scholarly journals A Low-cost Continuous-flow Gas Interface for Coupling an Elemental Analyzer with a Micadas AMS: gas flow Mathematical Model and first results

Radiocarbon ◽  
2019 ◽  
Vol 61 (6) ◽  
pp. 1795-1804
Author(s):  
Gary Salazar ◽  
Sönke Szidat

ABSTRACTA fully automatic continuous-flow gas injection interface was built to couple an elemental analyzer with a MICADAS accelerator mass spectrometer (AMS) as a low-cost option that does not require an absorber trap for CO2 injection. The complication of the variable ion current during gas injection can be overcome by understanding and controlling the mass flow-dependent ionization yield. The time-varying CO2 concentrations and carbon mass flows are estimated with a mathematical model in order to investigate their relationship with the abundant isotope (12C–) signal. This model is based on a complete CO2 diffusion equation and instantaneous mass flow. It shows a good agreement between model calculations and the measurements. A reversible suppression of the formation of ions occurs, if the carbon mass flow exceeds 2.0–2.3 µg C/min. This result repeats for different injection capillaries and for different carrier volumetric flow rates.

Author(s):  
Paulo R Espindola ◽  
Mariana L Aquino ◽  
Cicero R Cena ◽  
Diego C B Alves ◽  
Diogo D Reis ◽  
...  

In this paper we present a compact and low cost solution to set up and to monitor an electronic Mass Flow Controller (MFC) using an Arduino microcontroller. Usually, MFCs can find a great demand at materials science laboratories, mainly in techniques which requires  a precise gas flow control, such as synthesis of thin films by Chemical Vapor Deposition (CVD). The control unit produced is presented in details by using schematic diagrams of the circuit and a detailed configuration for connect the controller to the MFC are presented. The control unit is also capable to work with two Mass Flow Controllers (MFCs) simultaneously at manual and remote (via computer software) regime. The source code is quite simple and allows the user easily modify parameters as type of gas and flux capacity of the controllers. Although the low resolution of ADC (Analog-to-Digital Converter) (10 bits) and DAC (Digital-to-Analog Converter) (using PWM - “Pulse Width Modulation”, 8 bits), the flux can be adjusted in steps of 0.4 % and 1.5 % of the total flux, respectively, which is very satisfactory for practical purposes. Finally, the operation tests were taken by using Argon (Ar) gas, and great accordance between the set point flow and the MFC measured flow was found.


Author(s):  
Dieter Bohn ◽  
Uwe Krüger ◽  
Klaus Nitsche

The rotor of modern gas turbines often consists of single discs forming air-filled rotating cavities. During stationary operation each disc in the compressor section is of nearly uniform temperature. This results from the radial heat conduction in the disc material and from the negligible axial temperature gradients between surface and air in the adjacent cavities. The situation changes rapidly during cold start-ups of the engine. The disc rims respond quickly to the temperature of the mainstream (500 to 600 K), whereas the average temperature of the massive hub section follows with some delay thus forming a radial thermal gradient. This induces a buoyancy-driven flow inside the cavity, which is superimposed by a controlled hot gas ingress. A defined amount of hot air flows radially inwards through the Hirth-type serration at the head of the discs, causes increased convection within the cavity and speeds up the thermal equilibration process in the discs. Numerical investigations of the very complex flow situation have been carried out to get a better knowledge of both the flow-physics and the heat transfer from the hot fluid to the cold rotating wall. A modern numerical Finite-Volume-Code with multiblock and body-fitted grid-options has been used to calculate three different cases: one cavity without hot gas ingress and two cases with two different mass flow parameters. The boundary conditions have been chosen in such a way that they cover real gas turbine conditions at the very beginning of the start-up. The most stringent case has been investigated, i. e. the head of the discs and the hot gas mass flow having the mainstream temperature while the discs in the hub region remain at ambient temperature. It has been found that in the case without throughflow the core-region rotates approximately with the speed of a solid body. In the case of superimposed hot gas flow directed radially inwards, the flow has the character of a potential-vortex-flow, with exception of the regions near the wall. The hot gas is transported to the hub-region so that the heat transfer in this region is very large in the first period of the start-up-procedure. Some aspects are presented which should be investigated in more detail in future work, especially the 3-D effects and the conjugate heat transfer. First results of a 3-D calculation are shown.


Radiocarbon ◽  
2016 ◽  
Vol 59 (3) ◽  
pp. 921-932 ◽  
Author(s):  
Konstantinos Agrios ◽  
Gary Salazar ◽  
Sönke Szidat

AbstractThis article reports on the performance of a continuous-flow interface for CO2 gas feeding into the ion source of a 200-kV accelerator mass spectrometer (AMS) in splitless mode. Distinct CO2 fractions and subfractions produced by a commercial Sunset OC/EC (organic carbon/elemental carbon) analyzer from ambient atmospheric aerosols filters are injected into the source and then analyzed by their 14C/12C ratio in real time. New features are revealed from organic aerosol subfractions, which thermally desorb close to each other and are only visible by real-time analysis. An optimized setup for this purpose is presented for the measurement of CO2 amounts from 3 to 45 μg C. Efficiencies of 4.5–8.0% for the formation of C- ions from CO2 are obtained for sample masses of 5–10 μg C and carbon mass flow rates below 2 µg min–1. However, this ionization efficiency is substantially suppressed at high carbon mass flow rates. The potential of this method for a refined apportionment of aerosol sources is demonstrated with ambient filter samples.


2002 ◽  
Vol 729 ◽  
Author(s):  
Siyi Lai ◽  
L. James Lee ◽  
Liyong Yu ◽  
Kurt W. Koelling ◽  
Marc J. Madou

AbstractIn this paper, we review the approaches developed in our laboratory for polymer-based micro/nanofabrication. For fabrication of microscale features, UV-LIGA (UV-lithography, electroplating, and molding) technology was applied for low-cost mass production. For fabrication of sub-micron or nanoscale features, a novel nano-manufacturing protocol is being developed. The protocol applies a novel nano-lithography imprinting process on an ultra-precision motion-control station. It is capable of economically producing well-defined pores or channels at the nanometer scale on thin polymer layers. The formed thin layers can be used as nano-filters for chemical or bio-separation. They can also be integrated into miniaturized devices for cell immunoprotection or tissue growth. For bonding of polymer-based microfluidic platforms, a novel resin-gas injection-assisted technique has been developed that achieves both bonding and surface modification. This new approach can easily seal microfluidic devices with micron and sub-micron sized channels without blocking the flow path. It can also be used to modify the channel shape, size, and surface characteristics (e.g., hydrophilicity, degree of protein adsorption). By applying the masking technique, local modification of the channel surface can be achieved through cascade resin-gas injection.


1999 ◽  
Vol 121 (2) ◽  
pp. 96-101 ◽  
Author(s):  
H. Baca ◽  
J. Smith ◽  
A. T. Bourgoyne ◽  
D. E. Nikitopoulos

Results from experiments conducted in downward liquid-gas flows in inclined, eccentric annular pipes, with water and air as the working fluids, are presented. The gas was injected in the middle of the test section length. The operating window, in terms of liquid and gas superficial velocities, within which countercurrent gas flow occurs at two low-dip angles, has been determined experimentally. The countercurrent flow observed was in the slug regime, while the co-current one was stratified. Countercurrent flow fraction and void fraction measurements were carried out at various liquid superficial velocities and gas injection rates and correlated to visual observations through a full-scale transparent test section. Our results indicate that countercurrent flow can be easily generated at small downward dip angles, within the practical range of liquid superficial velocity for drilling operations. Such flow is also favored by low gas injection rates.


1974 ◽  
Vol 14 (01) ◽  
pp. 44-54 ◽  
Author(s):  
Gary W. Rosenwald ◽  
Don W. Green

Abstract This paper presents a mathematical modeling procedure for determining the optimum locations of procedure for determining the optimum locations of wells in an underground reservoir. It is assumed that there is a specified production-demand vs time relationship for the reservoir under study. Several possible sites for new wells are also designated. possible sites for new wells are also designated. The well optimization technique will then select, from among those wellsites available, the locations of a specified number of wells and determine the proper sequencing of flow rates from Those wells so proper sequencing of flow rates from Those wells so that the difference between the production-demand curve and the flow curve actually attained is minimized. The method uses a branch-and-bound mixed-integer program (BBMIP) in conjunction with a mathematical reservoir model. The calculation with the BBMIP is dependent upon the application of superposition to the results from the mathematical reservoir model.This technique is applied to two different types of reservoirs. In the first, it is used for locating wells in a hypothetical groundwater system, which is described by a linear mathematical model. The second application of the method is to a nonlinear problem, a gas storage reservoir. A single-phase problem, a gas storage reservoir. A single-phase gas reservoir mathematical model is used for this purpose. Because of the nonlinearity of gas flow, purpose. Because of the nonlinearity of gas flow, superposition is not strictly applicable and the technique is only approximate. Introduction For many years, members of the petroleum industry and those concerned with groundwater hydrology have been developing mathematical reservoir modeling techniques. Through multiple runs of a reservoir simulator, various production schemes or development possibilities may be evaluated and their relative merits may be considered; i.e., reservoir simulators can be used to "optimize" reservoir development and production. Formal optimization techniques offer potential savings in the time and costs of making reservoir calculations compared with the generally used trial-and-error approach and, under proper conditions, can assure that the calculations will lead to a true optimum.This work is an extension of the application of models to the optimization of reservoir development. Given a reservoir, a designated production demand for the reservoir, and a number of possible sites for wells, the problem is to determine which of those sites would be the best locations for a specified number of new wells so that the production-demand curve is met as closely as possible. Normally, fewer wells are to be drilled than there are sites available. Thus, the question is, given n possible locations, at which of those locations should n wells be drilled, where n is less than n? A second problem, that of determining the optimum relative problem, that of determining the optimum relative flow rates of present and future wells is also considered. The problem is attacked through the simultaneous use of a reservoir simulator and a mixed-integer programming technique.There have been several reported studies concerned with be use of mathematical models to select new wells in gas storage or producing fields. Generally, the approach has been to use a trial-and-error method in which different well locations are assumed. A mathematical model is applied to simulate reservoir behavior under the different postulated conditions, and then the alternatives are postulated conditions, and then the alternatives are compared. Methods that evaluate every potential site have also been considered.Henderson et al. used a trial-and-error procedure with a mathematical model to locate new wells in an existing gas storage reservoir. At the same time they searched for the operational stratagem that would yield the desired withdrawal rates. In the reservoir that they studied, they found that the best results were obtained by locating new wells in the low-deliverability parts of the reservoir, attempting to maximize the distance between wells, and turning the wells on in groups, with the low-delivery wells turned on first.Coats suggested a multiple trial method for determining well locations for a producing field. SPEJ P. 44


Author(s):  
Arup Kumar Biswas ◽  
Wasu Suksuwan ◽  
Khamphe Phoungthong ◽  
Makatar Wae-hayee

Underground Coal Gasification (UCG) is thought to be the most favourable clean coal technology option from geological-engineering-environmental viewpoint (less polluting and high efficiency) for extracting energy from coal without digging it out or burning it on the surface. UCG process requires only injecting oxidizing agent (O2 or air with steam) as raw material, into the buried coal seam, at an effective ratio which regulates the performance of gasification. This study aims to evaluate the influence of equivalent ratio (ER) on the flow and combustion characteristics in a typical half tear-drop shape of UCG cavity which is generally formed during the UCG process. A flow modeling software, Ansys FLUENT is used to construct a 3-D model and to solve problems in the cavity. The boundary conditions are- (i) a mass-flow-inlet passing oxidizer (in this case, air) into the cavity, (ii) a fuel-inlet where the coal volatiles are originated and (iii) a pressure-outlet for flowing the product Syngas out of the cavity. A steady-state simulation has been run using k-? turbulence model. The mass flow rate of air varied according to an equivalent ratio (ER) of 0.16, 0.33, 0.49 and 0.82, while the fuel flow rate was fixed. The optimal condition of ER has been identified through observing flow and combustion characteristics, which looked apparently stable at ER 0.33. In general, the flow circulation mainly takes place around the ash-rubble pile. A high temperature zone is found at the air-releasing point of the injection pipe into the ash-rubble pile. This study could practically be useful to identify one of the vital controlling factors of gasification performance (i.e., ER impact on product gas flow characteristics) which might become a cost-effective solution in advance of commencement of any physical operation.


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