Role of Surface Capping Molecule Polarity on the Optical Properties of Solution Synthesized Germanium Nanocrystals

Langmuir ◽  
2017 ◽  
Vol 33 (35) ◽  
pp. 8790-8798 ◽  
Author(s):  
B. F. P. McVey ◽  
P. B. O’Mara ◽  
A. J. McGrath ◽  
A. Faramus ◽  
V. B. Yasarapudi ◽  
...  
Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2349
Author(s):  
Alain Salvador Conejo-Dávila ◽  
Marco Armando Moya-Quevedo ◽  
David Chávez-Flores ◽  
Alejandro Vega-Rios ◽  
Erasto Armando Zaragoza-Contreras

The development of anilinium 2-acrylamide-2-methyl-1-propanesulfonate (Ani-AMPS) monomer, confirmed by 1H NMR, 13C NMR, and FTIR, is systematically studied. Ani-AMPS contains two polymerizable functional groups, so it was submitted to selective polymerization either by free-radical or oxidative polymerization. Therefore, poly(anilinium 2-acrylamide-2-methyl-1-propanesulfonic) [Poly(Ani-AMPS)] and polyaniline doped with 2-acrylamide-2-methyl-1-propanesulfonic acid [PAni-AMPS] can be obtained. First, the acrylamide polymer, poly(Ani-AMPS), favored the π-stacking of the anilinium group produced by the inter- and intra-molecular interactions and was studied utilizing 1H NMR, 13C NMR, FTIR, and UV-Vis-NIR. Furthermore, poly(Ani-AMPS) fluorescence shows quenching in the presence of Fe2+ and Fe3+ in the emission spectrum at 347 nm. In contrast, the typical behavior of polyaniline is observed in the cyclic voltammetry analysis for PAni-AMPS. The optical properties also show a significant change at pH 4.4. The PAni-AMPS structure was corroborated through FTIR, while the thermal properties and morphology were analyzed utilizing TGA, DSC (except PAni-AMPS), and FESEM.


RSC Advances ◽  
2021 ◽  
Vol 11 (14) ◽  
pp. 7961-7971
Author(s):  
N. D. Vinh ◽  
P. M. Tan ◽  
P. V. Do ◽  
S. Bharti ◽  
V. X. Hoa ◽  
...  

The role of samarium (Sm) dopant on the structural, morphological, and optical properties of CdS QDs and CdS/ZnS core/shell QDs was methodically reported.


2020 ◽  
Vol 281 ◽  
pp. 121028 ◽  
Author(s):  
Saad Mabrouk Yakout ◽  
Hanan A. Mousa ◽  
Hala T. Handal ◽  
Walid Sharmoukh

2010 ◽  
Vol 247 (8) ◽  
pp. 1960-1964 ◽  
Author(s):  
Conor Hogan ◽  
Rita Magri ◽  
Rodolfo Del Sole

Author(s):  
Mohammad Asad ◽  
Adèle D Laurent

UnaG is a new class of fluorescence protein for which an endogenous ligand namely bilirubin (BLR) is playing the role of the chromophore. Upon photoexcitation, holoUnaG emits the green light....


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