Electrocatalytic activity of CoFe1.9Mo0.1O4-Ce0.8Gd0.18Ca0.02O2-δ composite cathode for ammonia synthesis from water and nitrogen

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Ibrahim A. Amar ◽  
Mohammed M. Ahwidi
Keyword(s):  
Applied Voltage ◽  
Formation Rate ◽  
Sol Gel ◽  
Area Measurement ◽  
Content Type ◽  
Factors Affecting ◽  
Bet Specific Surface Area ◽  
Surface Area Measurement ◽  
Ammonia Formation ◽  
Double Chamber

Purpose This paper aims to investigate the electrocatalytic activity of CoFe1.9Mo0.1O4-Ce0.8Gd0.18Ca0.02O2-δ composite (CFMo-CGDC) for the direct synthesis of ammonia from H2O and N2 under atmospheric pressure. Designs CoFe1.9Mo0.1O4 nanoparticles (CFMo NPs) were synthesized via a sol-gel method. CFMo NPs were characterized using X-ray diffraction (XRD), Brunauer–Emmet–Teller (BET) specific surface area measurement and scanning electron microscope (SEM). Double-chamber reactor was used to synthesize ammonia using H2O and N2 as precursors. The factors affecting the ammonia formation rate (applied voltage and temperature) were studied. Findings CoFe1.9Mo0.1O4 nanoparticles (CFMo NPs) were synthesized via a sol-gel method. CFMo NPs were characterized using XRD, Brunauer–Emmet–Teller (BET) specific surface area measurement and SEM. Double-chamber reactor was used to synthesize ammonia using H2O and N2 as precursors. The factors affecting the ammonia formation rate (applied voltage and temperature) were studied. Originality/value The usage of CFMo-CGDC composite as an electrocatalyst for the synthesis of ammonia directly from H2O and N2.

scholarly journals Structuring of ZnTiO3/TiO2 Adsorbents for the Removal of Methylene Blue, Using Zeolite Precursor Clays as Natural Additives

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 898
Author(s):  
Ximena Jaramillo-Fierro ◽  
Silvia González ◽  
Fernando Montesdeoca-Mendoza ◽  
Francesc Medina
Keyword(s):  
Methylene Blue ◽  
Adsorption Process ◽  
Sol Gel ◽  
Area Measurement ◽  
X Ray Diffraction ◽  
Order Model ◽  
X Ray ◽  
Surface Area Measurement ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order

Adsorption is an effective method of removing harmful pollutants from air and water. In the present study, zeolites prepared by sol-gel method from two Ecuadorian clays were combined with precursor clays and the ZnTiO3/TiO2 semiconductor for adsorbing methylene blue (MB) as a water contaminant. The synthesized compounds were characterized using powder X-ray diffraction, X-ray fluorescence, scanning electron microscopy, energy dispersive X-ray, and surface area measurement. These compounds were combined to form cylindrical extrudates of 0.2 cm (diameter) and 1.0 cm (length). The adsorption characteristics of the composites were measured using batch sorption studies as a function of pH, initial concentration, and contact time. The pseudo-second-order model and the Langmuir isotherm model were better suited to the adsorption process. The equilibrium state was achieved around 180 min of adsorption, and a pH of 7 was established as the optimal operating condition. The maximum adsorption values of the dye were obtained with the composites derived from G-Clay, whose average adsorption capacity was 46.36 mg g−1, in contrast with composites derived from R-Clay, whose average adsorption value was 36.24 mg g−1. The results reflect that synthesized composites could be used potentially for the removal of cationic dye from wastewater.

Study on Preparation and Properties of Mesoporous Magnetic Silica

2011 ◽  
Vol 197-198 ◽  
pp. 269-272 ◽  
Author(s):  
Ya Ping Zhang ◽  
Han Sheng Li ◽  
Bin Zhen ◽  
Qin Wu ◽  
Chang Hao Liu
Keyword(s):  
Sol Gel ◽  
Area Measurement ◽  
Infrared Spectrometry ◽  
X Ray Diffraction ◽  
Bet Specific Surface Area ◽  
Sol Gel Process ◽  
Mesopore Structure ◽  
Magnetic Analysis ◽  
Thermal Technique ◽  
Adsorption Desorption

Magnetic materials are one of the promising material for their special magnetic properties and other functionalities. A sol-gel process in reverse microemulsion combined with solvent-thermal technique(ME-SG-ST) was developed for synthesizing nano-sized mesoporous SiO2/CoFe2O4(SCF). Fourier transform infrared spectrometry, TG-DSC, X-ray diffraction, TEM, BET specific surface area measurement, N2adsorption-desorption and magnetic analysis were used to characterize the structure and magnetism property. Results showed that spinel CoFe2O4was uniformly dispersed in nanosized SCF particles. The prepared SCF particles possessed mesopore structure and excellent paramagnetism, and will become great promising materials as the supports of catalyst and absorbents for biological and drugs.

Characterization of LiFePO4 Synthesized by Sol-Gel Processing

2007 ◽  
Vol 280-283 ◽  
pp. 453-456
Author(s):  
Jun Biao Lu ◽  
Zhong Tai Zhang ◽  
Zi Long Tang ◽  
Wan Ci Shen
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Sol Gel ◽  
Area Measurement ◽  
Capacity Fade ◽  
Sorption System ◽  
Surface Area Measurement ◽  
Gel Processing

LiFePO4 powder was obtained by sol-gel processing and was characterized by SEM, XRD, TEM, and surface area measurement of Quantachrome NOVA Automated Gas Sorption system. The cathode performance was evaluated using cylindrical battery. Cycle at C/10, samples sintered at 850°C with specific surface area of 188.5M2/g deliver capacity of 157.5mAh/g and cycle dozens of times without obvious capacity fade.

Sol-Gel Synthesis and Characterization of Ultrafine ZrSiO4 Powder

2014 ◽  
Vol 906 ◽  
pp. 66-71
Author(s):  
Zhen Quan Li ◽  
Qiang Zhen ◽  
Ya Li Wang
Keyword(s):  
Wavelength Range ◽  
High Purity ◽  
Raw Materials ◽  
Formation Rate ◽  
Sol Gel ◽  
Molar Ratio ◽  
Sem And Tem ◽  
Homogeneous Product ◽  
Sol Gel Synthesis ◽  
Calcined Temperature

High purity ZrSiO4 powder were synthesized using Si (C2H5O)4 and ZrOCl2·8H2O as raw materials by the sol-gel method, LiCl was added as mineralizer to promote crystallization of zircon. The influences of molar ratio of Zr:Si, calcined time and calcined temperature on the synthesis of ZrSiO4 powder were investigated. XRD, SEM and TEM were used to characterize the powders. It was found that when the molar ratio of Zr:Si was 1:1.2, the calcined temperature was 1600°C and the calcined time was 4h, the high purity ZrSiO4 ultrafine powder was obtained. The ZrSiO4 formation began at 1300°C and when the gel was calcined at 1600°Cfor 4 h, the formation rate of ZrSiO4 was up to 95%. SEM and TEM studies reveal a homogeneous product with particle sizes on the order of 0.1-1μm. The IR emissivity of ultrafine ZrSiO4 is 0.892 at the whole wavelength range, and that is up to 0.951 at the wavelength range of 8-14 μm.

scholarly journals Understanding employee turnover in humanitarian organizations

2016 ◽  
Vol 48 (4) ◽  
pp. 208-214 ◽  
Author(s):  
Rameshwar Dubey ◽  
Angappa Gunasekaran ◽  
Nezih Altay ◽  
Stephen J Childe ◽  
Thanos Papadopoulos
Keyword(s):  
Employee Turnover ◽  
Factor Loading ◽  
Personal Factors ◽  
Related Factors ◽  
Content Type ◽  
Factors Affecting ◽  
Work Related ◽  
Humanitarian Organizations ◽  
Using Data ◽  
High Level

Purpose – At a time when the number and seriousness of disasters seems to be increasing, humanitarian organizations find that besides their challenging work they are faced with problems caused by a high level of turnover of staff. The paper aims to discuss these issues. Design/methodology/approach – Based on the 24 variables leading to employee turnover identified by Cotton and Tuttle (1986) the authors analyse the work-related, external and personal factors affecting employee turnover in humanitarian organizations, using a survey of members of the Indian National Institute of Disaster Management. Findings – Results indicated that the three factors are present. Of the external factors, only employment perception had a factor loading over 0.7; of the work-related factors, all were significant; of the personal factors, biographical information, marital status, number of dependants, aptitude and ability and intelligence had the highest loadings. It was also shown that behavioural intentions and net expectation were not significant. Originality/value – Only a few studies reported on employee turnover and its reasons are not well understood in the context of humanitarian organizations. To address this need, the aim of this paper is to explore the personal reasons impacting employee turnover in humanitarian organizations. In the study the authors have adopted 24 variables used in Cotton and Tuttle (1986) and classified into constructs to explain turnover, and further tested the model using data gathered from humanitarian organizations.

scholarly journals Understanding consumer loyalty to technology-based self-services with credence qualities

2015 ◽  
Vol 29 (6/7) ◽  
pp. 522-532 ◽  
Author(s):  
Lisa Schuster ◽  
Judy Proudfoot ◽  
Judy Drennan
Keyword(s):  
Professional Services ◽  
Content Type ◽  
Consumer Responses ◽  
Factors Affecting ◽  
Behavioral Loyalty ◽  
Behavioral Domain ◽  
Continued Use ◽  
Self Service ◽  
The Impact ◽  
Goal Directed Behavior

Purpose – This paper aims to use the Model of Goal-Directed Behavior (MGB) to examine the factors affecting consumers’ continued use of emerging technology-based self-services (TBSSs) with credence qualities. Professional services, which traditionally require specialized knowledge and high levels of interpersonal interaction to produce owing to their credence qualities, are increasingly delivered via self-service technologies. Health services delivered via mobile devices, for example, facilitate self-care without direct involvement from health professionals. Design/methodology/approach – A mental health service delivered via the Internet and mobile phone, myCompass, was selected as the research context. Twenty interviews were conducted with users of myCompass and the data were thematically analyzed. Findings – The findings of the study showcase the unique determinants of consumers’ continued use of TBSSs with credence qualities relative to the more routine services which have been the focus of extant research. The findings further provide support for the utility of the MGB in explaining service continuance, although the importance of distinguishing between extrinsic and intrinsic motivational components of behavioral desire and capturing the impact of social influence beyond subjective norms is also highlighted. Originality/value – This study contributes to recent research examining differences in consumer responses across TBSSs and behavioral loyalty to these services. It also provides empirical evidence for broadening and deepening the MGB within this behavioral domain.

Quality of life in breast cancer sufferers

2016 ◽  
Vol 29 (7) ◽  
pp. 721-732 ◽  
Author(s):  
Ahmed Essmat Shouman ◽  
Nahla Fawzy Abou El Ezz ◽  
Nivine Gado ◽  
Amal Mahmoud Ibrahim Goda
Keyword(s):  
Breast Cancer ◽  
Quality Of Life ◽  
Family Income ◽  
Early Stage ◽  
Functional Domain ◽  
Related Factors ◽  
Specific Patient ◽  
Content Type ◽  
Factors Affecting

Purpose – The purpose of this paper is to measure health-related quality of life (QOL) among patients with early stage cancer breast under curative treatment at department of oncology and nuclear medicine at Ain Shams University Hospitals. Identify factors affecting QOL among these patients. Design/methodology/approach – A cross-sectional study measured QOL among early stage female breast cancer (BC) patients and determined the main factors affecting their QOL. Three interviewer administered questionnaires were used. Findings – The physical domain mostly affected in BC patients and the functional domain least. Socio-demographic factors that significantly affected BC patients QOL scores were patient age, education, having children and family income. Specific patient characteristics include caregiver presence – a factor that affected different QOL scores. Age at diagnosis, affection in the side of the predominant hand, post-operative chemotherapy and difficulty in obtaining the medication were the disease-related factors that affected QOL scores. Originality/value – The final model predicting QOL for early stage female BC patients included age, education and difficulty in obtaining the medication as determinants for total QOL score. Carer presence was the specific patient characteristic that affected different QOL scores.

Factors affecting coagulation: fibrinolysis in chronic subdural fluid collections

1983 ◽  
Vol 58 (2) ◽  
pp. 242-245 ◽  
Author(s):  
Bryce Weir ◽  
Philip Gordon
Keyword(s):  
Degradation Products ◽  
Hemoglobin Content ◽  
Fibrin Degradation Product ◽  
Content Type ◽  
Factors Affecting ◽  
Fibrin Degradation Products ◽  
Subdural Hematomas ◽  
Increased Risk ◽  
Fluid Collections ◽  
Fine Print

✓ Plasminogen, alpha2-antiplasmin, fibrinogen, fibrin degradation products (FDP's), and hemoglobin were measured in the supernatant fluid of 25 chronic subdural hematomas and five chronic subdural hygromas. The 30 patients underwent pre- and postoperative computerized tomography. The hematomas were characterized by low fibrinogen and high fibrin degradation product concentrations. The hemoglobin content varied directly with the alpha2-antiplasmin, and inversely with the plasminogen. Four patients underwent reoperation for recurrences. The initial fluid from these cases was characterized by relatively high plasminogen and low alpha2-antiplasmin. The hygromas had no hemoglobin, and low fibrinogen, high FDP's, low alpha2-antiplasmin, and variable plasminogen levels. It is possible that those cases having the greatest capacity to produce plasmin (high plasminogen and low alpha2-antiplasmin) can produce more FDP's which in turn causes more rebleeding and an increased risk of reaccumulation of chronic subdural hematomas.

Increasing revenue and attendance in Canadian Baptist churches

2015 ◽  
Vol 42 (12) ◽  
pp. 1071-1089
Author(s):  
Alan Chan ◽  
Bruce G. Fawcett ◽  
Shu-Kam Lee
Keyword(s):  
Church Health ◽  
Eastern Canada ◽  
Data Set ◽  
Content Type ◽  
Factors Affecting ◽  
Scarce Resources ◽  
Baptist Churches ◽  
And Performance ◽  
The Impact ◽  
Simulation Exercises

Purpose – Church giving and attendance are two important indicators of church health and performance. In the literature, they are usually understood to be simultaneously determined. The purpose of this paper is to estimate if there a sustainable church congregation size using Wintrobe’s (1998) dictatorship model. The authors want to examine the impact of youth and adult ministry as well. Design/methodology/approach – Using the data collected from among Canadian Baptist churches in Eastern Canada, this study investigates the factors affecting the level of the two indicators by the panel-instrumental variable technique. Applying Wintrobe’s (1998) political economy model on dictatorship, the equilibrium level of worship attendance and giving is predicted. Findings – Through various simulation exercises, the actual church congregation sizes is approximately 50 percent of the predicted value, implying inefficiency and misallocation of church resources. The paper concludes with insights on effective ways church leaders can allocate scarce resources to promote growth within churches. Originality/value – The authors are the only researchers getting the permission from the Atlantic Canada Baptist Convention to use their mega data set on church giving and congregation sizes as per the authors’ knowledge. The authors are also applying a theoretical model on dictatorship to religious/not for profits organizations.

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