Enhanced Cathodic Electrochemiluminescence of Luminol on Iron Electrodes

2021 ◽  
Author(s):  
Minghui Feng ◽  
Alice L. Dauphin ◽  
Laurent Bouffier ◽  
Feifei Zhang ◽  
Zonghua Wang ◽  
...  
Keyword(s):  
Iron Electrodes

scholarly journals Arsenic Removal by Advanced Electrocoagulation Processes: The Role of Oxidants Generated and Kinetic Modeling

Catalysts ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 928
Author(s):  
Micah Flor V. Montefalcon ◽  
Meliton R. Chiong ◽  
Augustus C. Resurreccion ◽  
Sergi Garcia-Segura ◽  
Joey D. Ocon
Keyword(s):  
Kinetic Modeling ◽  
Arsenic Removal ◽  
Fold Increase ◽  
Electrochemical Treatment ◽  
Promising Alternative ◽  
Iron Electrodes ◽  
Removal Capacity ◽  
Naturally Occurring ◽  
Treatment Technologies

Arsenic (As) is a naturally occurring element in the environment that poses significant risks to human health. Several treatment technologies have been successfully used in the treatment of As-contaminated waters. However, limited literature has explored advanced electrocoagulation (EC) processes for As removal. The present study evaluates the As removal performance of electrocoagulation, electrochemical peroxidation (ECP), and photo-assisted electrochemical peroxidation (PECP) technologies at circumneutral pH using electroactive iron electrodes. The influence of As speciation and the role of oxidants in As removal were investigated. We have identified the ECP process to be a promising alternative for the conventional EC with around 4-fold increase in arsenic removal capacity at a competitive cost of 0.0060 $/m3. Results also indicated that the rate of As(III) oxidation at the outset of electrochemical treatment dictates the extent of As removal. Both ECP and PECP processes reached greater than 96% As(III) conversion at 1 C/L and achieved 86% and 96% As removal at 5 C/L, respectively. Finally, the mechanism of As(III) oxidation was evaluated, and results showed that Fe(IV) is the intermediate oxidant generated in advanced EC processes, and the contribution of •OH brought by UV irradiation is insignificant.

Standardizing electrocoagulation reactor design: Iron electrodes for NOM removal

Chemosphere ◽  
2013 ◽  
Vol 91 (1) ◽  
pp. 55-60 ◽  
Author(s):  
Kristian L. Dubrawski ◽  
Madjid Mohseni
Keyword(s):  
Reactor Design ◽  
Iron Electrodes

An analysis of transient photocurrents measured on passivated iron electrodes

1990 ◽  
Vol 31 ◽  
pp. 715-720 ◽  
Author(s):  
Kazuhisa Azumi ◽  
Toshiaki Ohtsuka ◽  
Norio Sato
Keyword(s):  
Iron Electrodes

Carbonyl-Iron Electrodes for Rechargeable-Iron Batteries

2015 ◽  
Vol 1 (1) ◽  
Author(s):  
A. Sundar Rajan ◽  
M. K. Ravikumar ◽  
K. R. Priolkar ◽  
S. Sampath ◽  
A. K. Shukla
Keyword(s):  
Carbonyl Iron ◽  
Large Scale ◽  
Low Cost ◽  
Specific Capacity ◽  
Electrical Energy ◽  
Slow Increase ◽  
Faradaic Efficiency ◽  
Nickel Iron ◽  
In Situ Xrd ◽  
Iron Electrodes

AbstractNickel-iron and iron-air batteries are attractive for large-scale-electrical-energy storage because iron is abundant, low-cost and non-toxic. However, these batteries suffer from poor charge acceptance due to hydrogen evolution during charging. In this study, we have demonstrated iron electrodes prepared from carbonyl iron powder (CIP) that are capable of delivering a specific discharge capacity of about 400 mAh g−1 at a current density of 100 mA g−1 with a faradaic efficiency of about 80%. The specific capacity of the electrodes increases gradually during formation cycles and reaches a maximum in the 180th cycle. The slow increase in the specific capacity is attributed to the low surface area and limited porosity of the pristine CIP. Evolution of charge potential profiles is investigated to understand the extent of charge acceptance during formation cycles. In situ XRD pattern for the electrodes subsequent to 300 charge/discharge cycles confirms the presence of Fe with Fe(OH)2 as dominant phase.

A COMPARISON BETWEEN ALUMINIUM AND IRON ELECTRODES IN ELECTROCOAGULATION PROCESS FOR GLYPHOSATE REMOVAL

2015 ◽  
Vol 77 (32) ◽  
Author(s):  
Rabiatuladawiyah Danial ◽  
Luqman Chuah Abdullah ◽  
Mohsen Nourouzi Mobarekeh ◽  
Shafreeza Sobri ◽  
Nordayana Mohd Adnan
Keyword(s):  
Charged Particles ◽  
Deionized Water ◽  
Water Production ◽  
Batch Mode ◽  
Initial Concentration ◽  
Iron Electrodes ◽  
Metal Plates ◽  
Aqueous Environments ◽  
Electrocoagulation Process ◽  
Set Up

This study was intended to compare the performance of electrocoagulation process using aluminium and iron electrodes for glyphosate removal in aqueous solution. The effects of initial glyphosate concentration, electrocoagulation time and distance between electrodes, were discussed in detail. An electrocoagulation tank of 500mL with two metal plates electrodes, same in dimensions and metal types, was set up to perform batch mode laboratory experiment and the glyphosate in white powder was first diluted with deionized water. Production of metal cations showed an ability to neutralize negatively charged particles, which then encouraged to bind together to form aggregates of flocs composed of a combination of glyphosate and metal hydroxide. Compared with iron electrodes, aluminium electrodes were more effective for glyphosate removal, with a removal efficiency of over than 80%. This study revealed that electrocoagulation process using aluminium electrodes is reliable, especially designed for initial concentration 100 mg/L, electrocoagulation time 50 min, and distance between electrodes 6 cm. Finally, it can be concluded that electrocoagulation process using aluminium electrodes is efficient for glyphosate removal from aqueous environments.

scholarly journals Photoelectrochemical Behaviour of Fe(CN)6(4-)/Fe(CN)6(3-) at Passive Iron Electrodes in Borate Solution.

1981 ◽  
Vol 35a ◽  
pp. 359-363 ◽  
Author(s):  
W. Richard Bowen ◽  
Tor Hurlen ◽  
Ragnhild Seip ◽  
Ragnhild Seip ◽  
Olof Wahlberg
Keyword(s):  
Iron Electrodes ◽  
Borate Solution

Microbial fuel cell: Bio-energy production from Nigerian corn starch wastewater using iron electrodes

2020 ◽  
Author(s):  
Collins N. Nwaokocha ◽  
Solomon O. Giwa ◽  
Abayomi T. Layeni ◽  
Sidikat I. Kuye ◽  
Olusegun D. Samuel ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Energy Production ◽  
Corn Starch ◽  
Iron Electrodes ◽  
Starch Wastewater

scholarly journals Batch Electrocoagulation Treatment of Peat Water in Sarawak with Galvanized Iron Electrodes

2020 ◽  
Vol 997 ◽  
pp. 127-138
Author(s):  
Nazzeri Abdul Rahman ◽  
Nur Afifah Tomiran ◽  
Aiman Hakim Hashim
Keyword(s):  
Organic Carbon ◽  
Total Organic Carbon ◽  
Humic Acids ◽  
Current Density ◽  
Treatment Time ◽  
Oxygen Demand ◽  
Experimental Tests ◽  
Iron Electrodes ◽  
Filtration System ◽  
Standard Limit

Peat water is an abundant water resource in Sarawak where some of the coastal areas in Sarawak still utilize peat water for domestic usage. Peat water contains natural organic matters especially humic substances which include humic acids. Humic acids contribute to the brown color of peat water and can cause diseases such as stomach cancer, blackfoot disease and etc. if consumed by human. Electrocoagulation is an alternative to conventional water treatment methods which have the advantages of being environmental friendly, minimal sludge production and no addition of chemical substances. The aims of this study are to fabricate a desktop scale electrocoagulation system with galvanised iron electrodes and to investigate the effects of the operating parameters such as inter-electrode distance, applied current density, number of electrodes, and treatment time on peat water in the system. The performance of batch electrocoagulation system in term of their removal efficiency of several parameters such as total organic carbon (TOC), chemical oxygen demand (COD), color and turbidity are evaluated. Through experimental tests conducted, this system successfully removes 98.44% of COD, 92.02% of TOC, 97.92% of turbidity and 99.91% of color by using galvanized iron as an electrode at current density of 25 A/m2in 30 minutes with 10 galvanized iron electrodes. Despite the fact that there is a small amount of iron ions and zinc ions remained in the treated peat water which are 0.001mg/l and 0.0442mg/l respectively, these concentrations are far below the standard limits imposed by Malaysia Ministry of Health (MOH). Generally, all the parameters studied meet the standard limit imposed by MOH except for total organic carbon. This is particularly due to the improper filtration system adopted in this study. The total operating costs for 252 in 30 minutes treatment time of 10 electrode plates is RM 8.75 per . Overall, the study have successfully designed a batch electrocoagulation system to treat peat water by using galvanized iron for domestic usage.

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