Highly Reactive Cyclic Carbonates with a Fused Ring toward Functionalizable and Recyclable Polycarbonates

2022 ◽  
pp. 173-178
Author(s):  
Wei Zhang ◽  
Jiang Dai ◽  
Yan-Chen Wu ◽  
Jia-Xuan Chen ◽  
Si-Yi Shan ◽  
...  
Keyword(s):  
Cyclic Carbonates ◽  
Fused Ring

scholarly journals Reactive molecular dynamics simulation of the high-temperature pyrolysis of 2,2′,2′′,4,4′,4′′,6,6′,6′′-nonanitro-1,1′:3′,1′′-terphenyl (NONA)

RSC Advances ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 5507-5515
Author(s):  
Liang Song ◽  
Feng-Qi Zhao ◽  
Si-Yu Xu ◽  
Xue-Hai Ju
Keyword(s):  
Molecular Dynamics ◽  
High Temperature ◽  
Molecular Dynamics Simulation ◽  
Molecular Dynamics Simulations ◽  
Dynamics Simulation ◽  
Reactive Molecular Dynamics ◽  
Ring Compounds ◽  
Fused Ring ◽  
Dynamics Simulations

The bimolecular and fused ring compounds are found in the high-temperature pyrolysis of NONA using ReaxFF molecular dynamics simulations.

High-Performance and Low-Energy Loss Organic Solar Cells with Non-fused Ring Acceptor by Alkyl Chain Engineering

2021 ◽  
pp. 129768
Author(s):  
Dou Luo ◽  
Xue Lai ◽  
Nan Zheng ◽  
Chenghao Duan ◽  
Zhaojin Wang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Energy Loss ◽  
Organic Solar Cells ◽  
High Performance ◽  
Alkyl Chain ◽  
Low Energy ◽  
Fused Ring

scholarly journals Highly Efficient MOF Catalyst Systems for CO2 Conversion to Bis-Cyclic Carbonates as Building Blocks for NIPHUs (Non-Isocyanate Polyhydroxyurethanes) Synthesis

Catalysts ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 628
Author(s):  
Adolfo Benedito ◽  
Eider Acarreta ◽  
Enrique Giménez
Keyword(s):  
Molar Mass ◽  
Cycloaddition Reaction ◽  
Building Blocks ◽  
Catalyst System ◽  
Cyclic Carbonate ◽  
Ammonium Bromide ◽  
Cyclic Carbonates ◽  
High Molar Mass ◽  
Highly Efficient ◽  
Free Process

The present paper describes a greener sustainable route toward the synthesis of NIPHUs. We report a highly efficient solvent-free process to produce [4,4′-bi(1,3-dioxolane)]-2,2′-dione (BDC), involving CO2, as renewable feedstock, and bis-epoxide (1,3-butadiendiepoxide) using only metal–organic frameworks (MOFs) as catalysts and cetyltrimethyl-ammonium bromide (CTAB) as a co-catalyst. This synthetic procedure is evaluated in the context of reducing global emissions of waste CO2 and converting CO2 into useful chemical feedstocks. The reaction was carried out in a pressurized reactor at pressures of 30 bars and controlled temperatures of around 120–130 °C. This study examines how reaction parameters such as catalyst used, temperature, or reaction time can influence the molar mass, yield, or reactivity of BDC. High BDC reactivity is essential for producing high molar mass linear non-isocyanate polyhydroxyurethane (NIPHU) via melt-phase polyaddition with aliphatic diamines. The optimized Al-OH-fumarate catalyst system described in this paper exhibited a 78% GC-MS conversion for the desired cyclic carbonates, in the absence of a solvent and a 50 wt % chemically fixed CO2. The cycloaddition reaction could also be carried out in the absence of CTAB, although lower cyclic carbonate yields were observed.

scholarly journals Enhancing photovoltaic performance via aggregation dynamics control in fused‐ring electron acceptor

Aggregate ◽  
2021 ◽  
Author(s):  
Jiayu Wang ◽  
Runyu Zhu ◽  
Shijie Wang ◽  
Yawen Li ◽  
Boyu Jia ◽  
...  
Keyword(s):  
Electron Acceptor ◽  
Photovoltaic Performance ◽  
Fused Ring

Insights into the Solubility of Carbon Dioxide in Grafted Mesoporous Silica for the Catalytic Synthesis of Cyclic Carbonates by Nanoconfinement

2021 ◽  
Author(s):  
Shahab Boroun ◽  
Abolfazl Alizadeh Sahraei ◽  
Abdol Hadi Mokarizadeh ◽  
Houshang Alamdari ◽  
Frédéric-Georges Fontaine ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Mesoporous Silica ◽  
Catalytic Synthesis ◽  
Cyclic Carbonates

Insights into the BPO 4 ‐Driven Catalytic Mechanism for the Formation of Cyclic Carbonates from CO 2 and Epoxides

2021 ◽  
Vol 6 (29) ◽  
pp. 7489-7498
Author(s):  
Anderson Gonzalez‐Vargas ◽  
Fernando Castro‐Gómez ◽  
Pedro J. Castro
Keyword(s):  
Catalytic Mechanism ◽  
Cyclic Carbonates

Highly efficient fused ring electron acceptors based on a new undecacyclic core

2021 ◽  
Author(s):  
Chun-Ru Wang ◽  
Fuwen Zhao ◽  
Dan He ◽  
Jingming Xin ◽  
Huotian Zhang ◽  
...  
Keyword(s):  
Extinction Coefficient ◽  
Energy Levels ◽  
Electron Acceptors ◽  
Highly Efficient ◽  
Fused Ring ◽  
Nanoscale Morphology

Two FREAs, IUIC-O and IUIC-T, based on an undecacyclic core were developed. IUIC-T having higher extinction coefficient, affords aligned energy levels with PBDB-T, finer nanoscale morphology and more orderly molecular...

scholarly journals Correction to “In Silico Analysis of the Electronic Delocalization in Some Double Fused-Ring Metallabenzenes”

ACS Omega ◽  
2021 ◽  
Author(s):  
David Arias-Olivares ◽  
Andrés Becerra-Buitrago ◽  
Luis Carlos García-Sánchez ◽  
Rafael Islas
Keyword(s):  
In Silico ◽  
In Silico Analysis ◽  
Electronic Delocalization ◽  
Fused Ring ◽  
Silico Analysis
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