Design of High Efficiency Chelate Fibers with an Amine Group To Remove Heavy Metal Ions and pH-Related FT-IR Analysis

2004 ◽  
Vol 43 (9) ◽  
pp. 2060-2066 ◽  
Author(s):  
Dong Hun Shin ◽  
Young Gun Ko ◽  
Ung Su Choi ◽  
Woo Nyon Kim
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
High Efficiency ◽  
Amine Group ◽  
Ft Ir ◽  
Ir Analysis

Separation of Heavy Metal Ions from Petroleum Ash Liquor Using Organic Resins and FT-IR Study of the Process

2020 ◽  
Vol 62 (2) ◽  
pp. 243-250
Author(s):  
A. M. Abd El-Hamid ◽  
M. A. Zahran ◽  
Y. M. Z. Ahmed ◽  
S. M. El-Sheikh
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Ft Ir ◽  
Ir Study

scholarly journals Facile fabrication of bimetallic Fe–Mg MOF for the synthesis of xanthenes and removal of heavy metal ions

RSC Advances ◽  
2020 ◽  
Vol 10 (16) ◽  
pp. 9693-9703 ◽  
Author(s):  
W. S. Abo El-Yazeed ◽  
Y. G. Abou El-Reash ◽  
L. A. Elatwy ◽  
Awad I. Ahmed
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Solvothermal Technique ◽  
Facile Fabrication ◽  
Ft Ir

This work reported the preparation of Mg-MOF, Fe-MOF and Fe–Mg MOF by a solvothermal technique and their characterization with FT-IR, XRD, SEM, EDS, TEM and SBET analyses.

Synthesis of graphene oxide/ polyvinyl alcohol (GO/PVA) composite film as an adsorbent

2021 ◽  
Vol 10 (3) ◽  
pp. xx-xx
Author(s):  
Thu Le Dieu ◽  
Hoang Tran Vinh
Keyword(s):  
Waste Water ◽  
Aqueous Solution ◽  
Heavy Metal ◽  
Metal Ions ◽  
Composite Film ◽  
Heavy Metal Ions ◽  
Precipitation Method ◽  
Initial Concentration ◽  
Ft Ir ◽  
Co Precipitation

In this study, heavy metal ions or organic in the aqueous solution are removed by adsorbent without filtration or centrifugation as well as incorporate magnetic materials into the adsorbent. A composite film GO/PVA from PVA and self – synthesized GO by co - precipitation method has synthesized successfully. This composite was characterized by XRD, SEM, FT-IR to evaluate the properties of this material. The results showed that there was an interaction between GO and PVA so we have tested the adsorption capacity of this composite with Co(II) ions and the obtained efficiency of this process was 99.5% with the initial concentration of solution is 20 mg.L-1. This film is completely capable of removing heavy metal ions from waste water.

Functionalized magnetic Fe3O4 nanoparticles for removal of heavy metal ions from aqueous solutions

e-Polymers ◽  
2016 ◽  
Vol 16 (4) ◽  
pp. 313-322 ◽  
Author(s):  
Dun Chen ◽  
Tunsagnl Awut ◽  
Bin Liu ◽  
Yali Ma ◽  
Tao Wang ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Heavy Metal ◽  
Metal Ions ◽  
Removal Efficiency ◽  
Heavy Metal Ions ◽  
X Ray Diffraction ◽  
Transmission Electron ◽  
Magnetic Adsorbents ◽  
Ft Ir ◽  
Magnetic Fe3o4 Nanoparticles

AbstractFe3O4 nanoparticles (MNP) were coated with 3-aminopropyltriethoxy-silane (APTES), resulting in anchoring of primary amine groups on the surface of the particles, then four kinds of novel magnetic adsorbents (Fe3O4@SiO2-NH-HCGs) were formed by grafting of different heterocyclic groups (HCG) on amino groups via substitution reaction. These Fe3O4@SiO2-NH-HCGs were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and energy disperse spectroscopy (EDS). The results confirmed the formation of Fe3O4@SiO2-NH-HCGs nanoparticles and the Fe3O4 core possessed superparamagnetism. Batch experiments were performed to evaluate adsorption conditions of Cu2+, Hg2+, Pb2+ and Cd2+. Under normal temperature and neutral condition, just 20 min, the removal efficiency of any Fe3O4@SiO2-NH-HCGs is more than 96%. In addition, these Fe3O4@SiO2-NH-HCGs have good stability and reusability. Their removal efficiency has no obvious decrease after being used seven times. After the experiments were finished, Fe3O4@SiO2-NH-HCGs were conveniently separated via an external magnetic field due to superparamagnetism. These results indicate that these Fe3O4@SiO2-NH-HCGs are potentially attractive materials for the removal of heavy metal ions from industrial wastewater.

scholarly journals Novel Mixed Matrix Membranes Based on Polymer of Intrinsic Microporosity PIM-1 Modified with Metal-Organic Frameworks for Removal of Heavy Metal Ions and Food Dyes by Nanofiltration

Membranes ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 14
Author(s):  
Anna Kuzminova ◽  
Mariia Dmitrenko ◽  
Andrey Zolotarev ◽  
Aleksandra Korniak ◽  
Daria Poloneeva ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
High Efficiency ◽  
Metal Organic Frameworks ◽  
Mixed Matrix Membranes ◽  
Polymer Of Intrinsic Microporosity ◽  
Food Dyes ◽  
Metal Organic ◽  
Intrinsic Microporosity

Nowadays, nanofiltration is widely used for water treatment due to its advantages, such as energy-saving, sustainability, high efficiency, and compact equipment. In the present work, novel nanofiltration membranes based on the polymer of intrinsic microporosity PIM-1 modified by metal-organic frameworks (MOFs)—MIL-140A and MIL-125—were developed to increase nanofiltration efficiency for the removal of heavy metal ions and dyes. The structural and physicochemical properties of the developed PIM-1 and PIM-1/MOFs membranes were studied by the spectroscopic technique (FTIR), microscopic methods (SEM and AFM), and contact angle measurement. Transport properties of the developed PIM-1 and PIM-1/MOFs membranes were evaluated in the nanofiltration of the model and real mixtures containing food dyes and heavy metal ions. It was found that the introduction of MOFs (MIL-140A and MIL-125) led to an increase in membrane permeability. It was demonstrated that the membranes could be used to remove and concentrate the food dyes and heavy metal ions from model and real mixtures.

Synthesis of Ethylenediaminetetraacetic Acid-Functionalized Chitosan Cryogels as Potential Sorbents of Heavy Metal Ions

2021 ◽  
Vol 58 (2) ◽  
pp. 155-166
Author(s):  
Maria Marinela Lazar ◽  
Ionel Adrian Dinu ◽  
Maria Valentina Dinu
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Ethylenediaminetetraacetic Acid ◽  
Tubular Structures ◽  
Retention Capacity ◽  
Ft Ir ◽  
Spectroscopy Optical ◽  
Porosity Measurements ◽  
Ft Ir Spectroscopy

An original functionalization strategy is proposed here to design chitosan (CS)-based cryogels with ethylenediaminetetraacetic acid (EDTA) moieties. Cryogels with aligned micro-sized tubular structures were further engineered through an unidirectional freezing approach. Attachment of EDTA groups onto CS chains was proved by 1H-RMN and FT-IR spectroscopy. The formation of EDTA-functionalized 3D porous CS-based cryogels was demonstrated by several methods of characterization (FTIR spectroscopy, optical microscopy, SEM, porosity measurements, swelling behavior, copper (II) retention capacity). The sorption tests pointed out the high potential of EDTA-functionalized CS-based cryogels for heavy metal ions retention.

Anion Ion Exchange Fiber Based on Polyacrylonitrile (PAN) Matrixes and Its Selective Adsorption for Heavy Metal Ions

2010 ◽  
Vol 129-131 ◽  
pp. 430-434 ◽  
Author(s):  
Huan Zhang ◽  
Jun Fu Wei ◽  
Hai Tao Wang ◽  
Li Juan Mu ◽  
Fan Lei Yan
Keyword(s):  
Heavy Metal ◽  
Ion Exchange ◽  
Metal Ions ◽  
Selective Adsorption ◽  
Adsorption Property ◽  
Pan Fiber ◽  
Ft Ir ◽  
Ir Analysis ◽  
Surface Modified ◽  
Ion Exchange Fiber

The purpose of this paper was to evaluate the capacity of anion ion exchange fiber to uptake the heavy metal(Co2+、Cu2+、Zn2+、Cd2+、Pb2+、Ag+) from the water. A new polyamine-type ion exchange fiber(IEF) based on polyacrylonitrile (PAN) with higher exchange capacities was prepared by crosslinking through hydrazine hydrate, followed reacting with diethylene triamine. FT-IR analysis indicated that amine, imido, acylamino and carboxyl groups were introduced into PAN fiber through the surface modified reaction of cross linking and amination. The structures of the IEF were characterized by means of SEM. The results showed that the surface of fiber became rougher and thicker and more heterogeneous. The static and dynamic adsorption experiments demonstrated the high selective adsorption property of the IEF for Ag+ and Cu2+. Furthermore, the adsorption mechanism for the metal ions with IEF was investigated with the FT-IR spectra studies.

In situ growth of monodispersed Fe3O4 nanoparticles on graphene for the removal of heavy metals and aromatic compounds

2013 ◽  
Vol 68 (11) ◽  
pp. 2351-2358 ◽  
Author(s):  
Hai-Xia Wu ◽  
Jia-Wei Wu ◽  
Zhi-Gang Niu ◽  
Xiu-Li Shang ◽  
Jun Jin
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Aromatic Compounds ◽  
Heavy Metal Ions ◽  
High Efficiency ◽  
Maximum Adsorption Capacity ◽  
X Ray Diffraction ◽  
Transmission Electron ◽  
Vis Spectroscopy ◽  
Removal Of Heavy Metals

We report on the efficient removal of heavy metal ions and aromatic compounds from simulated wastewater with a nanocomposite. The nanocomposite was obtained via thermal decomposition of the precursor Fe(acac)3 onto the surface of graphene, modified by diethylenetriamine pentaacetic anhydride through dopamine. It was found that the maximum adsorption capacity of the nanocomposite toward Cu2+ and naphthalene was 207.9 and 72.2 mg g−1 respectively, displaying a high efficiency for the removal of heavy metal ions as well as aromatic compounds at pH 7.0 and 293 K. The Langmuir for naphthalene and the Freundlich for the Cu2+ adsorption isotherms were applicable for describing the removal processes. Furthermore, the nanocomposite was carefully examined by transmission electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, Raman spectra, and UV-vis spectroscopy. This work provides a very efficient, fast and convenient approach to exploring a promising nanocomposite for water treatment.

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