scholarly journals Unprecedented Ultralow Detection Limit of Amines using a Thiadiazole-Functionalized Zr(IV)-Based Metal–Organic Framework

2019 ◽  
Vol 141 (18) ◽  
pp. 7245-7249 ◽  
Author(s):  
Arijit Mallick ◽  
Ahmed M. El-Zohry ◽  
Osama Shekhah ◽  
Jun Yin ◽  
Jiangtao Jia ◽  
...  
2021 ◽  
Vol 9 (36) ◽  
pp. 12086-12093
Author(s):  
Junjie Wang ◽  
Yao Cheng ◽  
Jie Zhou ◽  
Weihua Tang

Zn(ii)-based MOF for detecting FOX-7 like explosives is designed via hydrogen-bond-intensified host–guest interactions. The crystalline MOF achieves 0.14 ppm detection limit and a highest fluorescence quenching constant of 3.22 × 104 M−1.


RSC Advances ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 3705-3714 ◽  
Author(s):  
Muppidathi Marieeswaran ◽  
Perumal Panneerselvam

Here, we propose a magnetic nanoscale metal–organic framework as a novel quenching material and reveal its quenching–quenching mechanism. It sensitively and selectively binds Hg(ii) and a detection limit of 8 nM.


The Analyst ◽  
2019 ◽  
Vol 144 (9) ◽  
pp. 3111-3118 ◽  
Author(s):  
Marieeswaran Muppidathi ◽  
Panneerselvam Perumal ◽  
Ravikumar Ayyanu ◽  
Sivanesan Subramanian

In this work, we fabricated a metal–organic framework derived magnetic porous carbon (MPC) and with ssDNA achieved specific and efficient recognition of harmful arsenate ions. The detection limit was achieved at 630 pM.


2020 ◽  
Vol 8 (5) ◽  
pp. 1008-1016 ◽  
Author(s):  
Haihan Zou ◽  
Dongyan Tian ◽  
Chao Lv ◽  
Songmei Wu ◽  
Guanxuan Lu ◽  
...  

Co–Ni ultrathin metal organic framework nanosheets exhibited extremely high sensitivity, wide linear range, low detection limit and excellent selectivity as a glucose sensing electrode material.


RSC Advances ◽  
2016 ◽  
Vol 6 (91) ◽  
pp. 87945-87949 ◽  
Author(s):  
Xin-Lei Huang ◽  
Lin Liu ◽  
Ming-Liang Gao ◽  
Zheng-Bo Han

A luminescent metal–organic frameworkgea-MOF-1, can act as a fluorescent sensor for sensitive and selective detection of nitrobenzene and aniline. More importantly, the detection limit of nitrobenzene is on the 5–60 ppm scale.


2019 ◽  
Vol 43 (26) ◽  
pp. 10232-10236 ◽  
Author(s):  
Mengjie Huangfu ◽  
Xueqin Tian ◽  
Shuang Zhao ◽  
Pengyan Wu ◽  
Huacong Chu ◽  
...  

Post-synthetic modification of a MOF led to selectivity and sensitivity enhancement for Fe3+ detection in water with a detection limit of 70 nM.


Author(s):  
Pei-Pei Zhang ◽  
Bo Song ◽  
Zhongyi Li ◽  
Jian-Jun Zhang ◽  
Ai-Yun Ni ◽  
...  

Highly selective and sensitive, and low detection limit probes that can work in aqueous solution are of great significance for detection. Present here is a unique metal organic framework of...


BMC Chemistry ◽  
2021 ◽  
Vol 15 (1) ◽  
Author(s):  
Massoud Kaykhaii ◽  
Sayyed Hossein Hashemi ◽  
Fariba Andarz ◽  
Amin Piri ◽  
Ghasem Sargazi ◽  
...  

Abstract Background A chromium-based metal organic framework was synthesized and employed as an efficient sorbent for pipette tip micro-solid phase extraction and preconcentration of parabens from wastewater and shampoo samples up to sub-ppb level before their spectrophotometric analysis. Results Factors affecting preconcentration including volume and type of solvent, amount of sorbent, number of extraction, and volume and pH of samples were optimized employing one-variable-at-a-time and response surface methodology. Obtained analytical characteristics of the method proves its usefulness for analysis of real samples. Linear range of the method for parabens was 1.0–200.0 μg/L. Detection limit of the protocol was 0.24 µg/L for propyl paraben and 0.25 µg/L for methyl paraben. Reproducibility of the protocol defined as % RSD was better than 5.78%. Synthesized adsorbent can be re-used for at least 20 extractions. Conclusion The method showed a good detection limit and precision for determination of methyl- and propyl-paraben in wastewater and shampoo samples.


2017 ◽  
Vol 5 (36) ◽  
pp. 19378-19389 ◽  
Author(s):  
Yingpan Song ◽  
Fenghe Duan ◽  
Shuai Zhang ◽  
Jia-Yue Tian ◽  
Zhihong Zhang ◽  
...  

An Fe-MOF-derived Fe3O4@mC-based aptasensor was constructed to sensitively and selectivity detect trace oxytetracycline and a low detection limit was obtained.


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