Unraveling a Graphene Exfoliation Technique Analogy in the Making of Ultrathin Nickel–Iron Oxyhydroxides@Nickel Foam to Promote the OER

Author(s):  
Zubair Ahmed ◽  
Krishankant ◽  
Ritu Rai ◽  
Rajinder Kumar ◽  
Takahiro Maruyama ◽  
...  
2018 ◽  
Vol 43 (15) ◽  
pp. 7299-7306 ◽  
Author(s):  
Chi Zhang ◽  
Yunchao Xie ◽  
Heng Deng ◽  
Cheng Zhang ◽  
Jheng-Wun Su ◽  
...  

2021 ◽  
Vol 290 ◽  
pp. 01036
Author(s):  
Qiuyu Zhao ◽  
Wenke Xi ◽  
Jianjun Wang

It is extensively accepted that electrolysis of water producing regenerable energy is a crucial substitution of traditional fuel strategy. Herein, we report a wet-chemical route to Ni-Fe layered double hydroxide (LDH) interconnected nanosheets with large surface area with the support of vertically aligned ZnO microrods arrays on the nickel foam (Ni-Fe LDH@ZnO/NF) for oxygen evolution reaction. Owing to the 2D Ni-Fe LDH nanosheets distributed in 3D space, the Ni-Fe LDH@ZnO/NF demonstrates excellent OER performances with a reasonably low overpotential of 271 mV at a current density of 10 mA·cm-2, and a long-term stability up to 29 hours. This work proposes a new strategy to prepare Ni-Fe LDH/NF as efficient OER catalyst.


2014 ◽  
Vol 1053 ◽  
pp. 41-49
Author(s):  
Xiao Min Huo ◽  
Gang He ◽  
Hong Yun Lin ◽  
Jian Li Wang ◽  
De Qing Wang

An Ni-Fe alloy on the surface of nickel foam was prepared by electro deposition. The effects of technological parameters including current density, pH value, temperature and the ratio of [Ni2+] to [Fe2+] of planting solution on the thickness and iron content of the alloy coating were studied. The cross-section microstructure and surface morphologies were observed by optical microscopy and scanning electron microscope, and the compositions of the alloy coating were analyzed by energy dispersive spectrometer and ICP-AES. Experiment results show that the thickness of the alloy coating is increased with increasing current density, temperature, pH value and the ratio of [Ni2+] to [Fe2+] of the planting solution. The Fe contents of the alloy coating is increased with increasing current density and pH value of the planting solution, and decreased with increasing temperature and the ratio of [Ni2+] to [Fe2+] of the planting solution. A 36.2 μm thick alloy layer of uniform and dense coating with the Fe content of 60.5 wt% is obtained under the parameters ofn(Ni2+)/n(Fe2+)= 4, current density = 10 A/dm2and pH = 4.2 at 50 °C for one hour.


2017 ◽  
Vol 5 (23) ◽  
pp. 11661-11670 ◽  
Author(s):  
Joseph M. Barforoush ◽  
Dylan T. Jantz ◽  
Tess E. Seuferling ◽  
Kelly R. Song ◽  
Laura C. Cummings ◽  
...  

Nickel–iron oxyhydroxides (Ni1−xFexOOH) are non-precious metal electrocatalysts for the oxygen evolution reaction (OER) that have high efficiency in alkaline media.


2017 ◽  
Vol 114 (22) ◽  
pp. 5607-5611 ◽  
Author(s):  
Haiqing Zhou ◽  
Fang Yu ◽  
Jingying Sun ◽  
Ran He ◽  
Shuo Chen ◽  
...  

Commercial hydrogen production by electrocatalytic water splitting will benefit from the realization of more efficient and less expensive catalysts compared with noble metal catalysts, especially for the oxygen evolution reaction, which requires a current density of 500 mA/cm2 at an overpotential below 300 mV with long-term stability. Here we report a robust oxygen-evolving electrocatalyst consisting of ferrous metaphosphate on self-supported conductive nickel foam that is commercially available in large scale. We find that this catalyst, which may be associated with the in situ generated nickel–iron oxide/hydroxide and iron oxyhydroxide catalysts at the surface, yields current densities of 10 mA/cm2 at an overpotential of 177 mV, 500 mA/cm2 at only 265 mV, and 1,705 mA/cm2 at 300 mV, with high durability in alkaline electrolyte of 1 M KOH even after 10,000 cycles, representing activity enhancement by a factor of 49 in boosting water oxidation at 300 mV relative to the state-of-the-art IrO2 catalyst.


2016 ◽  
Vol 4 (42) ◽  
pp. 16394-16402 ◽  
Author(s):  
Pandian Ganesan ◽  
Arumugam Sivanantham ◽  
Sangaraju Shanmugam

The inexpensive fabrication of nano-honeycomb structured nickel iron sulphides on a nickel foam current collector is described and used as both anode and cathode in the alkaline membrane water electrolysis.


Author(s):  
O. Yu. Kichigina

At production of stainless steel expensive alloying elements, containing nickel, are used. To decrease the steel cost, substitution of nickel during steel alloying process by its oxides is an actual task. Results of analysis of thermodynamic and experimental studies of nickel reducing from its oxide presented, as well as methods of nickel oxide obtaining at manganese bearing complex raw materials enrichment and practice of its application during steel alloying. Technology of comprehensive processing of complex manganese-containing raw materials considered, including leaching and selective extraction out of the solution valuable components: manganese, nickel, iron, cobalt and copper. Based on theoretical and experiment studies, a possibility of substitution of metal nickel by concentrates, obtained as a result of hydrometallurgical enrichment, was confirmed. Optimal technological parameters, ensuring high degree of nickel recovery out of the initial raw materials were determined. It was established, that for direct steel alloying it is reasonable to add into the charge pellets, consisting of nickel concentrate and coke fines, that enables to reach the through nickel recovery at a level of 90%. The proposed method of alloying steel by nickel gives a possibility to decrease considerably steel cost at the expense of application of nickel concentrate, obtained out of tails of hydrometallurgical enrichment of manganese-bearing raw materials, which is much cheaper comparing with the metal nickel.


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