Insight into the Active Contribution of N-Coordinated Cobalt Phosphate Nanocrystals Coupled with Carbon Nanotubes for Oxygen Electrochemistry

2021 ◽  
Vol 9 (4) ◽  
pp. 1856-1866
Author(s):  
Lei Chen ◽  
Jin-Tao Ren ◽  
Zhong-Yong Yuan
2020 ◽  
Vol 534 ◽  
pp. 147635
Author(s):  
Shuang Tian ◽  
Yesheng Wang ◽  
Tonghui Cai ◽  
Dongqing Kong ◽  
Dandan Wang ◽  
...  

2014 ◽  
Vol 605 ◽  
pp. 75-78
Author(s):  
A. Ndiaye ◽  
J. Brunet ◽  
C. Varenne ◽  
P. Bonnet ◽  
A. Pauly ◽  
...  

With an objective to fabricate Carbon nanotubes (CNTs) based sensors, the solution route is investigated. The dispersion routes are chosen here to avoid the CNTs to form bundles which can reduce their surface area. The results show that SWNTs-based gas sensors made by the surfactant method is possible if the annealing temperature is correctly chosen. The use of a surfactant allows preparing sensing layers which present responses to NO2 exposure in the 50-200 ppb Range. In a second procedure the CNTs are noncovalently functionalized and used as sensing material for BTX (Benzene, Toluene and Xylenes) detection. The noncovalent functionalisation occurs through p-p stacking between the SWNTs framework and the highly delocalized π-system of the macrocycle which are phthalocyanines and porphyrines derivatives. The SWNTs materials are characterized by standard techniques (UV-Vis spectroscopy, TGA, TEM, Raman analysis). For BTX detection, we used a double transduction mode: IDEs (Interdigitated electrodes) and QCM (Quartz Crystal Microbalance) in order to get insight into the sensing mechanism.


1999 ◽  
Vol 593 ◽  
Author(s):  
D. Tekleab ◽  
R. Czerw ◽  
A. Rubio ◽  
P.M. Ajayan ◽  
D.L. Carroll

ABSTRACTWe report the use of high power ultrasonic agitation to create inelastic deformations in multiwalled carbon nanotubes. Using STM coupled with TEM we show that this damage can range from kinking to breaking of continuous tube walls into segments. Such deformed tubes provide an insight into the role of re-hybridization in the electrical and mechanical properties of tubes.


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