Electronic and Optical Property Control of Polycation/MXene Layer-by-Layer Assemblies with Chemically Diverse MXenes

Langmuir ◽  
2021 ◽  
Author(s):  
Ian J. Echols ◽  
Hyosung An ◽  
Junyeong Yun ◽  
Kasturi T. Sarang ◽  
Ju-Hyun Oh ◽  
...  
2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Chien-Ho Ko

Purpose Additive manufacturing of concrete (AMoC) is an emerging technology for constructing buildings. However, due to the nature of the concrete property and constructing buildings in layers, constraints and limitations are encountered while applying AMoC in architecture. This paper aims to analyze the constraints and limitations that may be encountered while using AMoC in architecture. Design/methodology/approach A descriptive research approach is used to conduct this study. First, basic notions of AMoC are introduced. Then, challenges of AMoC, including hardware, material property, control and design, are addressed. Finally, strategies that may be used to overcome the challenges are discussed. Findings Factors influencing the success of AMoC include hardware, material, control methods, manufacturing process and design. Considering these issues in the early design phase is crucial to achieving a successful computer-aided design (CAD)/computer-aided manufacturing (CAM) integration to bring CAD and CAM benefits into the architecture industry. Originality/value In three-dimensional (3D) printing, objects are constructed layer by layer. Printing results are thus affected by the additive method (such as toolpath) and material properties (such as tensile strength and slump). Although previous studies attempt to improve AMoC, most of them focus on the manufacturing process. However, a successful application of AMoC in architecture needs to consider the possible constraints and limitations of concrete 3D printing. So far, research on the potential challenges of applying AMoC in architecture from a building lifecycle perspective is still limited. The study results of this study could be used to improve design and construction while applying AMoC in architecture.


2013 ◽  
Vol 832 ◽  
pp. 612-616
Author(s):  
Aadila Aziz ◽  
N.A.M. Asib ◽  
A.N. Afaah ◽  
R. Mohamed ◽  
Mohamad Rusop ◽  
...  

Preparation of ZnO/PMMA nanocomposite has been reported by using the solution-immersion method. These studies involve depositing poly (methyl methacrylate) (PMMA) layer by layer on glass substrate using the spin coating technique. Surface morphologies deposited layer of PMMA on glass substrate was characterized using Atomic Force Microscope (AFM) and an optical property of ZnO/PMMA nanocomposite was characterized using UV-Vis Spectrometer. For AFM result, the highest surface roughness 0.048 nm represent layer of platinum due to its function as a seeded-catalyst followed by 1 layer of PMMA show surface roughness 0.015 nm. 4 hours immersion time show highest absorption for 5 layer of deposited PMMA at 279.21 nm. While, for 6 hours show highest absorption for 1 layer and 3 layer of PMMA with overlapped each other at 278.54 nm.


2015 ◽  
Vol 23 (5) ◽  
pp. 1288-1296
Author(s):  
汤洋 TANG Yang ◽  
郭逦达 GUO Li-da ◽  
张增光 ZHANG Zeng-guang ◽  
陈颉 CHEN Jie

2020 ◽  
Vol 56 (73) ◽  
pp. 10654-10657
Author(s):  
Takahiro Yanbe ◽  
Kei Mizuguchi ◽  
Ryohei Yamakado ◽  
Shuji Okada

π-Electronic systems bearing Lewis pairs were synthesized. The tuning of the optical properties was demonstrated by the addition of various ion pairs, and these behaviours were elucidated by theoretical calculations.


2012 ◽  
Vol 10 (s1) ◽  
pp. S11601-311604
Author(s):  
Ling Li Ling Li ◽  
Ling Fu Ling Fu ◽  
Xintong Xu Xintong Xu ◽  
Jianpang Zhai Jianpang Zhai ◽  
Shuangchen Ruan Shuangchen Ruan

2019 ◽  
Vol 5 (7) ◽  
pp. eaav4916 ◽  
Author(s):  
Hyunmin Cho ◽  
Jinhyeong Kwon ◽  
Inho Ha ◽  
Jinwook Jung ◽  
Yoonsoo Rho ◽  
...  

Active control of transparency/color is the key to many functional optoelectric devices. Applying an electric field to an electrochromic or liquid crystal material is the typical approach for optical property control. In contrast to the conventional electrochromic method, we developed a new concept of smart glass using new driving mechanisms (based on mechanical stimulus and thermal energy) to control optical properties. This mechano-thermo-chromic smart glass device with an integrated transparent microheater uses a sodium acetate solution, which shows a unique marked optical property change under mechanical impact (mechanochromic) and heat (thermochromic). Such mechano-thermo-chromic devices may provide a useful approach in future smart window applications that could be operated by external environment conditions.


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