Impact Ionization Induced by Accelerated Photoelectrons for Wide-Range and Highly Sensitive Detection of Volatile Organic Compounds at Room Temperature

2019 ◽  
Vol 11 (22) ◽  
pp. 20491-20499
Author(s):  
Yunsung Kang ◽  
Soonjae Pyo ◽  
Han-Il Jeong ◽  
Kyounghoon Lee ◽  
Dae-Hyun Baek ◽  
...  
Proceedings ◽  
2018 ◽  
Vol 2 (13) ◽  
pp. 790 ◽  
Author(s):  
Stella Vallejos ◽  
Zdenka Fohlerová ◽  
Milena Tomić ◽  
Isabel Gràcia ◽  
Eduard Figueras ◽  
...  

Gas microsensors based on tungsten oxide (WO3-x) nanowires (NWs) silanized with APTES (3-aminopropyltriethoxysilane) are developed in this work. These surface modified microsensors are highly sensitive to ethanol at room temperature (RT) via photoactivation and show enhanced selectivity towards other volatile organic compounds (VOCs) including acetone and toluene.


2016 ◽  
Vol 4 (22) ◽  
pp. 8700-8706 ◽  
Author(s):  
Ye-Qing Zhang ◽  
Zhe Li ◽  
Tao Ling ◽  
Sergei A. Kulinich ◽  
Xi-Wen Du

Highly sensitive and selective detection of volatile organic compounds (VOCs) with fast response time is imperative based on safety requirements, yet often remains a challenge.


Sensors ◽  
2021 ◽  
Vol 21 (2) ◽  
pp. 440
Author(s):  
Daniel Garcia-Osorio ◽  
Pilar Hidalgo-Falla ◽  
Henrique E. M. Peres ◽  
Josue M. Gonçalves ◽  
Koiti Araki ◽  
...  

Gas sensors are fundamental for continuous online monitoring of volatile organic compounds. Gas sensors based on semiconductor materials have demonstrated to be highly competitive, but are generally made of expensive materials and operate at high temperatures, which are drawbacks of these technologies. Herein is described a novel ethanol sensor for room temperature (25 °C) measurements based on hematite (α‑Fe2O3)/silver nanoparticles. The AgNPs were shown to increase the oxide semiconductor charge carrier density, but especially to enhance the ethanol adsorption rate boosting the selectivity and sensitivity, thus allowing quantification of ethanol vapor in 2–35 mg L−1 range with an excellent linear relationship. In addition, the α-Fe2O3/Ag 3.0 wt% nanocomposite is cheap, and easy to make and process, imparting high perspectives for real applications in breath analyzers and/or sensors in food and beverage industries. This work contributes to the advance of gas sensing at ambient temperature as a competitive alternative for quantification of conventional volatile organic compounds.


2013 ◽  
Vol 13 (12) ◽  
pp. 32649-32701 ◽  
Author(s):  
M. Li ◽  
Q. Zhang ◽  
D. G. Streets ◽  
K. B. He ◽  
Y. F. Cheng ◽  
...  

Abstract. An accurate speciation mapping of non-methane volatile organic compounds (NMVOC) emissions has an important impact on the performance of chemical transport models (CTMs) in simulating ozone mixing ratios and secondary organic aerosols. In this work, we developed an improved speciation framework to generate model-ready anthropogenic Asian NMVOC emissions for various gas-phase chemical mechanisms commonly used in CTMs by using an explicit assignment approach and updated NMVOC profiles, based on the total NMVOC emissions in the INTEX-B Asian inventory for the year 2006. NMVOC profiles were selected and aggregated from a wide range of new measurements and the SPECIATE database. To reduce potential uncertainty from individual measurements, composite profiles were developed by grouping and averaging source profiles from the same category. The fractions of oxygenated volatile organic compounds (OVOC) were corrected during the compositing process for those profiles which used improper sampling and analyzing methods. Emissions of individual species were then lumped into species in different chemical mechanisms used in CTMs by applying mechanism-dependent species mapping tables, which overcomes the weakness of inaccurate mapping in previous studies. Gridded emissions for eight chemical mechanisms are developed at 30 min × 30 min resolution using various spatial proxies and are provided through the website: http://mic.greenresource.cn/intex-b2006. Emission estimates for individual NMVOC species differ between one and three orders of magnitude for some species when different sets of profiles are used, indicating that source profile is the most important source of uncertainties of individual species emissions. However, those differences are diminished in lumped species as a result of the lumping in the chemical mechanisms.


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