An experiment to measure the recombination rate of oxygen

1963 ◽  
Vol 15 (4) ◽  
pp. 497-512 ◽  
Author(s):  
J. Wilson

The feasibility of an experiment to measure the recombination rate of oxygen is examined using the ideal-dissociating-gas model. The experiment is to be performed in a shock tube, the shock-heated (and dissociated) gas being cooled by passing it through a Prandtl-Meyer expansion, and then allowed to recombine in a constant-area channel. At appropriate densities and shock Mach numbers it is found that recombination takes place in a distance suitable for a laboratory experiment.Using this technique, the recombination rate of oxygen has been measured at 2700 ˚K. To determine the recombination rate, the absorption of ultraviolet light at a wavelength of 2283 å measured 11 cm downstream of the expansion was compared with absorptions calculated for various values of the recombination rate constant.The measured value of the recombination rate constant of oxygen is in agreement with values calculated from dissociation rate measurements.

1976 ◽  
Vol 31 (12) ◽  
pp. 1489-1499
Author(s):  
E. Czuchaj

Abstract A new approach to the calculation of a teratomic recombination rate constant k(T) has been dem-onstrated. An expression for k(T) has been obtained in the eikonal approximation. The numerical calculation has been carried out for the Rb*-Xe system. Good agreement in the order of magnitude between the present results and the experimental data of Carrington et al. has been obtained.


1990 ◽  
Vol 59 (1) ◽  
pp. 56-65 ◽  
Author(s):  
Kazuyo Kaneko ◽  
Jun-ichi Takimoto ◽  
Yoshiyuki Usami ◽  
Kazuo Kitahara

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