On the ability of drops or bubbles to stick to non-horizontal surfaces of solids

1983 ◽  
Vol 137 ◽  
pp. 1-29 ◽  
Author(s):  
E. B. Dussan V. ◽  
Robert Tao-Ping Chow
Keyword(s):  
Contact Angle ◽  
Solid Surface ◽  
Contact Line ◽  
Common Knowledge ◽  
Contact Angle Hysteresis ◽  
Point Of View ◽  
Fluid Interface ◽  
Mathematical Point

It is common knowledge that relatively small drops or bubbles have a tendency to stick to the surfaces of solids. Two specific problems are investigated: the shape of the largest drop or bubble that can remain attached to an inclined solid surface; and the shape and speed at which it moves along the surface when these conditions are exceeded. The slope of the fluid-fluid interface relative to the surface of the solid is assumed to be small, making it possible to obtain results using analytic techniques. It is shown that from both a physical and mathematical point of view contact-angle hysteresis, i.e. the ability of the position of the contact line to remain fixed as long as the value of the contact angle θ lies within the interval θR [les ] θ [les ] θA, where θA [nequiv ] θR, emerges as the single most important characteristic of the system.

Anomalous Contact Angle Hysteresis of a Captive Bubble: Advancing Contact Line Pinning

Langmuir ◽  
2011 ◽  
Vol 27 (11) ◽  
pp. 6890-6896 ◽  
Author(s):  
Siang-Jie Hong ◽  
Feng-Ming Chang ◽  
Tung-He Chou ◽  
Seong Heng Chan ◽  
Yu-Jane Sheng ◽  
...  
Keyword(s):  
Contact Angle ◽  
Contact Line ◽  
Contact Angle Hysteresis ◽  
Contact Line Pinning

Simulation of Spreading Dynamics of a EWOD Droplet With Dynamic Contact Angle and Contact Angle Hysteresis

2009 ◽  
Author(s):  
Fangjun Hong ◽  
Ping Cheng ◽  
Zhen Sun ◽  
Huiying Wu
Keyword(s):  
Contact Angle ◽  
Contact Line ◽  
Low Voltage ◽  
Contact Angle Hysteresis ◽  
Dynamic Contact Angle ◽  
Dynamic Contact ◽  
Dielectric Surface ◽  
Contact Radius ◽  
Droplet Spreading ◽  
Spreading Dynamics

In this paper, the electrowetting dynamics of a droplet on a dielectric surface was investigated numerically by a mathematical model including dynamic contact angle and contact angle hysteresis. The fluid flow is described by laminar N-S equation, the free surface of the droplet is modeled by the Volume of Fluid (VOF) method, and the electrowetting force is incorporated by exerting an electrical force on the cells at the contact line. The Kilster’s model that can deal with both receding and advancing contact angle is adopted. Numerical results indicate that there is overshooting and oscillation of contact radius in droplet spreading process before it ceases the movement when the excitation voltage is high; while the overshooting is not observed for low voltage. The explanation for the contact line overshooting and some special characteristics of variation of contact radius with time were also conducted.

scholarly journals Hybrid Modification of Unsaturated Polyester Resins to Obtain Hydro- and Icephobic Properties

Processes ◽  
2020 ◽  
Vol 8 (12) ◽  
pp. 1635
Author(s):  
Rafał Kozera ◽  
Bartłomiej Przybyszewski ◽  
Katarzyna Żołyńska ◽  
Anna Boczkowska ◽  
Bogna Sztorch ◽  
...  
Keyword(s):  
Contact Angle ◽  
Composite Structures ◽  
Unsaturated Polyester ◽  
Contact Angle Hysteresis ◽  
Point Of View ◽  
Polyhedral Oligomeric Silsesquioxanes ◽  
Adhesion Forces ◽  
Ice Accumulation ◽  
Hybrid Modification ◽  
Ice Adhesion

Ice accumulation is a key and unsolved problem for many composite structures with polymer matrices, e.g., wind turbines and airplanes. One of the solutions to avoid icing is to use anti-icing coatings. In recent years, the influence of hydrophobicity of a surface on its icephobic properties has been studied. This solution is based on the idea that a material with poor wettability maximally reduces the contact time between a cooled drop of water and the surface, consequently prevents the formation of ice, and decreases its adhesion to the surface. In this work, a hybrid modification of a gelcoat based on unsaturated polyester resin with nanosilica and chemical modifiers from the group of triple functionalized polyhedral oligomeric silsesquioxanes (POSS) and double organofunctionalized polysiloxanes (generally called multi-functionalized organosilicon compounds (MFSC)) was applied. The work describes how the change of modifier concentration and its structural structure finally influences the ice phobic properties. The modifiers used in their structure groups lowered the free surface energy and crosslinking groups with the applied resin, lowering the phenomena of migration and removing the modifier from the surface layer of gelcoat. The main studies from the icephobicity point of view were the measurements of ice adhesion forces between modified materials and ice. The tests were based on the measurements of the shear strength between the ice layer and the modified surface and were conducted using a tensile machine. Hydrophobic properties of the obtained nanocomposites were determined by measurement of the contact angle and contact angle hysteresis. As the results of the work, it was found that the modification of gelcoat with nanosilica and multi-functionalized silicone compounds results in the improvement of icephobic properties when compared to unmodified gelcoat while no direct influence of wettability properties was found. Ice adhesion decreased by more than 30%.

Understanding contact angle hysteresis on an ambient solid surface

2016 ◽  
Vol 93 (5) ◽  
Author(s):  
Yong Jian Wang ◽  
Shuo Guo ◽  
Hsuan-Yi Chen ◽  
Penger Tong
Keyword(s):  
Contact Angle ◽  
Solid Surface ◽  
Contact Angle Hysteresis

Shear flow over a liquid drop adhering to a solid surface

1996 ◽  
Vol 307 ◽  
pp. 167-190 ◽  
Author(s):  
Xiaofan Li ◽  
C. Pozrikidis
Keyword(s):  
Contact Angle ◽  
Shear Flow ◽  
Contact Line ◽  
Simple Shear ◽  
Liquid Drop ◽  
Contact Angle Hysteresis ◽  
Boundary Integral ◽  
Simple Shear Flow ◽  
Contact Lines ◽  
Transient Deformation

The hydrostatic shape, transient deformation, and asymptotic shape of a small liquid drop with uniform surface tension adhering to a planar wall subject to an overpassing simple shear flow are studied under conditions of Stokes flow. The effects of gravity are considered to be negligible, and the contact line is assumed to have a stationary circular or elliptical shape. In the absence of shear flow, the drop assumes a hydrostatic shape with constant mean curvature. Families of hydrostatic shapes, parameterized by the drop volume and aspect ratio of the contact line, are computed using an iterative finite-difference method. The results illustrate the effect of the shape of the contact line on the distribution of the contact angle around the base, and are discussed with reference to contact-angle hysteresis and stability of stationary shapes. The transient deformation of a drop whose viscosity is equal to that of the ambient fluid, subject to a suddenly applied simple shear flow, is computed for a range of capillary numbers using a boundary-integral method that incorporates global parameterization of the interface and interfacial regriding at large deformations. Critical capillary numbers above which the drop exhibits continued deformation, or the contact angle increases beyond or decreases below the limits tolerated by contact angle hysteresis are established. It is shown that the geometry of the contact line plays an important role in the transient and asymptotic behaviour at long times, quantified in terms of the critical capillary numbers for continued elongation. Drops with elliptical contact lines are likely to dislodge or break off before drops with circular contact lines. The numerical results validate the assumptions of lubrication theory for flat drops, even in cases where the height of the drop is equal to one fifth the radius of the contact line.

scholarly journals The Possibility of Changing the Wettability of Material Surface by Adjusting Gravity

Research ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-11 ◽  
Author(s):  
Yong-Ming Liu ◽  
Zi-Qing Wu ◽  
Sheng Bao ◽  
Wei-Hong Guo ◽  
Da-Wei Li ◽  
...  
Keyword(s):  
Contact Angle ◽  
Solid Surface ◽  
Contact Region ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Angle Measurement ◽  
Measured Parameter ◽  
Material Surface ◽  
Vapor Interface ◽  
Liquid Vapor

The contact angle, as a vital measured parameter of wettability of material surface, has long been in dispute whether it is affected by gravity. Herein, we measured the advancing and receding contact angles on extremely low contact angle hysteresis surfaces under different gravities (1-8G) and found that both of them decrease with the increase of the gravity. The underlying mechanism is revealed to be the contact angle hysteresis and the deformation of the liquid-vapor interface away from the solid surface caused by gradient distribution of the hydrostatic pressure. The real contact angle is not affected by gravity and cannot measured by an optical method. The measured apparent contact angles are angles of inclination of the liquid-vapor interface away from the solid surface. Furthermore, a new equation is proposed based on the balance of forces acting on the three-phase contact region, which quantitatively reveals the relation of the apparent contact angle with the interfacial tensions and gravity. This finding can provide new horizons for solving the debate on whether gravity affects the contact angle and may be useful for the accurate measurement of the contact angle and the development of a new contact angle measurement system.

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