Sourceland controls and dispersal pathways of Holocene muds from boreholes of the Ionian Basin, Calabria, southern Italy

2015 ◽  
Vol 152 (6) ◽  
pp. 957-972 ◽  
Author(s):  
FRANCESCO PERRI ◽  
SALVATORE CRITELLI ◽  
ROCCO DOMINICI ◽  
FRANCESCO MUTO ◽  
MAURIZIO PONTE

AbstractDeep-marine muds were collected from two boreholes (Crati II and Neto VI) along the Ionian Calabrian Basin. The samples from the Crati II and the Neto VI boreholes show a similar mineralogical distribution; the marine muds contain mostly phyllosilicates, quartz, calcite, feldspars and dolomite. Traces of gypsum are present in a few samples. The Neto muds show higher concentrations of carbonates than the Crati muds; these contents are mainly related to recycling of the Neogene–Quaternary carbonate-rich marine deposits of the Crotone Basin, which mostly influences the composition of the Neto muds. The geochemical signatures of the muds mainly reflect a provenance characterized by felsic rocks with a minor, but not negligible, mafic supply. In particular, the hinterland composition of the Crati drainage area is on average more mafic in composition than the Neto drainage area. The higher mafic concentration of the Crati sample muds is probably related to the ophiolitiferous units that are exposed in the Crati drainage basin. The degree of source area weathering was most probably of low–moderate intensity because the Chemical Index of Alteration values for the studied muds range from 67 to 69. Furthermore, the low and constant Al/K and Rb/K ratios suggest low–moderate weathering without important fluctuations in weathering intensity. The Al2O3–TiO2–Zr ternary diagram and the values of the Index of Compositional Variability indicate that both the Neto and Crati muds are first-cycle, compositionally immature sediments, related to a tectonically active (collision) setting such as the Calabria–Peloritani Arc, where chemical weathering plays a minor role.

Author(s):  
Tha Hoang Van ◽  
Shahid Iqbal ◽  
Urszula Czarniecka ◽  
Anna Wysocka ◽  
Pha Phan Dong ◽  
...  

During the Miocene-Pleistocene, generally sub-tropical to tropical warm and humid paleoclimate prevailed in Southeast Asia with a gradual cooling trend. The Truc Thon clay (TTC) mine presents interesting outcrops for sedimentological and provenance analysis. The present study uses results of geological investigation in 16 outcrops and wells at the clay mine Truc Thon. The TTC has lens-shaped geometry, filled with two clay bodies, including grey-white clay and multicolor clay. Bulk mineralogy indicates the predominance of quartz and a relatively high amount of pyrophyllite. Clay mineralogy shows the presence of main kaolinite, followed by illite and mixed-layer illite-smectite. These may interpret a warm, humid paleoclimatic condition in the source areas. Illite may be inherited from basement rocks. The bulk rock geochemistry supports intense chemical weathering with the Chemical Index of Alteration (CIA) in the TTC ranged ca. 80.6-98 (average = 90.4). In combination with the geochemical proxies and the mineralogical composition of the TTC, the chemical weathering intensity indicated warm/hot, semi-humid/humid tropical paleoclimate in the source area. A combination of mineralogical and geochemical analyses with regional geological features show that the Hon Gai Triassic rocks are the main source for the TTC. Source materials are originally related to silicic rocks of granitic-granodioritic composition. Paleoclimatic conditions favored intense chemical weathering of the Hon Gai Triassic rocks and surrounding rocks, creating a ceramic mine of great industrial value.


2020 ◽  
Vol 90 (5) ◽  
pp. 493-512
Author(s):  
Sanne Lorentzen ◽  
Tonje Braut ◽  
Carita Augustsson ◽  
Johan P. Nystuen ◽  
Jens Jahren ◽  
...  

ABSTRACT Lower Cambrian quartz arenite deposits have a world-wide occurrence and are also present on Baltica. However, the processes influencing the deposits from source to sink have not been accordingly investigated. The provenance of these deposits is crucial for the understanding of the extent of chemical weathering in the cratonic drainage area and reworking at the broad shallow shelves of Baltica during early Cambrian time. Provenance analysis and study of weathering effects was done for lower Cambrian sandstone from southern Scandinavia, including southern Norway, southern Sweden, and Bornholm (Denmark). For the quartz-arenite sandstone of the Ringsaker Member and the Hardeberga Formation, predominantly moderately weathered felsic–intermediate plutonic and meta-igneous source terranes are suggested from negative Eu anomalies, high LaN/YbN, and low to moderate Ti/Nb ratios, as well as trace amounts of plutonic lithoclasts. Similarly, a felsic–intermediate igneous and metamorphic signature is indicated in the heavy-mineral assemblage and a dominance of dark cathodoluminescence of quartz in a special study of samples from Bornholm, thus suggesting a mixed provenance of local granitoid–orthogneissic Mesoproterozoic basement and distant sources from the Transscandinavian Igneous Belt for the Hardeberga Formation on Bornholm. High percentages of mostly rounded ultra-stable heavy-mineral grains, quartz, and extremely high SiO2/Al2O3 ratios indicate a compositionally and texturally mature sand that was subjected to extensive to moderate weathering following removal of detritus from the source area. The main controls on the alteration of framework composition and the heavy-mineral assemblage are interpreted as surface weathering, based on moderate Chemical Index of Alteration values and meteoric flushing, and reworking by waves, based on an estimated low amount of feldspar before burial. Thus, the maturation of lower Cambrian quartz arenite on southwestern Baltica can be ascribed to a combination of processes including weathering in the source-rock area, extensive reworking, and early diagenesis. This study also highlights the importance of understanding alteration processes affecting the deposits from source to sink, and to be careful to describe quartz-rich rocks as simply recycled deposits.


1992 ◽  
Vol 129 (2) ◽  
pp. 223-237 ◽  
Author(s):  
Jürgen Schieber

AbstractA provenance study was conducted on the Mid-Proterozoic Newland Formation, in which petrographical features of sandstones and geochemical characteristics of shales were integrated to arrive at an internally consistent interpretation.Sandstones of the Newland Formation are typically arkosic sands and arkoses with very-well-rounded quartz and feldspar grains and only minor amounts of extrabasinal rock fragments. The predominant feldspar types are K-spar and microcline, feldspar grains are smaller than quartz grains, and feldspars show little alteration due to weathering. Detrital modes of Newland sandstones (QFL diagrams) indicate that they were derived from a stable cratonic source. These petrographical features imply a source area dominated by granites and granitoid gneisses, semi-arid to arid climate, tectonic quiescence, and overall peneplain conditions.Shales of the Newland Formation are dominated by illite, quartz silt, and fine crystalline dolomite. They have small La/Th rations, relatively large Hf contents, and small contents of Cr, Co, and Ni, all indicative of derivation from crust of granitic composition. Small Tio2/Al2O3ratios also suggest source rocks of granitic composition. The average chemical index of alteration (CIA) for Newland shales is 71.8, which in light of the probable granitoid source indicates modest amounts of chemical weathering. Relatively large SiO2contents and large K2O/Na2O ratios reflect derivation from stable cratonic areas and tectonic quiescence.Thus, in general, the petrography of sandstones and geochemistry of shales provides the same provenance clues for the Newland Formation. One notable discrepancy between the two approaches is that the sandstones indicate an arid to semi-arid climate with very minor chemical weathering, whereas the CIA of the shales indicates at least modest amounts of chemical weathering. This indicates on one hand the need to better calibrate the CIA with a large variety of muds from modern climatic settings, and on the other hand the possibility that this discrepancy is due to transport segregation.


2012 ◽  
Vol 63 (5) ◽  
pp. 365-382 ◽  
Author(s):  
Slavomír Nehyba ◽  
Reinhard Roetzel ◽  
Lubomír Maštera

Abstract The provenance analyses of Permo-Carboniferous fluvial sandstones of the southern part of the Boskovice Basin and the Zöbing area are based on a wide spectrum of analytical techniques (petrography, heavy mineral assemblages, chemistry of garnet, rutile and spinel, zircon study, major and trace elements). The studied sandstones are poorly sorted and reveal a relatively immature composition implying short distance transport, rapid deposition, a high-relief source area, mainly physical weathering and the minor role of chemical weathering. Different source areas for the Boskovice Basin and the Zöbing area were proved. The Zöbing material was predominantly derived from crystalline units, mainly formed by metamorphic complexes, although the portions of magmatic and volcanic material were significant. The source area is supposed to be located in the Moldanubian Unit. The Boskovice Basin deposits, on the other hand, seem to be mainly derived from metamorphic complexes, corresponding especially to the Moravian Unit, with a relatively wider spectrum of metamorphites, together with the derivation of the detritus from pre-existing sedimentary rocks (especially from Moravo- Silesian Paleozoic deposits/Drahany Culm unit). The transport direction in the basin was more complex, both from the west and east. These results did not confirm the possibility of communication between the Boskovice Basin and the Zöbing area during the Late Paleozoic. The existence of “colinear” marginally offset half grabens with predominant transversal sources is here hypothesized. The general heavy mineral evolution in time does not indicate the successive exhumation of a simple structured orogen but may be interpreted as differences in the extent of the source areas.


Author(s):  
Katherine Guérard ◽  
Sébastien Tremblay

In serial memory for spatial information, some studies showed that recall performance suffers when the distance between successive locations increases relatively to the size of the display in which they are presented (the path length effect; e.g., Parmentier et al., 2005) but not when distance is increased by enlarging the size of the display (e.g., Smyth & Scholey, 1994). In the present study, we examined the effect of varying the absolute and relative distance between to-be-remembered items on memory for spatial information. We manipulated path length using small (15″) and large (64″) screens within the same design. In two experiments, we showed that distance was disruptive mainly when it is varied relatively to a fixed reference frame, though increasing the size of the display also had a small deleterious effect on recall. The insertion of a retention interval did not influence these effects, suggesting that rehearsal plays a minor role in mediating the effects of distance on serial spatial memory. We discuss the potential role of perceptual organization in light of the pattern of results.


1958 ◽  
Vol 02 (05/06) ◽  
pp. 462-480 ◽  
Author(s):  
Marc Verstraete ◽  
Patricia A. Clark ◽  
Irving S. Wright

SummaryAn analysis of the results of prothrombin time tests with different types of thromboplastins sheds some light on the problem why the administration of coumarin is difficult to standardize in different centers. Our present ideas on the subject, based on experimental data may be summarized as follows.Several factors of the clotting mechanism are influenced by coumarin derivatives. The action of some of these factors is by-passed in the 1-stage prothrombin time test. The decrease of the prothrombin and factor VII levels may be evaluated in the 1-stage prothrombin time determination (Quick-test). The prolongation of the prothrombin times are, however, predominantly due to the decrease of factor VII activity, the prothrombin content remaining around 50 per cent of normal during an adequate anticoagulant therapy. It is unlikely that this degree of depression of prothrombin is of major significance in interfering with the coagulation mechanism in the protection against thromboembolism. It may, however, play a minor role, which has yet to be evaluated quantitatively. An exact evaluation of factor VII is, therefore, important for the guidance of anticoagulant therapy and the method of choice is the one which is most sensitive to changes in factor VII concentration. The 1-stage prothrombin time test with a rabbit lung thromboplastin seems the most suitable method because rabbit brain preparations exhibit a factor VII-like activity that is not present in rabbit lung preparations.


2016 ◽  
Vol 46 (185) ◽  
pp. 621-638 ◽  
Author(s):  
Christian Siefkes

The ‘Fragment on Machines’ from Marx’s Grundrisse is often cited as an argument that the internal forces of capitalism will lead to its doom. But the argument that the progressive reduction of labor must doom capitalism lacks a proper foundation, as a comparison with the ‘Schemes of Reproduction’ given in Capital II shows. The latter, however, aren’t fully convincing either. In reality, more depends on the private consumption of capitalists than either model recognizes. Ultimately, most can be made of the ‘Fragment on Machines’ by reading it not as an exposure of capitalism’s internal contractions, but as a discussion of a possible communist future where labor (or work) will play but a minor role.


2019 ◽  
Vol 12 (4) ◽  
pp. 311-323 ◽  
Author(s):  
Salvatore Benvenga ◽  
Antonio Micali ◽  
Giovanni Pallio ◽  
Roberto Vita ◽  
Consuelo Malta ◽  
...  

Background: Cadmium (Cd) impairs gametogenesis and damages the blood-testis barrier. Objective: As the primary mechanism of Cd-induced damage is oxidative stress, the effects of two natural antioxidants, myo-inositol (MI) and seleno-L-methionine (Se), were evaluated in mice testes. Methods: Eighty-four male C57 BL/6J mice were divided into twelve groups: 0.9% NaCl (vehicle; 1 ml/kg/day i.p.); Se (0.2 mg/kg/day per os); Se (0.4 mg/kg/day per os); MI (360 mg/kg/day per os); MI plus Se (0.2 mg/kg/day); MI plus Se (0.4 mg/kg/day); CdCl2 (2 mg/kg/day i.p.) plus vehicle; CdCl2 plus MI; CdCl2 plus Se (0.2 mg/kg/day); CdCl2 plus Se (0.4 mg/kg/day); CdCl2 plus MI plus Se (0.2 mg/kg/day); and CdCl2 plus MI plus Se (0.4 mg/kg/day). After 14 days, testes were processed for biochemical, structural and immunohistochemical analyses. Results: CdCl2 increased iNOS and TNF-α expression and Malondialdehyde (MDA) levels, lowered glutathione (GSH) and testosterone, induced testicular lesions, and almost eliminated claudin-11 immunoreactivity. Se administration at 0.2 or 0.4 mg/kg significantly reduced iNOS and TNF-α expression, maintained GSH, MDA and testosterone levels, structural changes and low claudin-11 immunoreactivity. MI alone or associated with Se at 0.2 or 0.4 mg/kg significantly reduced iNOS and TNF-α expression and MDA levels, increased GSH and testosterone levels, ameliorated structural organization and increased claudin-11 patches number. Conclusion: We demonstrated a protective effect of MI, a minor role of Se and an evident positive role of the association between MI and Se on Cd-induced damages of the testis. MI alone or associated with Se might protect testes in subjects exposed to toxicants, at least to those with behavior similar to Cd.


1985 ◽  
Vol 50 (3) ◽  
pp. 581-599 ◽  
Author(s):  
Petr Vaňura ◽  
Emanuel Makrlík

Extraction of microamounts of Sr2+ and Ba2+ (henceforth M2+) from the aqueous solutions of perchloric acid (0.0125-1.02 mol/l) by means of the nitrobenzene solutions of dicarbolide (0.004-0.05 mol/l of H+{Co(C2B9H11)2}-) was studied in the presence of monoglyme (only Ba2+), diglyme, triglyme, and tetraglyme (CH3O-(CH2-CH2O)nCH3, where n = 1, 2, 3, 4). The distribution of glyme betweeen the aqueous and organic phases, the extraction of the protonized glyme molecule HL+ together with the extraction of M2+ ion and of the glyme complex with the M2+ ion, i.e., ML2+ (where L is the molecule of glyme), were found to be the dominating reactions in the systems under study. In the systems with tri- and tetraglymes the extraction of H+ and M2+ ions solvated with two glyme molecules, i.e., the formation of HL2+ and ML22+ species, can probably play a minor role. The values of the respective equilibrium constants, of the stability constants of complexes formed in the organic phase, and the theoretical separation factors αBa/Sr were determined. The effect of the ligand structure on the values of extraction and stability constants in the organic phase is discussed.


1991 ◽  
Vol 113 (4) ◽  
pp. 731-741 ◽  
Author(s):  
S H Hansen ◽  
K Sandvig ◽  
B van Deurs

The transfer of molecules from the cell surface to the early endosomes is mediated by preendosomal vesicles. These vesicles, which have pinched off completely from the plasma membrane but not yet fused with endosomes, form the earliest compartment along the endocytic route. Using a new assay to distinguish between free and cell surface connected vesicle profiles, we have characterized the preedosomal compartment ultrastructurally. Our basic experimental setup was labeling of the entire cell surface at 4 degrees C with Con A-gold, warming of the cells to 37 degrees C to allow endocytosis, followed by replacing incubation medium with fixative, all within either 30 or 60 s. Then the fixed cells were incubated with anti-Con A-HRP to distinguish truly free (gold labeled) endocytic vesicles from surface-connected structures. Finally, analysis of thin (20-30 nm) serial sections and quantification of vesicle diameters were carried out. Based on this approach it is shown that the preendosomal compartment comprises both clathrin-coated and non-coated endocytic vesicles with approximately the same frequency but with distinct diameter distributions, the average noncoated vesicle being smaller (95 nm) than the average coated one (110 nm). In parallel experiments, using an anti-transferrin receptor gold-conjugate as a specific marker for clathrin-dependent endocytosis it is also shown that uncoating of coated vesicles plays only a minor role for the total frequency of noncoated vesicles. Furthermore, after perturbation of clathrin-dependent endocytosis by potassium depletion where uptake of transferrin is blocked, noncoated endocytic vesicles with Con A-gold, but not coated vesicles, exist already after 30 and 60 s. Finally, it is shown that the existence of small, free vesicles in the short-time experiments cannot be ascribed to recycling from the early endosomes.


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