Synergetic Improvement in Thermal Conductivity and Flame Retardancy of Epoxy/Silver Nanowires Composites by Incorporating “Branch-Like” Flame-Retardant Functionalized Graphene

2018 ◽  
Vol 10 (25) ◽  
pp. 21628-21641 ◽  
Author(s):  
Yuezhan Feng ◽  
Xiongwei Li ◽  
Xiaoyu Zhao ◽  
Yunsheng Ye ◽  
Xingping Zhou ◽  
...  
2018 ◽  
Vol 38 (8) ◽  
pp. 767-774 ◽  
Author(s):  
Liang Wang ◽  
Luchong Zhang ◽  
Andreas Fischer ◽  
Yuhua Zhong ◽  
Dietmar Drummer ◽  
...  

Abstract High performance composite of polyamide 6 (PA6)/flame retardant (FR)/hexagonal boron nitride (hBN) was prepared via twin screw extrusion, followed by injection molding. The heat dissipation of the composite was significantly improved by incorporating 40 vol% of hBN, and the corresponding thermal conductivity was up to 5.701 W/(m·K), nearly 17 times that of the PA6/FR composites. In addition, the combination effect of hBN and FR to the flame retardancy of the composites was observed, and the addition of hBN could dramatically enhance the flame retardancy of composites, achieving a UL94 V-0 rating with a limited oxygen index (LOI) value of 37%. This multifunctional modification would broaden the application field of PA6 composites in light-emitting diode (LED) lamps, electronic products, and so on.


2017 ◽  
Vol 5 (26) ◽  
pp. 13544-13556 ◽  
Author(s):  
Yuezhan Feng ◽  
Ji Hu ◽  
Yang Xue ◽  
Chengen He ◽  
Xingping Zhou ◽  
...  

A synergistic enhancement effect of PFR-fRGO and Al2O3 on the flame resistance and thermal conductivity of epoxy-based composites.


RSC Advances ◽  
2018 ◽  
Vol 8 (44) ◽  
pp. 24993-25000 ◽  
Author(s):  
Kang Dai ◽  
Shuai Sun ◽  
Wenbin Xu ◽  
Yuan Song ◽  
Zhenzhen Deng ◽  
...  

A covalently-functionalized graphene oxide with excellent flame retardancy was successfully prepared.


2017 ◽  
Vol 5 (35) ◽  
pp. 18542-18550 ◽  
Author(s):  
Fubin Luo ◽  
Kun Wu ◽  
Jun Shi ◽  
Xiangxiang Du ◽  
Xiaoya Li ◽  
...  

Inspired by mussels, dopamine (DOPA) was used as a green reducing agent for graphene oxide (GO) to prepare a superior flame retardant and high thermal conductive flexible film.


2019 ◽  
Vol 7 (45) ◽  
pp. 14159-14169 ◽  
Author(s):  
Xiu Wang ◽  
Song-Lin Ji ◽  
Xin-Qi Wang ◽  
Hui-Yang Bian ◽  
Ling-Rui Lin ◽  
...  

LNPs were utilized as functional fillers to enhance the thermal conductivity, flame-retardancy, and flexibility of BN-OH/PVA composite film.


Materials ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4114 ◽  
Author(s):  
Fang Wang ◽  
Wenbo Shi ◽  
Yuliang Mai ◽  
Bing Liao

In this work, polyamide 6 (PA6) composites with improved flame retardancy and thermal conductivity were prepared with different thermal conductive fillers (TC fillers) such as aluminum nitride (AlN) and boron nitride (BN) in a PA6 matrix with aluminum diethylphosphinate (AlPi) as a fire retardant. The resultant halogen-free flame retardant (HFFR) and thermal conductive (TC) PA6 (HFFR-TC-PA6) were investigated in detail with a mechanical property test, a limiting oxygen index (LOI), the vertical burning test (UL-94), a cone calorimeter, a thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC). The morphology of the impact fracture surface and char residue of the composites were analyzed by scanning electron microscopy (SEM). It was found that the thermal conductivity of the HFFR-TC-PA6 composite increased with the amount of TC fillers. The TC fillers exerted a positive effect for flame retardant PA6. For example, the HFFR-TC-PA6 composites with the thickness of 1.6 mm successfully passed the UL-94 V-0 rating with an LOI of more than 29% when the loading amount of AlN-550RFS, BN-SW08 and BN-NW04 was 30 wt%. The morphological structures of the char residues revealed that TC fillers formed a highly integrated char layer surface (without holes) during the combustion process, as compared to that of flame retardant PA6/AlPi composites. In addition, the thermal stability and crystallization behavior of the composites were studied.


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