Ozone Initiated Ni/Metal Oxide Catalyzed Conversion of 1,2-Dichlorobenzene to Mucochloric Acid in Aqueous Solutions

2012 ◽  
Vol 51 (7) ◽  
pp. 2864-2873 ◽  
Author(s):  
Estelle C. Chetty ◽  
S. Maddila ◽  
C. Southway ◽  
S. B. Jonnalagadda

1993 ◽  
Vol 89 (2) ◽  
pp. 267 ◽  
Author(s):  
Geoff. H. Kelsall ◽  
Yingyang Zhu ◽  
Hugh A. Spikes




2004 ◽  
Vol 6 (4) ◽  
pp. 227-231 ◽  
Author(s):  
E. Gkika ◽  
P. Kormali ◽  
S. Antonaraki ◽  
D. Dimoticali ◽  
E. Papaconstantinou ◽  
...  

Polyoxometallates (POM), i.e., metal oxide clusters of mainly tungsten are effective homogeneous photocatalysts for the mineralization of organic pollutants. POM are, at least, as effective as the well studiedTiO2.OH⋅radicals formed by the reaction of the photo-excited polyoxometallates withH2O, appear to play a key role in the process. In this study, the photocatalytic activity of POM have been tested on some diversified pesticides of interest such as lindane, bentazone and fenitrothion to determine the feasibility of decontamination of aqueous solutions from these pollutants. The results show that aqueous solutions containing the above pesticides, upon photolysis in the presence of polyoxotungstates undergo effective degradation toCO2,H2Oand the corresponding inorganic anions. The intermediates identified give rise to complicated degradation mechanisms prior to mineralization. The characteristic reactions that take place consist of hydroxylation, H-abstraction, dehalogenation, denitration, desulfurization, breaking of the C-C bond etc.



RSC Advances ◽  
2015 ◽  
Vol 5 (26) ◽  
pp. 20371-20375 ◽  
Author(s):  
H. Uchiyama ◽  
T. Ito ◽  
R. Sasaki ◽  
H. Kozuka

Transparent, crack-free SnO2 and TiO2 precursor films were obtained from organic-additive-free aqueous solutions by low-speed dip-coating. The precursor films were crystallized to SnO2 and TiO2 by the heat treatment at 700 °C for 10 min in air.



2020 ◽  
Vol 392 ◽  
pp. 123635 ◽  
Author(s):  
Khalid Z. Elwakeel ◽  
Ahmed Shahat ◽  
Ziya A. Khan ◽  
Wael Alshitari ◽  
Eric Guibal


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