Modeling of a Two-Phase Electrochemical Reactor for the Fluorination of Organic Compounds. 2. Multiple Steady States

2001 ◽  
Vol 40 (14) ◽  
pp. 3117-3126 ◽  
Author(s):  
Javit A. Drake ◽  
Clayton J. Radke ◽  
John Newman
Keyword(s):  
Organic Compounds ◽  
Electrochemical Reactor ◽  
Steady States ◽  
Multiple Steady States ◽  
Two Phase

Multiple steady states in two-phase reactors under boiling conditions

2003 ◽  
Vol 58 (11) ◽  
pp. 2203-2214 ◽  
Author(s):  
R. Waschler ◽  
S. Pushpavanam ◽  
A. Kienle
Keyword(s):  
Steady States ◽  
Multiple Steady States ◽  
Two Phase

SYNTHESIS OF HYDROGEN IN ACOUSTOPLASMA DISCHARGE IN A LIQUID-PHASE STREAM

2019 ◽  
pp. 42-48 ◽  
Author(s):  
N. A. Bulychev
Keyword(s):  
Liquid Phase ◽  
Organic Compounds ◽  
Electrode Materials ◽  
Solid Phase ◽  
Plasma Discharge ◽  
Raw Material ◽  
Two Phase ◽  
Reduced Pressure ◽  
External Power Source ◽  
Phase Medium

In this paper, the plasma discharge in a high-pressure fluid stream in order to produce gaseous hydrogen was studied. Methods and equipment have been developed for the excitation of a plasma discharge in a stream of liquid medium. The fluid flow under excessive pressure is directed to a hydrodynamic emitter located at the reactor inlet where a supersonic two-phase vapor-liquid flow under reduced pressure is formed in the liquid due to the pressure drop and decrease in the flow enthalpy. Electrodes are located in the reactor where an electric field is created using an external power source (the strength of the field exceeds the breakdown threshold of this two-phase medium) leading to theinitiation of a low-temperature glow quasi-stationary plasma discharge.A theoretical estimation of the parameters of this type of discharge has been carried out. It is shown that the lowtemperature plasma initiated under the flow conditions of a liquid-phase medium in the discharge gap between the electrodes can effectively decompose the hydrogen-containing molecules of organic compounds in a liquid with the formation of gaseous products where the content of hydrogen is more than 90%. In the process simulation, theoretical calculations of the voltage and discharge current were also made which are in good agreement with the experimental data. The reaction unit used in the experiments was of a volume of 50 ml and reaction capacity appeared to be about 1.5 liters of hydrogen per minute when using a mixture of oxygen-containing organic compounds as a raw material. During their decomposition in plasma, solid-phase products are also formed in insignificant amounts: carbon nanoparticles and oxide nanoparticles of discharge electrode materials.

POVERTY TRAPS AND INFERIOR GOODS IN A DYNAMIC HECKSCHER–OHLIN MODEL

2012 ◽  
Vol 17 (6) ◽  
pp. 1227-1251 ◽  
Author(s):  
Eric W. Bond ◽  
Kazumichi Iwasa ◽  
Kazuo Nishimura
Keyword(s):  
Economic Theory ◽  
Steady State ◽  
World Economy ◽  
Steady States ◽  
The Other ◽  
Poverty Traps ◽  
Poverty Trap ◽  
Multiple Steady States ◽  
The World ◽  
State Capital

We extend the dynamic Heckscher–Ohlin model in Bond et al. [Economic Theory(48, 171–204, 2011)] and show that if the labor-intensive good is inferior, then there may exist multiple steady states in autarky and poverty traps can arise. Poverty traps for the world economy, in the form of Pareto-dominated steady states, are also shown to exist. We show that the opening of trade can have the effect of pulling the initially poorer country out of a poverty trap, with both countries having steady state capital stocks exceeding the autarky level. However, trade can also pull an initially richer country into a poverty trap. These possibilities are a sharp contrast with dynamic Heckscher–Ohlin models with normality in consumption, where the country with the larger (smaller) capital stock than the other will reach a steady state where the level of welfare is higher (lower) than in the autarkic steady state.

50 Multiple steady states in electrochemical reactors

1980 ◽  
Vol 35 (1-2) ◽  
pp. 396-404 ◽  
Author(s):  
George P. Sakellaropoulos ◽  
Brian G. Volintine
Keyword(s):  
Steady States ◽  
Multiple Steady States ◽  
Electrochemical Reactors

scholarly journals Intensification of Reactive Distillation for TAME Synthesis Based on the Analysis of Multiple Steady-State Conditions

Processes ◽  
2018 ◽  
Vol 6 (12) ◽  
pp. 241 ◽  
Author(s):  
Takehiro Yamaki ◽  
Keigo Matsuda ◽  
Duangkamol Na-Ranong ◽  
Hideyuki Matsumoto
Keyword(s):  
Liquid Flow ◽  
Reactive Distillation ◽  
Steady States ◽  
Vapor Flow ◽  
Multiple Steady States ◽  
Reflux Ratio ◽  
Flow Rates ◽  
Reaction Conversion ◽  
Reaction Performance ◽  
Separation Performances

Our previous study reported that operation in multiple steady states contributes to an improvement in reaction conversion, making it possible to reduce the energy consumption of the reactive distillation process for tert-amyl methyl ether (TAME) synthesis. This study clarified the factors responsible for an improvement in the reaction conversion for operation in the multiple steady states of the reactive distillation column used in TAME synthesis. The column profiles for those conditions, in which multiple steady states existed and those in which they did not exist, were compared. The vapor and liquid flow rates with the multiple steady states were larger than those when the multiple steady states did not exist. The effect of the duty of the intermediate condenser, which was introduced at the top of the reactive section, on the liquid flow rate for a reflux ratio of 1 was examined. The amount of TAME production increased from 55.2 to 72.1 kmol/h when the intermediate condenser was operated at 0 to −5 MW. Furthermore, the effect of the intermediate reboiler duty on the reaction performance was evaluated. The results revealed that the liquid and vapor flow rates influenced the reaction and separation performances, respectively.

The NO + CO reaction on clean Pt(lOO): Multiple steady states and oscillations

1988 ◽  
Vol 206 (1-2) ◽  
pp. 169-186 ◽  
Author(s):  
S.B. Schwartz ◽  
L.D. Schmidt
Keyword(s):  
Steady States ◽  
Multiple Steady States
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