Facile Strategy for Modulating the Nanoporous Structure of Ultrathin π-Conjugated Polymer Films for High-Performance Gas Sensors

ACS Sensors ◽  
2021 ◽  
Author(s):  
Vinh Van Tran ◽  
Gwanghoon Jeong ◽  
Keun Seong Kim ◽  
Jeongho Kim ◽  
Hong-Ryun Jung ◽  
...  
1998 ◽  
Vol 5 (3-4) ◽  
pp. 217-221 ◽  
Author(s):  
P. Altamura ◽  
A. Bearzotti ◽  
A. D'Amico ◽  
V. Foglietti ◽  
I. Fratoddi ◽  
...  

2018 ◽  
Vol 30 (20) ◽  
pp. 1705463 ◽  
Author(s):  
Dongyoon Khim ◽  
Alessandro Luzio ◽  
Giorgio Ernesto Bonacchini ◽  
Giuseppina Pace ◽  
Mi-Jung Lee ◽  
...  

2003 ◽  
Vol 771 ◽  
Author(s):  
M. Kemerink ◽  
S.F. Alvarado ◽  
P.M. Koenraad ◽  
R.A.J. Janssen ◽  
H.W.M. Salemink ◽  
...  

AbstractScanning-tunneling spectroscopy experiments have been performed on conjugated polymer films and have been compared to a three-dimensional numerical model for charge injection and transport. It is found that field enhancement near the tip apex leads to significant changes in the injected current, which can amount to more than an order of magnitude, and can even change the polarity of the dominant charge carrier. As a direct consequence, the single-particle band gap and band alignment of the organic material can be directly obtained from tip height-voltage (z-V) curves, provided that the tip has a sufficiently sharp apex.


2018 ◽  
Author(s):  
Nicholas Marshall

A set of experiments in surface-initiated ring-opening metathesis polymerization, including end-functionalization of growing brushes and contact angle/cyclic voltammetry measurements. We report preparation and CV of two different conjugated polymer films, and several endgroup and sidechain functionalization experiments using cross-metathesis and active ester substitution.<br>


Sensors ◽  
2021 ◽  
Vol 21 (3) ◽  
pp. 783 ◽  
Author(s):  
Andrea Gaiardo ◽  
David Novel ◽  
Elia Scattolo ◽  
Michele Crivellari ◽  
Antonino Picciotto ◽  
...  

The substrate plays a key role in chemoresistive gas sensors. It acts as mechanical support for the sensing material, hosts the heating element and, also, aids the sensing material in signal transduction. In recent years, a significant improvement in the substrate production process has been achieved, thanks to the advances in micro- and nanofabrication for micro-electro-mechanical system (MEMS) technologies. In addition, the use of innovative materials and smaller low-power consumption silicon microheaters led to the development of high-performance gas sensors. Various heater layouts were investigated to optimize the temperature distribution on the membrane, and a suspended membrane configuration was exploited to avoid heat loss by conduction through the silicon bulk. However, there is a lack of comprehensive studies focused on predictive models for the optimization of the thermal and mechanical properties of a microheater. In this work, three microheater layouts in three membrane sizes were developed using the microfabrication process. The performance of these devices was evaluated to predict their thermal and mechanical behaviors by using both experimental and theoretical approaches. Finally, a statistical method was employed to cross-correlate the thermal predictive model and the mechanical failure analysis, aiming at microheater design optimization for gas-sensing applications.


Nano Energy ◽  
2021 ◽  
Vol 86 ◽  
pp. 106055
Author(s):  
Yang Zhao ◽  
Manman Wu ◽  
Hongbin Chen ◽  
Jie Zhu ◽  
Jie Liu ◽  
...  

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