Degradation of cellulose with high voltage electrons
As part of a larger study of the degradation of polymers, cotton cellulose is being intentionally degraded with high voltage electrons. The initial results were reported earlier (1). Because of the implications of this study to the electron microscopy of beam sensitive materials, special attention is being given to relating these studies to electron microscopy.Generally, the microscopist's main, and perhaps only, information on specimen degradation is that provided by diminution of the electron diffraction pattern. It will be shown in this paper that even though specimen diffraction patterns are only slightly altered, the mechanical and chemical properties are vastly changed.To produce degraded fabrics having strength losses of 75% or more, cotton fabrics were exposed to radiation doses of 50 and 100 Mrad at 550 kV in an electron accelerator manufactured by High Voltage Engineering Corporation. Properties of such cotton fabrics before (i.e., control) and after exposure to 50 and 100 Mrad dosages are presented in Table I.