scholarly journals Infrared spectra of complex organic molecules in astronomically relevant ice matrices

2019 ◽  
Vol 15 (S350) ◽  
pp. 356-357
Author(s):  
J. Terwisscha van Scheltinga ◽  
N. F. W. Ligterink ◽  
A. C. A. Boogert ◽  
E. F. van Dishoeck ◽  
H. Linnartz
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Infrared Spectra ◽  
Organic Molecules ◽  
Laboratory Studies ◽  
Astronomical Observations ◽  
James Webb Space Telescope ◽  
Circumstellar Gas ◽  
Complex Organic ◽  
Recent Laboratory

AbstractThe identification of complex organic molecules, COMs, in inter- and circumstellar gas phase environments is steadily increasing. The formation of such COMs takes largely place on the icy dust grains, as has been shown in recent laboratory studies. Until now solid state features of smaller molecular species have been directly identified in these environments. The presented work on acetaldehyde (CH3CHO), ethanol (CH3CH2OH), and dimethyl ether (CH3OCH3) in different astronomically relevant ice environments and for temperatures in the range 15 to 160 Kelvin, provides the necessary tools to guide or interpret astronomical observations, specifically for upcoming James Webb Space Telescope observations.

scholarly journals Infrared spectra of complex organic molecules in astronomically relevant ice matrices

2018 ◽  
Vol 611 ◽  
pp. A35 ◽  
Author(s):  
J. Terwisscha van Scheltinga ◽  
N. F. W. Ligterink ◽  
A. C. A. Boogert ◽  
E. F. van Dishoeck ◽  
H. Linnartz
Keyword(s):  
Gas Phase ◽  
Dimethyl Ether ◽  
Organic Molecules ◽  
Laboratory Data ◽  
Laboratory Studies ◽  
Astronomical Data ◽  
Astronomical Observations ◽  
Circumstellar Gas ◽  
Complex Organic ◽  
Recent Laboratory

Context. The number of identified complex organic molecules (COMs) in inter- and circumstellar gas-phase environments is steadily increasing. Recent laboratory studies show that many such species form on icy dust grains. At present only smaller molecular species have been directly identified in space in the solid state. Accurate spectroscopic laboratory data of frozen COMs, embedded in ice matrices containing ingredients related to their formation scheme, are still largely lacking.Aim. This work provides infrared reference spectra of acetaldehyde (CH3CHO), ethanol (CH3CH2OH), and dimethyl ether (CH3OCH3) recorded in a variety of ice environments and for astronomically relevant temperatures, as needed to guide or interpret astronomical observations, specifically for upcoming James Webb Space Telescope observations.Methods. Fourier transform transmission spectroscopy (500–4000 cm−1/20–2.5 μm, 1.0 cm−1 resolution) was used to investigate solid acetaldehyde, ethanol and dimethyl ether, pure or mixed with water, CO, methanol, or CO:methanol. These species were deposited on a cryogenically cooled infrared transmissive window at 15 K. A heating ramp was applied, during which IR spectra were recorded until all ice constituents were thermally desorbed.Results. We present a large number of reference spectra that can be compared with astronomical data. Accurate band positions and band widths are provided for the studied ice mixtures and temperatures. Special efforts have been put into those bands of each molecule that are best suited for identification. For acetaldehyde the 7.427 and 5.803 μm bands are recommended, for ethanol the 11.36 and 7.240 μm bands are good candidates, and for dimethyl ether bands at 9.141 and 8.011 μm can be used. All spectra are publicly available in the Leiden Database for Ice.

scholarly journals Laboratory data in support of JWST observations of interstellar ices

2019 ◽  
Vol 15 (S350) ◽  
pp. 420-421
Author(s):  
Marina G. Rachid ◽  
Jeroen Terwisscha van Scheltinga ◽  
Daniël Koletzki ◽  
Giulia Marcandalli ◽  
Ewine F. van Dishoeck ◽  
...  
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Organic Molecules ◽  
Methyl Formate ◽  
Laboratory Data ◽  
Protoplanetary Disks ◽  
Theoretical Studies ◽  
James Webb Space Telescope ◽  
Complex Organic ◽  
Experimental And Theoretical Studies

AbstractExperimental and theoretical studies have shown that Complex Organic Molecules (COMs) can be formed on icy dusty grains in molecular clouds and protoplanetary disks. The number of astronomical detections of solid COMs, however, is very limited. With the upcoming launch of the James Webb Space Telescope (JWST) this should change, but in order to identify solid state features of COMs, accurate laboratory data are needed. Here we present high resolution (0.5 cm–1) infrared ice spectra of acetone (C3H6O) and methyl formate (HCOOCH3), two molecules already identified in astronomical gas phase surveys, whose interstellar synthesis is expected to follow solid state pathways.

scholarly journals Dust and molecules in extra-galactic planetary nebulae

2015 ◽  
Vol 11 (A29B) ◽  
Author(s):  
D. A. García-Hernández
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Organic Molecules ◽  
Local Group ◽  
Planetary Nebulae ◽  
Circumstellar Envelopes ◽  
The Galaxy ◽  
Models Comparison ◽  
Polycyclic Aromatic ◽  
Complex Organic

AbstractExtra-galactic planetary nebulae (PNe) permit the study of dust and molecules in metallicity environments other than the Galaxy. Their known distances lower the number of free parameters in the observations vs. models comparison, providing strong constraints on the gas-phase and solid-state astrochemistry models. Observations of PNe in the Galaxy and other Local Group galaxies such as the Magellanic Clouds (MC) provide evidence that metallicity affects the production of dust as well as the formation of complex organic molecules and inorganic solid-state compounds in their circumstellar envelopes. In particular, the lower metallicity MC environments seem to be less favorable to dust production and the frequency of carbonaceous dust features and complex fullerene molecules is generally higher with decreasing metallicity. Here, I present an observational review of the dust and molecular content in extra-galactic PNe as compared to their higher metallicity Galactic counterparts. A special attention is given to the level of dust processing and the formation of complex organic molecules (e.g., polycyclic aromatic hydrocarbons, fullerenes, and graphene precursors) depending on metallicity.

scholarly journals Synthesis of solid-state complex organic molecules through accretion of simple species at low temperatures

2019 ◽  
Vol 15 (S350) ◽  
pp. 46-50
Author(s):  
D. Qasim ◽  
G. Fedoseev ◽  
K.-J. Chuang ◽  
V. Taquet ◽  
T. Lamberts ◽  
...  
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Low Temperatures ◽  
Laboratory Experiments ◽  
Organic Molecules ◽  
Primary Alcohol ◽  
Major Product ◽  
Activation Barriers ◽  
Upper Limit ◽  
Complex Organic

AbstractComplex organic molecules (COMs) have been detected in the gas-phase in cold and lightless molecular cores. Recent solid-state laboratory experiments have provided strong evidence that COMs can be formed on icy grains through ‘non-energetic’ processes. In this contribution, we show that propanal and 1-propanol can be formed in this way at the low temperature of 10 K. Propanal has already been detected in space. 1-propanol is an astrobiologically relevant molecule, as it is a primary alcohol, and has not been astronomically detected. Propanal is the major product formed in the C2H2 + CO + H experiment, and 1-propanol is detected in the subsequent propanal + H experiment. ALMA observations towards IRAS 16293-2422B are discussed and provide a 1-propanol:propanal upper limit of < 0.35–0.55, which are complemented by computationally-derived activation barriers in addition to the performed laboratory experiments.

scholarly journals Precursors of complex organic molecules: NH3 and CH3OH in the ices surrounding low-mass protostars

2008 ◽  
Vol 4 (S251) ◽  
pp. 105-110 ◽  
Author(s):  
Sandrine Bottinelli ◽  
Adwin C. A. Boogert ◽  
Ewine F. van Dishoeck ◽  
Martha Beckwith ◽  
Jordy Bouwman ◽  
...  
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Organic Molecules ◽  
High Sensitivity ◽  
Young Stellar Objects ◽  
Stellar Objects ◽  
Space Telescope ◽  
Low Mass ◽  
Complex Organic

AbstractNH3 and CH3OH are key molecules in the chemical networks leading to the formation of complex N- and O-bearing organic molecules. However, despite a number of recent studies, there is still a lot to learn about their abundances in the solid state and how they relate to those of other N/O-bearing organic molecules or to NH3 and CH3OH abundances in the gas phase. This is particularly true in the case of low-mass young stellar objects (YSOs), for which only the recent advent of the Spitzer Space Telescope has allowed high sensitivity observations of the ices in their enveloppes. We present a combined study of Spitzer data (obtained within the Legacy program “From Molecular Cores to Planet-Forming Disks”, c2d) and laboratory spectra, leading to the detections of NH3 and CH3OH in the ices of low-mass protostars. We investigate correlations with other ice features and conclude with prospects on further studies linking these two precursors of complex organic molecules with their gas-phase products.

Conceptual Examination of Gas Phase Particulate Formation in Gas Turbine Combustors

1980 ◽  
Vol 102 (3) ◽  
pp. 613-618 ◽  
Author(s):  
A. S. Kesten ◽  
J. J. Sangiovanni ◽  
P. Goldberg
Keyword(s):  
Gas Turbine ◽  
Gas Phase ◽  
Mathematical Framework ◽  
Droplet Combustion ◽  
Laboratory Studies ◽  
Gas Turbine Combustors ◽  
Large Particles ◽  
Fuel Pyrolysis ◽  
Insight Into ◽  
Recent Laboratory

Recent laboratory studies of droplet combustion indicate the potential for substantial gas phase particulate formation even with single component hydrocarbon fuels. Formation of large particles has been observed in the neighborhood of burning droplet arrays, particularly when the droplets are closely spaced. To provide insight into the potential for particulate formation during the combustion of fuel droplet sprays in gas turbine combustors, a mathematical framework is developed for examining the formation of soot nuclei in droplet combustion. A simplified model of the chemistry of fuel pyrolysis and nuclei formation is used and a series of calculations is made to explore the sensitivity of soot nuclei formation to conditions typical of gas turbine combustion systems.

scholarly journals Infrared spectra of complex organic molecules in astronomically relevant ice mixtures. IV. Methylamine

2021 ◽  
Author(s):  
M. G. Rachid ◽  
N. Brunken ◽  
D de Boe ◽  
G. Fedoseev ◽  
A. C. A. Boogert ◽  
...  
Keyword(s):  
Infrared Spectra ◽  
Organic Molecules ◽  
Complex Organic
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