scholarly journals Slow Electron Attachment as a Probe of Cluster Evaporation Processes

2011 ◽  
Vol 115 (25) ◽  
pp. 6961-6972 ◽  
Author(s):  
Roman Rabinovitch ◽  
Klavs Hansen ◽  
Vitaly V. Kresin
2021 ◽  
Vol 23 (7) ◽  
pp. 4317-4325
Author(s):  
Andriy Pysanenko ◽  
Kateryna Grygoryeva ◽  
Jaroslav Kočišek ◽  
Ragesh Kumar T. P. ◽  
Juraj Fedor ◽  
...  

Fragmentation of pyruvic acid upon slow electron attachment is investigated in relevance to its formation on ice grains in the interstellar medium.


1979 ◽  
Vol 40 (C7) ◽  
pp. C7-103-C7-104
Author(s):  
A. N. Vasilieva ◽  
I. A. Grishina ◽  
V. I. Ktitorov ◽  
A. S. Kovalev ◽  
A. T. Rakhimov

2020 ◽  
Author(s):  
Soumi Haldar ◽  
Achintya Kumar Dutta

We have presented a multi-layer implementation of the equation of motion coupled-cluster method for the electron affinity, based on local and pair natural orbitals. The method gives consistent accuracy for both localized and delocalized anionic states. It results in many fold speedup in computational timing as compared to the canonical and DLPNO based implementation of the EA-EOM-CCSD method. We have also developed an explicit fragment-based approach which can lead to even higher speed-up with little loss in accuracy. The multi-layer method can be used to treat the environmental effect of both bonded and non-bonded nature on the electron attachment process in large molecules.<br>


2019 ◽  
Vol 8 (4) ◽  
pp. 9487-9492

The outdoor insulator is commonly exposed to environmental pollution. The presence of water like raindrops and dew on the contaminant surface can lead to surface degradation due to leakage current. However, the physical process of this phenomenon is not well understood. Hence, in this study we develop a mathematical model of leakage current on the outdoor insulator surface using the Nernst Planck theory which accounts for the charge transport between the electrodes (negative and positive electrode) and charge generation mechanism. Meanwhile the electric field obeys Poisson’s equation. Method of Lines technique is used to solve the model numerically in which it converts the PDE into a system of ODEs by Finite Difference Approximations. The numerical simulation compares reasonably well with the experimental conduction current. The findings from the simulation shows that the conduction current is affected by the electric field distribution and charge concentration. The rise of the conduction current is due to the distribution of positive ion while the dominancy of electron attachment with neutral molecule and recombination with positive ions has caused a significant reduction of electron and increment of negative ions.


1988 ◽  
Author(s):  
H. Sambe ◽  
D. E. Ramaker
Keyword(s):  

1979 ◽  
Vol 44 (5) ◽  
pp. 1540-1551 ◽  
Author(s):  
Jaro Komenda ◽  
Jiří Huzlík

Compounds of the type of 2-(4'-nitrobenzoyl)methylene-3-ethylbenzothiazoline (I) and 2-bis-(p-nitrobenzoyl)methylene-3-ethylbenzothiazoline (II) were studied polarographically and by ESR spectroscopy to obtain informations about their electrochemical and follow-up reactions and their conformation. Whereas with compounds of the type I the conjugation in their molecules is preserved, with type II the coplanarity of the molecules is disturbed, which is manifested in the values of the splitting constants of the ESR spectra and a slow electron transfer between both nitrophenyl substituents. These conclusions are supported by NMR spectroscopic studies.


1977 ◽  
Vol 49 (2) ◽  
pp. 233-236 ◽  
Author(s):  
Karl Westberg
Keyword(s):  

2006 ◽  
Vol 110 (27) ◽  
pp. 8451-8456 ◽  
Author(s):  
Sylwia Ptasińska ◽  
Olof Echt ◽  
Stephan Denifl ◽  
Michal Stano ◽  
Philipp Sulzer ◽  
...  

Author(s):  
Pooja Verma ◽  
Debashree Ghosh ◽  
Achintya Kumar Dutta
Keyword(s):  

Sign in / Sign up

Export Citation Format

Share Document