ALCHEMI studies on the location of zinc in GaAs

Author(s):  
K. K. Christenson ◽  
J.A. Eades

The diffusion of Zn in GaAs is anomalous in that the diffusion coefficient D is proportional to the Zn concentration squared. Further, the diffusion rate of the column III species in III-V layer structures (ie. Ga and Al in GaAs-GaAlAs) can be increased by 105 with the addition of doping levels of Zn3. The column V sites are not affected. As an aid to understanding the diffusion process we have located the position of the Zn in the GaAs lattice.There are four high symmetry positions in the zincblende structure that the Zn could occupy: Ga, As, T (Tetrahedral interstitial, located at 1/2 1/2 1/2 with four nearest neighbors at 0.433 a0) and H (Hexagonal interstitial, located at 5/8 5/8 5/8 with six nearest neighbors at 0.415 a0). Interstitial diffusion involves hopping between alternating T and H sites with the energy barrier to diffusion being equivalent to the difference in the potential energy of the two sites. Figure 1 indicates the possible low-index orientations for ALCHEMI studies which can differentiate between these sites.

1987 ◽  
Vol 92 ◽  
Author(s):  
A. Usami ◽  
Y. Tokuda ◽  
H. Shiraki ◽  
H. Ueda ◽  
T. Wada ◽  
...  

ABSTRACTRapid thermal processing using halogen lamps was applied to the diffusion of Zn into GaAs0.6 P0.4:Te from Zn-doped oxide films. The Zn diffusion coefficient of the rapid thermal diffused (RTD) samples at 800°C for 6 s was about two orders of magnitude higher than that of the conventional furnace diffused samples at 800°C for 60 min. The enhanced diffusion of Zn by RTD may be ascribed to the stress field due to the difference in the thermal expansion coefficient between the doped oxide films and GaAs0.6P0.4 materials, and due to the temperature gradient in GaAs0.6P0 4 materials. The Zn diffusion coefficient at Zn concentration of 1.0 × l018 cm−3 was 3.6 × 10−11, 3.1 × 10−11 and 5.0 × 10−12 cm2 /s for the RTD samples at 950°C for 6 s from Zn-, (Zn,Ga)- and (Zn,P)-doped oxide films, respectively. This suggests that Zn diffusibility was controlled by the P in the doped oxide films.


2011 ◽  
Vol 25 (21) ◽  
pp. 1749-1760 ◽  
Author(s):  
Y. LACHTIOUI ◽  
M. MAZROUI ◽  
Y. BOUGHALEB

This study deals with the investigation of diffusion process of one-dimensional system with steps for adsorbates interacting via the nearest-neighbor harmonic forces. The results are obtained from numerical studies, utilizing the method of stochastic Langevin dynamics. To study commensurability effects and the role of steps in the behavior of the diffusing particles, we have computed the diffusion coefficient for large concentrations and several interaction strengths. Our numerical results show that the diffusive behavior is reduced for commensurate structure case when the ground state has only one particle per one period of the substrate potential and enhanced for incommensurate density. Furthermore, the dynamic is qualitatively similar to that obtained in the case of no steps but with a clear reduction of the diffusion rate. Implications of these findings are discussed.


1969 ◽  
Vol 42 (5) ◽  
pp. 1277-1284
Author(s):  
N. R. Langley ◽  
R. A. Dickie ◽  
Chiu-ping Wong ◽  
J. D. Ferry ◽  
R. Chasset ◽  
...  

Abstract Measurements of the complex shear compliance have been made from 0.1 to 7 cycles/sec and from − 5° to 45° C on several samples of natural rubber cross-linked by dicumyl peroxide in the presence of a diluent oil (volume fraction of rubber, v2=0.63 and 0.76) which was subsequently extracted. The properties of the extracted vulcanizates were compared with those having the oil still present and with those of conventional undiluted vulcanizates. Measurements of the diffusion coefficient of radioactively tagged n-hexadecane in trace amounts through the polymer structure were also made both before and after extraction of the oil. The diffusion coefficient was higher in the presence of the oil by an amount consistent with the Fujita theory for concentration dependence of diffusion rate based on free volume considerations. The low-frequency mechanical losses (reduced to 25° C by the method of reduced variables), as measured by the loss tangent, were shifted to higher frequencies by the presence of oil to a much larger degree than would be expected from the difference in local mobility gauged by the diffusion coefficient. The equilibrium modulus, derived by extrapolation to zero frequency, was diminished by the presence of oil to a greater extent than the factor of v21/3 expected from the simple theory of rubberlike elasticity. The low-frequency losses in the extracted vulcanizates were smaller than those in conventional vulcanizates with comparable degrees of cross-linking; the differences are attributed to differences in network topology.


1992 ◽  
Vol 57 (10) ◽  
pp. 2100-2112 ◽  
Author(s):  
Vladimír Kudrna ◽  
Pavel Hasal ◽  
Andrzej Rochowiecki

A process of segregation of two distinct fractions of solid particles in a rotating horizontal drum mixer was described by stochastic model assuming the segregation to be a diffusion process with varying diffusion coefficient. The model is based on description of motion of particles inside the mixer by means of a stochastic differential equation. Results of stochastic modelling were compared to the solution of the corresponding Kolmogorov equation and to results of earlier carried out experiments.


Author(s):  
Е.Г. СТЕПАНОВА ◽  
Б.Ю. ОРЛОВ ◽  
М.А. ПЕЧЕРИЦА

Приведено решение нелинейной задачи диффузионного переноса с учетом предварительной подготовки экстрагента методом электрохимической активации. Для расчета параметров процесса использована капиллярная модель. Показаны результаты расчета симплекса концентраций от числа Фурье Е = f(Fo). Представлены экстракционные кривые в чистых сахарных растворах с различными видами экстрагентов и температурами процесса 20 и 70°С. Аналитическая обработка кинетических кривых позволила определить основные параметры диффузионного процесса экстрагирования сахарозы. Проведен полный двухфакторный эксперимент lnЕ= f(С; τ), получено уравнение регрессии и построена поверхность отклика, которая исследована методом неопределенных множителей Лагранжа с получением оптимальных значений для проведенной серии опытов С = 15,4% и τ = 750 с. Выполненные расчеты позволяют моделировать внутренний массоперенос экстрагирования концентрационно-зависимого коэффициента диффузии сахарозы при наложении электрического поля при обработке экстрагента. We present a solution to the nonlinear diffusion transfer problem, taking into account the preliminary preparation of the extractant by electrochemical activation (ECHA). A capillary model is used to calculate the process parameters. The results of calculating the concentration simplex from the Fourier number E= f(Fo) are shown. The description of the laboratory installation, the method of the process, and the modes of ECHA preparation of extractants are given. Extraction curves in pure sucrose solutions with different types of extractants and process temperatures are presented. Analytical processing of the kinetic curves of the sucrose extraction process for the regular stage of the process allowed us to determine the main parameters of the diffusion process. A complete two-factor experiment lnE= f(C; τ) was performed. A regression equation was obtained and the response surface was constructed, which was studied by the method of indeterminate Lagrange multipliers to obtain optimal values for the series of experiments С = 15,4% and τ = 750 s. The calculations performed allow us to model the internal mass transfer of extraction of the concentration-dependent sucrose diffusion coefficient when an electric field is applied during processing of the extractant.


2010 ◽  
Vol 638-642 ◽  
pp. 1131-1136
Author(s):  
Wei Liang Wang ◽  
Kazuhiro Ishikawa ◽  
Kiyoshi Aoki

In general, hydrogen permeabilityΦ of the alloy membrane is expressed as the product of the hydrogen diffusion coefficient D and the hydrogen solution coefficient K. Therefore, to improve the hydrogen permeability efficiently, the values of K and D should be separately considered. In the present study, hydrogen absorption and permeation behaviors of the Nb19Ti40Ni41 alloy consisting of the eutectic phase are investigated by measuring pressure-composition-isotherm (PCI) and by the hydrogen flow method and compared with those of palladium. The hydrogen absorption in the Nb19Ti40Ni41 alloy does not obey the Sieverts’ law in the pressure region of 0-1.0MPa at 523K, but it shows linear relationship between the difference in the square root of hydrogen pressure and hydrogen content between 0.1 and 0.4MPa. Although the value of D for the Nb19Ti40Ni41 alloy is considerably lower than that of palladium, its high K value enhances the hydrogen permeability Φ. It is suggested that the enhancement of D by microstructural control for Nb19Ti40Ni41 alloy is effective for improvement of Φ.


Author(s):  
Jinki Kim ◽  
Patrick Dorin ◽  
K. W. Wang

Many common environmental vibration sources exhibit low and broad frequency spectra. In order to exploit such excitations, energy harvesting architectures utilizing nonlinearity, especially bistability, have been widely studied since the energetic interwell oscillations between their stable equilibria can provide enhanced power harvesting capability over a wider bandwidth compared to the linear counterpart. However, one of the limitations of these nonlinear architectures is that the interwell oscillation regime may not be activated for a low excitation level that is not strong enough to overcome the potential energy barrier, thus resulting in low amplitude intrawell response which provides poor energy harvesting performance. While the strategic integration of bistability and additional dynamic elements has shown potential to improve broadband energy harvesting performance by lowering the potential barrier, there is a clear opportunity to further improve the energy harvesting performance by extracting electrical power from the kinetic energy in the additional element that is induced when the potential barrier is lowered. To explore this opportunity and advance the state of the art, this research develops a novel hybrid bistable vibration energy harvesting system with a passive mechanism that not only adaptively lowers the potential energy barrier level to improve broadband performance but also exploits additional means to capture more usable electrical power. The proposed harvester is comprised of a cantilever beam with repulsive magnets, one attached at the free end and the other attached to a linear spring that is axially aligned with the cantilever (a spring-loaded magnet oscillator). This new approach capitalizes on the adaptive bistable potential that is passively realized by the spring-loaded magnet oscillator, which lowers the double-well potential energy barrier thereby facilitating the interwell oscillations of the cantilever across a broad range of excitation conditions, especially for low excitation amplitudes and frequencies. The interwell oscillation of the cantilever beam enhances not only the piezoelectric energy harvesting from the beam but also the electromagnetic energy harvesting from the spring-loaded magnet oscillator by inducing large amplitude vibrations of the magnet oscillator. Numerical investigations found that the proposed architecture yields significantly enhanced energy harvesting performance compared to the conventional bistable harvester with fixed magnet.


1999 ◽  
Vol 32 (5) ◽  
pp. 864-870 ◽  
Author(s):  
H. Putz ◽  
J. C. Schön ◽  
M. Jansen

A new direct-space method forabinitiosolution of crystal structures from powder diffraction diagrams is presented. The approach consists of a combined global optimization (`Pareto optimization') of the difference between the calculated and the measured diffraction pattern and of the potential energy of the system. This concept has been tested successfully on a large variety of ionic and intermetallic compounds.


Sign in / Sign up

Export Citation Format

Share Document