Freezing Point Elevation of an Aqueous Solution in 3 nm Diameter Carbon Nanotubes

2020 ◽  
Vol 124 (26) ◽  
pp. 14213-14219
Author(s):  
Tomonori Ohba
2019 ◽  
Vol 943 ◽  
pp. 95-99
Author(s):  
Li Jun Wang ◽  
Kazuo Umemura

Optical absorption spectroscopy provides evidence for individually dispersed carbon nanotubes. A common method to disperse SWCNTs into aqueous solution is to sonicate the mixture in the presence of a double-stranded DNA (dsDNA). In this paper, optical characterization of dsDNA-wrapped HiPco carbon nanotubes (dsDNA-SWCNT) was carried out using near infrared (NIR) spectroscopy and photoluminescence (PL) experiments. The findings suggest that SWCNT dispersion is very good in the environment of DNA existing. Additionally, its dispersion depends on dsDNA concentration.


Small ◽  
2008 ◽  
Vol 4 (12) ◽  
pp. 2166-2170 ◽  
Author(s):  
Peng Wang ◽  
Qihui Shi ◽  
Hongjun Liang ◽  
David W. Steuerman ◽  
Galen D. Stucky ◽  
...  

2001 ◽  
Vol 703 ◽  
Author(s):  
G.F. Farrell ◽  
G. Chambers ◽  
A.B Dalton ◽  
E. Cummins ◽  
M. McNamara ◽  
...  

ABSTRACTIn this study the intermolecular interactions of small diameter (∼0.7nm) carbon nanotubes and γ-cyclodextrin were examined. Four samples of γ cyclodextrin and HiPco carbon nanotubes were prepared. The first, by grinding the tubes and the cyclodextrin (1:30 ratio) together in a dry mixture, the second was prepared in a similar fashion but was ground in the presence of water (1ml). Finally an aqueous solution of γ-cyclodextrin (0.3M) and HiPco carbon nanotubes (5mg) was prepared by refluxing for ∼100 hours, forming a pale yellow solution from which a number of crystals were produced, both the solution and the recrystallised material were analysed. The samples were analysed using UV-Vis-NIR and Raman spectroscopy. The results presented are the first spectroscopic evidence of an intermolecular interaction between γ-cyclodextrin and single wall nanotubes.


2013 ◽  
Vol 21 (01) ◽  
pp. 1350004 ◽  
Author(s):  
KOJI FUMOTO ◽  
TSUYOSHI KAWANAMI ◽  
TAKAO INAMURA

A cold thermal energy storage system has been developed for HVAC. There are many ice-based cooling systems operating around the world. Ice slurry, which is a mixture of fine ice crystals and liquid water, is utilized in ice storage systems owing to its good flowability and large latent heat of fusion. For slurry ice production techniques, there are presently a number of commercially available ice slurry generators (e.g., Supercooled slurry ice generator, Scraper type generator, and Vacuum type generator, etc.). In the present study, a new method was developed to generate ice slurry without the deposition of an ice layer on a cooled surface. The basic components of the experimental apparatus is a cooling brine circulating loop, a high pressure pump, a valve, an aqueous solution flow loop containing the test section, which is made of transparent acrylic, and the associated instrumentation. This new method is based on freezing-point depression of the aqueous solution, which is maintained under high-pressure conditions. To control the timing for solidification and to generate ice slurry, we investigated the relationships among the pressure and temperature of the aqueous solution. The freezing phenomenon of the aqueous solution in the test section was observed in detail. As a result, we developed a new ice slurry generator based on the new method that controls the pressure and temperature of the aqueous solution. Experimental results showed that the characteristics of the ice slurry generation were closely related to the pressure and initial stage temperature of the test fluid. Finally, the optimum operation condition of the ice slurry generator based on visualization experiment was discussed.


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