Removal of chlorinated phenols in upflow anaerobic sludge blanket reactors

1998 ◽  
Vol 38 (8-9) ◽  
Keyword(s):  
Upflow Anaerobic Sludge Blanket ◽  
Anaerobic Sludge ◽  
Chlorinated Phenols ◽  
Anaerobic Sludge Blanket

Degradation of chlorinated aromatic compounds in UASB reactors

1995 ◽  
Vol 31 (1) ◽  
pp. 249-259 ◽  
Author(s):  
Nina Christiansen ◽  
Hanne V. Hendriksen ◽  
Kimmo T. Järvinen ◽  
Birgitte K. Ahring
Keyword(s):  
Metabolic Pathways ◽  
Granular Sludge ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Ring Cleavage ◽  
Anaerobic Sludge ◽  
Chlorinated Phenols ◽  
Desulfomonile Tiedjei ◽  
Anaerobic Sludge Blanket ◽  
Uasb Reactors

Data on anaerobic degradation of chloroaromatic compounds in Upflow Anaerobic Sludge Blanket Reactors (UASB-reactor) are presented and compared. Special attention is given to the metabolic pathways for degradation of chlorinated phenols by granular sludge. Results indicate that PCP can be degraded in UASB-reactors via stepwise dechlorination to phenol. Phenol will subsequently be converted to benzoate before ring cleavage. Dechlorination proceeds via different pathways dependent upon the inocula used. Results are further presented on the design of special metabolic pathways in granules which do not possess this activity using the dechlorinating organism, Desulfomonile tiedjei. Additionally, it is shown that it is possible to immobilize Dechlorosporium hafniense, a newly isolated dechlorinating anaerobe, into granular sludge, thereby introducing an ability not previously present in the granules.

Modeling simultaneous removal of primary substrates and chlorinated phenols in upflow anaerobic sludge blanket reactors

2001 ◽  
Vol 28 (6) ◽  
pp. 910-921 ◽  
Author(s):  
K J Kennedy ◽  
Z Ning ◽  
L Fernandes
Keyword(s):  
Dynamic Model ◽  
Model Development ◽  
Oxygen Demand ◽  
Upflow Anaerobic Sludge Blanket ◽  
Organic Loading Rate ◽  
Anaerobic Sludge ◽  
Chlorinated Phenols ◽  
Degradation Rates ◽  
Anaerobic Sludge Blanket ◽  
Uasb Reactors

A dynamic model describing the simultaneous degradation of easily degradable substrates (sucrose and acetic acid (HAc)) and 2,4-dichlorophenol (2,4-DCP) in upflow anaerobic sludge blanket (UASB) reactors was developed. The two critical factors considered in the model development were sorption and substrate interaction during degradation. Data obtained from experiments on the multiple substrate degradation in continuous UASB reactors were used to validate and verify the dynamic model. The model predicts the system responses for 2,4-DCP, 4-monochlorophenol (4-MCP), HAc, propionic acid (HPr), and chemical oxygen demand (COD) concentration in the effluent. The modeling results indicated that the degradation rates for 2,4-DCP and for cosubstrates, HAc and HPr, changed inversely as a function of the specific organic loading rate for UASB reactors.Key words: dynamic, modeling, UASB, 2,4-dichlorophenol, sorption, degradation, co-metablism.

Removal of chlorinated phenols in upflow anaerobic sludge blanket reactors

1998 ◽  
Vol 38 (8-9) ◽  
pp. 359-367 ◽  
Author(s):  
Ronald L. Droste ◽  
Kevin J. Kennedy ◽  
Jingua Lu ◽  
Mercedes Lentz
Keyword(s):  
Acetic Acid ◽  
Upflow Anaerobic Sludge Blanket ◽  
Synthetic Wastewater ◽  
Anaerobic Sludge ◽  
Chlorinated Phenols ◽  
Reactor Performance ◽  
Chlorine Atoms ◽  
Toxic Agents ◽  
Anaerobic Sludge Blanket ◽  
Uasb Reactors

The dechlorination of chlorophenol (CP) compounds was investigated using upflow anaerobic sludge blanket reactors. A total of five trichlorophenols (TCPs) and a single dichlorophenol (DCP) were individually treated: 2,3,4-TCP; 2,3,5-TCP; 2,3,6-TCP; 2,4,5-TCP; 2,4,6-TCP; and 3,5-DCP. Synthetic wastewater composed of sucrose and acetic acid provided an alternate, readily biodegradable carbon source. Each chlorinated compound was concurrently fed to separate reactors. The parameters that were quantified include biogas composition, acetic acid concentration, COD, and VSS. The degree to which CPs were sorbed to the granular biomass in actively dechlorinating UASB reactors was found to be insignificant. CP compounds were able to be metabolized to mineral end products to a large extent at loadings where reactor performance was not impaired. Ortho chlorine atoms were most readily removed from CPs. CPs containing chlorine atoms in the para position were the most toxic agents with 2,4,5-TCP being the most toxic compound. Toxicity was reversible.

Pemodelan Reaktor Hibrid Anaerob Pengolah Molasse Pada Pembebanan Organik Tinggi

2020 ◽  
Author(s):  
Gede H Cahyana
Keyword(s):  
Fluidized Bed ◽  
Fixed Bed ◽  
High Rate ◽  
Upflow Anaerobic Sludge Blanket ◽  
Anaerobic Sludge ◽  
Expanded Bed ◽  
Anaerobic Sludge Blanket

Telah dikembangkan reaktor anaerob kecepatan tinggi (high rate) yang merupakan modifikasi reaktor konvensional. Di antaranya berupa (bio)reaktor pertumbuhan tersuspensi (contoh: UASB, Upflow Anaerobic Sludge Blanket) dan reaktor pertumbuhan lekat (Fixed Bed atau Biofilter, Fluidized Bed, Expanded Bed, Rotating Biodisc dan Baffled Reactor). Kedua tipe reaktor di atas memiliki sejumlah kelebihan dan kekurangan. Untuk mengoptimalkan nilai positifnya (terutama untuk keperluan desain) maka reaktor tersebut, pada penelitian ini, disusun menjadi satu urutan yang disebut Reaktor Hibrid Anaerob (Rehan) yakni UASB di bawah dan AF di atasnya. Lebih lanjut, penelitian ini diharapkan dapat memberikan informasi tentang kinerja Rehan dalam mengolah air limbah (substrat) yang konsentrasi zat organiknya (COD) sangat tinggi dan suatu model matematika yang dapat mewakili reaktor tersebut.

The treatment of iron oxalate leach liquors in a UASB with sulfate reduction

1997 ◽  
Vol 36 (6-7) ◽  
pp. 383-390 ◽  
Author(s):  
J. E. Teer ◽  
D. J. Leak ◽  
A. W. L. Dudeney ◽  
A. Narayanan ◽  
D. C. Stuckey
Keyword(s):  
Bacterial Species ◽  
Upflow Anaerobic Sludge Blanket ◽  
Anaerobic Sludge ◽  
Desulfovibrio Vulgaris ◽  
Hydrogenotrophic Methanogenesis ◽  
Irreversible Effects ◽  
High Concentrations ◽  
A Minor ◽  
Anaerobic Sludge Blanket ◽  
Reducing Bacteria

The presence of small amounts of iron (>0.013% Fe) in sand creates problems in the manufacture of high quality glass. Removal by hot sulphuric acid is possible, but creates environmental problems, and is costly. Hence organic acids such as oxalic have been investigated since they are effective in removing iron, and can be degraded anaerobically. The aim of this work was to identify key intermediates in the anaerobic degradation of oxalate in an upflow anaerobic sludge blanket reactor (UASB) which was removing iron from solution in the sulphide form, and to determine the bacterial species involved. 2-bromoethanesulfonic acid (BES) and molybdenum were selected as suitable inhibitors for methanogenic and sulphate reducing bacteria (SRB) respectively. 40mM molybdenum was used to inhibit the SRB in a reactor with a 12hr HRT. Total SRB inhibition took place in 20 hrs, with a complete breakthrough of influent sulphate. The lack of an immediate oxalate breakthrough confirmed Desulfovibrio vulgaris subspecies oxamicus was not the predominant oxalate utilising species. Nevertheless, high concentrations of molybdenum were found to inhibit oxalate utilising bacteria in granular reactors but not in suspended population reactors; this observation was puzzling, and at present cannot be explained. Based on the intermediates identified, it was postulated that oxalate was degraded to formate by an oxalate utilising bacteria such as Oxalobacter formigenes, and the formate used by the SRBs to reduce sulphate. Acetate, as a minor intermediate, existed primarily as a source of cell carbon for oxalate utilising bacteria. Methanogenic inhibition identified that 62% of the CH4 in the reactor operated at 37°C originated from hydrogenotrophic methanogenesis, whilst this figure was 80% at 20°C. Possible irreversible effects were recorded with hydrogenotrophic methanogens.

High process activity of a two-phase UASB (upflow anaerobic sludge blanket) receiving ethanol wastewater: Operational conditions in relation to granulation development

2021 ◽  
Vol 148 ◽  
pp. 106012
Author(s):  
Achiraya Jiraprasertwong ◽  
Pattaratorn Karnchanapaisal ◽  
Kessara Seneesrisakul ◽  
Pramoch Rangsunvigit ◽  
Sumaeth Chavadej
Keyword(s):  
Upflow Anaerobic Sludge Blanket ◽  
Anaerobic Sludge ◽  
Two Phase ◽  
Operational Conditions ◽  
Anaerobic Sludge Blanket

scholarly journals Microbial Removal of Pb(II) Using an Upflow Anaerobic Sludge Blanket (UASB) Reactor

Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 512
Author(s):  
Jeremiah Chimhundi ◽  
Carla Hörstmann ◽  
Evans M. N. Chirwa ◽  
Hendrik G. Brink
Keyword(s):  
Treatment Process ◽  
Removal Rate ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Reduction Potentials ◽  
Oxidation Reduction ◽  
Anaerobic Sludge Blanket ◽  
Microbial Removal ◽  
Maximum Removal

The main objective of this study was to achieve the continuous biorecovery and bioreduction of Pb(II) using an industrially obtained consortia as a biocatalyst. An upflow anaerobic sludge blanket reactor was used in the treatment process. The bioremediation technique that was applied made use of a yeast extract as the microbial substrate and Pb(NO3)2 as the source of Pb(II). The UASB reactor exhibited removal efficiencies of between 90 and 100% for the inlet Pb concentrations from 80 to 2000 ppm and a maximum removal rate of 1948.4 mg/(L·d) was measured. XRD and XPS analyses of the precipitate revealed the presence of Pb0, PbO, PbS and PbSO4. Supporting experimental work carried out included growth measurements, pH, oxidation–reduction potentials and nitrate levels.

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