area in the tube gradually expands from the wall to the center along the flow direction, and the crystallization rate is higher near the tube wall. The field sampling test results show that the corrosion cracking is hydrogen-induced cracking, which is due to the existence of large amount of hydrogen, high impacting force, excessive flow rate, and the risk of ammonium chloride particle erosion at the U-bend. In order to alleviate the corrosion of ammonium chloride deposition, some improvement measures are put forward, such as raising the inlet temperature of the tube side to 215 °C and increasing the water injection by 30%, which play an important role in decreasing the formation of ammonium chloride in the heat exchange system.

CFD-based structure optimization of plate bundle in plate-fin heat exchanger considering flow and heat transfer performance

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Yao Li ◽  
Haiqing Si ◽  
Jingxuan Qiu ◽  
Yingying Shen ◽  
Peihong Zhang ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Mass Transfer ◽  
Heat Exchanger ◽  
Heat And Mass Transfer ◽  
Field Performance ◽  
High Specific Surface Area ◽  
Calculation Model ◽  
Air Separation ◽  
Transfer Efficiency ◽  
Heat Transfer Efficiency

Abstract The plate-fin heat exchanger has been widely applied in the field of air separation and aerospace due to its high specific surface area of heat transfer. However, the low heat transfer efficiency of its plate bundles has also attracted more attention. It is of great significance to optimize the structure of plate-fin heat exchanger to improve its heat transfer efficiency. The plate bundle was studied by combining numerical simulation with experiment. Firstly, according to the heat and mass transfer theory, the plate bundle calculation model of plate-fin heat exchanger was established, and the accuracy of the UDF (User-Defined Functions) for describing the mass and heat transfer was verified. Then, the influences of fin structure parameters on the heat and mass transfer characteristics of channel were discussed, including the height, spacing, thickness and length of fins. Finally the influence of various factors on the flow field performance under different flow states was integrated to complete the optimal design of the plate bundle.

Analysis of Heat and Mass Transfer Between a Desiccant-Air System in a Packed Tower

1987 ◽  
Vol 109 (2) ◽  
pp. 89-93 ◽  
Author(s):  
P. Gandhidasan ◽  
M. Rifat Ullah ◽  
C. F. Kettleborough
Keyword(s):  
Mass Transfer ◽  
Gas Phase ◽  
Heat And Mass Transfer ◽  
Packing Material ◽  
Mass Transfer Resistance ◽  
Liquid Desiccant ◽  
Governing Equations ◽  
Packed Tower ◽  
Transfer Resistance ◽  
Steady State Model

Heat and mass transfer analysis between a desiccant-air contact system in a packed tower has been studied in application to air dehumidification employing liquid desiccant, namely calcium chloride. Ceramic 2 in. Raschig rings are used as the packing material. To predict the tower performance, a steady-state model which considers the heat and mass transfer resistances of the gas phase and the mass transfer resistance of the liquid phase is developed. The governing equations are solved on a digital computer to simulate the performance of the tower. The various parameters such as the effect of liquid concentration and temperature, air temperature and humidity and the rates of flow of air and liquid affecting the tower performance have been discussed.

The Experimental Investigation of Steam Condensation With Non-Condensable Gas Under Natural Convection

2018 ◽  
Author(s):  
Xizhen Ma ◽  
Wen Fu ◽  
Haijun Jia ◽  
Peiyue Li ◽  
Jun Li
Keyword(s):  
Heat Transfer ◽  
Mass Transfer ◽  
High Pressure ◽  
Natural Convection ◽  
Heat And Mass Transfer ◽  
Vertical Wall ◽  
Experimental System ◽  
Steam Condensation ◽  
Transfer Coefficients ◽  
Calculation Results

The non-condensable gas is used to keep the pressure stable in the steam-gas pressurizer. The processes of heat and mass transfer during steam condensation in the presence of non-condensable gas play an important role and the thermal hydraulic characteristics in the pressurizer is particularly complicated due to the non-condensable gas. The effects of non-condensable gas on the process of heat and mass transfer during steam condensation were experimental investigated. A steam condensation experimental system under high pressure and natural convection was built and nitrogen was chosen in the experiments. The steam and nitrogen were considered in thermal equilibrium and shared the same temperature in the vessel under natural convection. In the experiments, the factors, for instance, pressure, mass fraction of nitrogen, subcooling of wall and the distribution of nitrogen in the steam, had been taken into account. The rate of heat transfer of steam condensation on the vertical wall with nitrogen was obtained and the heat transfer coefficients were also calculated. The characteristics curve of heat and mass transfer during steam condensation with non-condensable gas under high pressure were obtained and an empirical correlation was introduced to calculated to heat transfer coefficient of steam condensation with nitrogen which the calculation results showed great agreement with the experimental data.

scholarly journals Influence of Frost Growth and Migration in Cryogenic Heat Exchanger on Air Refrigerator

2019 ◽  
Vol 9 (4) ◽  
pp. 753 ◽  
Author(s):  
Shanju Yang ◽  
Zhan Liu ◽  
Bao Fu ◽  
Yu Chen
Keyword(s):  
Mass Transfer ◽  
Heat Exchanger ◽  
Numerical Model ◽  
Heat And Mass Transfer ◽  
Frost Formation ◽  
Transient Model ◽  
Transfer Rates ◽  
Low Humidity ◽  
And Migration ◽  
Frost Layer

Frost formation degrades the performance of heat exchangers greatly, thus influencing the cryogenic refrigerator. Different from frost formation on the evaporator surface, the growth and migration of frost layer inside the heat exchanger is of low temperature and humidity. In addition to the constantly changing boundary conditions, the effective prediction is difficult. In the present study, a numerical model was proposed to analyze the frost formation in the cryogenic heat exchanger of a reverse Brayton air refrigerator. Under small amounts of moisture, the growing of frost layer was simulated through the numerical heat and mass transfer by adopting semiempirical correlations. The frost formation model was inserted into the transient model of refrigerator, and numerical calculations were performed on heat and mass transfer rates, and growth and migration of frost layers in forced convection conditions. Experiments were conducted under different air humidity to investigate the frost formation and verify the numerical model. Through the model, the influences of frosting on the refrigerator were evaluated under different moisture contents and running time. It can be used to predict the performance of air refrigerators with low humidity and provide a basis for improving the system operation and efficiency.

Heat and mass transfer in commercial desorbers with a heating surface in the form of a vertical tube bundle and a thermofluidized heat-carrier bed

1986 ◽  
Vol 50 (5) ◽  
pp. 549-553
Author(s):  
A. P. Nesenchuk ◽  
A. M. Gabri�l' ◽  
E. N. Antonishina ◽  
V. A. Sednin ◽  
A. A. Sklyar ◽  
...  
Keyword(s):  
Mass Transfer ◽  
Heat And Mass Transfer ◽  
Heat Carrier ◽  
Tube Bundle ◽  
Heating Surface ◽  
Vertical Tube
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