Nucleobase-Functionalized Poly(alkylthiophene)s: One-Pot, Sequential Direct Arylation Polymerization and Deprotection, and Surface Modification for Oil–Water Separations

Many researches have been done to obtain a low band gap and high Polymeric solar cell (PSCs) polymer either by creating new polymer or revising reported polymers from previous studies. In present work, two new copolymers were synthesized through direct arylation polymerization to produce poly(9,9-didodecylfluorene-alt-benzo[c][1,2,5]thiadiazole (P1) and poly(9,9-didodecylfluorene-altthieno[ 3,2-b]thiophene) (P2). The P1 and P2 are donor-accepter copolymers. P1 and P2 were compared to investigate its suitability to be applied in PSCs. The polymers obtained were characterized using FT-IR, NMR and UV-Vis spectroscopy. P1 shows two adsorption bands at λmax1 = 243 nm and λmax2 = 320 nm, whereas P2 also shows two adsorption bands at λmax1 = 243 nm and λmax2 = 427 nm. The optical band gap was calculated, P1 enabled band gap of 3.88 eV while P2 showed band gap of 2.91 eV. This work could be provided an insight to design and synthesize more efficient fluorene-based copolymers as active layer of PSCs in due course.

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One-Pot Synthesis and Surface Modification of Lauric-Acid-Capped CoFe2O4 Nanoparticles

IEEE Transactions on Magnetics ◽

10.1109/tmag.2018.2834524 ◽

2018 ◽

Vol 54 (11) ◽

pp. 1-5 ◽

Cited By ~ 2

Author(s):

Yun Teng ◽

Philip W. T. Pong

Keyword(s):

Surface Modification ◽

Lauric Acid ◽

Cofe2o4 Nanoparticles ◽

One Pot ◽

One Pot Synthesis

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One-pot Synthesis and Surface Modification of Fe3O4 Nanoparticles Using Polyvinyl Alcohol by Coprecipitation and Ultrasonication Methods

IOP Conference Series Materials Science and Engineering ◽

10.1088/1757-899x/299/1/012066 ◽

2018 ◽

Vol 299 ◽

pp. 012066 ◽

Cited By ~ 2

Author(s):

Aditya D Nugraha ◽

Ika O Wulandari ◽

L B Hutami Rahayu ◽

Imam Riva’i ◽

D J Djoko H Santojo ◽

...

Keyword(s):

Surface Modification ◽

Polyvinyl Alcohol ◽

Fe3o4 Nanoparticles ◽

One Pot ◽

One Pot Synthesis

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One pot synthesis and surface modification of mesoporous iron oxide nanoparticles

Nano-Structures & Nano-Objects ◽

10.1016/j.nanoso.2019.100343 ◽

2019 ◽

Vol 19 ◽

pp. 100343 ◽

Cited By ~ 5

Author(s):

Ruby Phul ◽

Vipul Shrivastava ◽

Umar Farooq ◽

Meryam Sardar ◽

Abul Kalam ◽

...

Keyword(s):

Surface Modification ◽

Iron Oxide ◽

Iron Oxide Nanoparticles ◽

Oxide Nanoparticles ◽

One Pot ◽

One Pot Synthesis

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Visible Light-Promoted C–C Bond Formation from Hydroxyaryls in Water

Australian Journal of Chemistry ◽

10.1071/ch19378 ◽

2019 ◽

Vol 72 (12) ◽

pp. 978 ◽

Cited By ~ 1

Author(s):

Dafne Saporito ◽

Sergio A. Rodriguez ◽

Maria T. Baumgartner

Keyword(s):

Visible Light ◽

Bond Formation ◽

High Yield ◽

Reaction Yield ◽

Halogen Lamp ◽

One Pot ◽

Direct Arylation ◽

Photoinduced Reactions ◽

Optical Applications ◽

Very High

An eco-friendly and direct arylation of hydroxyaryls in water using photoinduced reactions with different substrates (1-bromo-2-naphthol, 1-iodo-2-naphthol, N-(2-iodophenyl)acetamide, 5-bromouracil, 2-iodo-N-methylbenzamide, and 2-iodobenzamide) was studied. For example, π-expanded coumarins, compounds with potential optical applications, were synthesized in very high yield, without the use of toxic reagents, in a one-pot reaction. In addition, we demonstrate that the irradiation source (halogen lamp) can be efficiently replaced by an LED without altering the reaction yield.

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