A thiolate-bridged FeIVFeIV μ-nitrido complex and its hydrogenation reactivity toward ammonia formation

2021 ◽  
Author(s):  
Yixin Zhang ◽  
Jinfeng Zhao ◽  
Dawei Yang ◽  
Baomin Wang ◽  
Yuhan Zhou ◽  
...  
Keyword(s):  
RSC Advances ◽  
2021 ◽  
Vol 11 (29) ◽  
pp. 17891-17900
Author(s):  
Chien-I. Li ◽  
Hiroki Matsuo ◽  
Junichiro Otomo

Electrochemical promotion of ammonia formation is mainly governed by surface reaction with N2 and H2 in the cathode.


1954 ◽  
Vol 44 (3) ◽  
pp. 270-273 ◽  
Author(s):  
E. F. Annison ◽  
Margaret I. Chalmers ◽  
S. B. M. Marshall ◽  
R. L. M. Synge

1. Ruminal ammonia concentrations were measured in sheep receiving basal diets of hay and meals with various supplementary sources of protein. Ammonia production from groundnut meal was great and from maize products slight. Herring meal behaved in an intermediate way.2. The extent of ammonia production from a given amount of protein-rich material was decreased when the amount of starch or cereal meal fed at the same time was increased.


The Lancet ◽  
1965 ◽  
Vol 285 (7378) ◽  
pp. 195-198 ◽  
Author(s):  
J.E.A. Wickham ◽  
G.P. Sharma

1993 ◽  
Vol 15 (4) ◽  
pp. 141-146 ◽  
Author(s):  
J. S. Cosano ◽  
M. D. Luque de Castro ◽  
M. Valcárcel

This paper describes a simple flow-injection (FI) manifold for the determination of a variety of species in industrial water. The chemical systems involved in the determination of ammonia (formation of Indophenol Blue), sulfate (precipitation with Ba(II)), and iron (complexation with 1,10-phenanthroline with the help of a prior redox reaction for speciation) were selected so that a common manifold could be used for the sequential determination of batches of each analyte. A microcolumn of a suitable ion exchange material was used for on-line preconcentration of each analyte prior to injection; linear ranges for the determination of the analytes at the ng/ml levels were obtained with good reproducibility. The manifold and methods are ready for full automation.


2002 ◽  
Vol 124 (32) ◽  
pp. 9567-9573 ◽  
Author(s):  
Melissa Vettraino ◽  
Michel Trudeau ◽  
Andy Y. H. Lo ◽  
Robert W. Schurko ◽  
David Antonelli

2017 ◽  
Vol 114 ◽  
pp. 1986-1990 ◽  
Author(s):  
Kamonchanok Maneelam ◽  
Chintana Saiwan ◽  
Raphael Idem ◽  
Teeradet Supap
Keyword(s):  

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Ibrahim A. Amar ◽  
Mohammed M. Ahwidi

Purpose This paper aims to investigate the electrocatalytic activity of CoFe1.9Mo0.1O4-Ce0.8Gd0.18Ca0.02O2-δ composite (CFMo-CGDC) for the direct synthesis of ammonia from H2O and N2 under atmospheric pressure. Designs CoFe1.9Mo0.1O4 nanoparticles (CFMo NPs) were synthesized via a sol-gel method. CFMo NPs were characterized using X-ray diffraction (XRD), Brunauer–Emmet–Teller (BET) specific surface area measurement and scanning electron microscope (SEM). Double-chamber reactor was used to synthesize ammonia using H2O and N2 as precursors. The factors affecting the ammonia formation rate (applied voltage and temperature) were studied. Findings CoFe1.9Mo0.1O4 nanoparticles (CFMo NPs) were synthesized via a sol-gel method. CFMo NPs were characterized using XRD, Brunauer–Emmet–Teller (BET) specific surface area measurement and SEM. Double-chamber reactor was used to synthesize ammonia using H2O and N2 as precursors. The factors affecting the ammonia formation rate (applied voltage and temperature) were studied. Originality/value The usage of CFMo-CGDC composite as an electrocatalyst for the synthesis of ammonia directly from H2O and N2.


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