As promising building blocks for functional materials and devices, metasurfaces have gained widespread attention in recent years due to their unique electromagnetic (EM) properties, as well as subwavelength footprints. However, current designs based on discrete unit cells often suffer from low working efficiencies, narrow operation bandwidths, and fixed EM functionalities. Here, by employing the superior performance of a continuous metasurface, combined with the reconfigurable properties of a phase change material (PCM), a dual-functional meta-grating is proposed in the infrared region, which can achieve a broadband polarization conversion of over 90% when the PCM is in an amorphous state, and a perfect EM absorption larger than 91% when the PCM changes to a crystalline state. Moreover, by arranging the meta-grating to form a quasi-continuous metasurface, subsequent simulations indicated that the designed device exhibited an ultralow specular reflectivity below 10% and a tunable thermal emissivity from 14.5% to 91%. It is believed that the proposed devices with reconfigurable EM responses have great potential in the field of emissivity control and infrared camouflage.
Dual-functional materials via CCTP and selective orthogonal thiol-Michael addition/epoxide ring opening reactions
