Heat and mass transfer phenomena during the early growth of a catalyst particle in gas-phase olefin polymerization : the effect of prepolymerization temperature and time

2001 ◽  
Vol 56 (13) ◽  
pp. 3979-3995 ◽  
Author(s):  
A. Yiagopoulos ◽  
H. Yiannoulakis ◽  
V. Dimos ◽  
C. Kiparissides
1987 ◽  
Vol 109 (2) ◽  
pp. 89-93 ◽  
Author(s):  
P. Gandhidasan ◽  
M. Rifat Ullah ◽  
C. F. Kettleborough

Heat and mass transfer analysis between a desiccant-air contact system in a packed tower has been studied in application to air dehumidification employing liquid desiccant, namely calcium chloride. Ceramic 2 in. Raschig rings are used as the packing material. To predict the tower performance, a steady-state model which considers the heat and mass transfer resistances of the gas phase and the mass transfer resistance of the liquid phase is developed. The governing equations are solved on a digital computer to simulate the performance of the tower. The various parameters such as the effect of liquid concentration and temperature, air temperature and humidity and the rates of flow of air and liquid affecting the tower performance have been discussed.


2011 ◽  
Vol 20 (2) ◽  
pp. 192-200 ◽  
Author(s):  
M. M. Grigoryeva ◽  
G. V. Kuznetsov ◽  
P. A. Strizhak

Author(s):  
Jian-Hong Liu ◽  
Fu-Min Shang ◽  
Nikolay Efimov

Abstract Numerical simulation was performed to establishing a two-dimensional pulsating heat pipe model, to investigate the flow and heat transfer characteristics in the pulsating heat pipe by using the Mixture and Euler models, which were unsteady models of vapor-liquid two-phase, based on the control-volume numerical procedure utilizing the semi-implicit method. Through comparing and analyzing the volume fraction and velocity magnitude of gas phase to decide which model was more suitable for numerical simulation of the pulsating heat pipe in heat and mass transfer research. It was showed there had gas phase forming in stable circulation flow in the heating section, the adiabatic section using the Mixture and Euler models respectively, and they were all in a fluctuating state at 10s, besides, the pulsating heat pipe had been starting up at 1s and stabilizing at 5s, it was all found that small bubbles in the heat pipe coalescing into large bubbles and gradually forming into liquid plugs and gas columns from the contours of volume fraction of the gas phase; through comparing the contours of gas phase velocity, it could be seen that there had further stably oscillating flow and relatively stabler gas-liquid two-phase running speed in the pulsating heat pipe used the Mixture model, the result was consistent with the conclusion of the paper[11] extremely, from this it could conclude that the Mixture model could be better simulate the vaporization-condensation process in the pulsating heat pipe, which could provide an effective theoretical support for further understanding and studying the phase change heat and mass transfer mechanism of the pulsating heat pipe.


Author(s):  
Hedvig Paradis ◽  
Martin Andersson ◽  
Jinliang Yuan ◽  
Bengt Sunde´n

The transport processes in the porous, micro-structured electrodes are one of the least understood areas of research of the solid oxide fuel cell (SOFC). To enhance the knowledge of the transport process’ impact on the performance in the electrodes, the micro-structure needs to be modeled in detail. But at these smaller scales, it can be both cost and time saving to first conclude at which scales, the limiting action on the transport processes occurs. This study investigates the limiting effect of the kinetic parameters’ on the heat and mass transfer at interparticle, interphase and intraparticle transport level. The internal reaction and the electrochemical reaction rates are studied at three levels in the microscopic range or even smaller. At the intraparticle level the effect of temperature distribution, i.e., heat transfer, within a catalyst particle is often less limiting than the internal mass diffusion process, while at the interphase level the former is more limiting. In this study, no severe risk for transport limitations for the anode and the cathode of the SOFC was found with the chosen kinetic parameters. It was found that the reaction rates constitute the largest risk. A parameter study was conducted by increasing the steam reforming and the electrochemical reaction rates by a factor of 100 without any transport limitations for the same kinetic parameters. The result of this study provides one type of control of the kinetic parameters which in turn have an impact on the reforming reaction rates and the cell performance.


Sign in / Sign up

Export Citation Format

Share Document