scholarly journals Low cost, high performance ultrafiltration membranes from glass fiber-PTFE–graphene composites

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Umar Khan ◽  
Sonia Biccai ◽  
Conor S. Boland ◽  
Jonathan N. Coleman
Keyword(s):  
Flow Rate ◽  
Glass Fibre ◽  
High Performance ◽  
Graphene Nanosheets ◽  
Low Cost ◽  
Composite Membranes ◽  
Field Trials ◽  
Ultrafiltration Membranes ◽  
Alumina Membranes ◽  
Fibre Membrane

AbstractThe development of low-cost ultrafiltration membranes with relatively high flow rate and selectivity is an important goal which could improve access to clean water in the developing world. Here we demonstrate a method to infuse mixtures of graphene nanosheets and Teflon nanoparticles into ultra-cheap glass fibre membranes. Annealing the resultant composites leads to coalescence of the Teflon, resulting in very stable membranes with significantly enhanced mechanical properties. In filtration tests, while adding ~ 10 wt% graphene/Teflon to the glass fibre membrane decreased the flow rate by × 100, the selectivity improved by × 103 compared to the neat glass fibre membrane. This combination of selectively and flow rate was significantly better than any commercial membrane tested under similar circumstances. We found these membranes could remove > 99.99% of 25–250 nm diameter SiC nanoparticles dispersed in ethanol, transmitting only particles with diameters < 40 nm, performance which is superior to commercial alumina membranes. Field trials on dirty canal water showed these composite membranes to remove aluminium to a level × 10 below the EU limit for drinking water and reduce iron and bacteria contents to below detectable levels.

scholarly journals A low cost, superhydrophobic and superoleophilic hybrid kaolin-based hollow fibre membrane (KHFM) for efficient adsorption–separation of oil removal from water

RSC Advances ◽  
2018 ◽  
Vol 8 (6) ◽  
pp. 2986-2995 ◽  
Author(s):  
Siti Khadijah Hubadillah ◽  
Preven Kumar ◽  
Mohd Hafiz Dzarfan Othman ◽  
A. F. Ismail ◽  
Mukhlis A. Rahman ◽  
...  
Keyword(s):  
High Performance ◽  
Low Cost ◽  
Sol Gel ◽  
Hollow Fibre ◽  
Oil Removal ◽  
Hollow Fibre Membrane ◽  
Fibre Membrane

This paper outlines a low cost, high performance superhydrophobic/superoleophilic KHFM through a simple sol–gel grafted method using TEOS and MTES for efficient adsorption–separation of oil removal from water.

Performance Enhancements of Polysulfone Ultrafiltration Membranes through Blending with Functionalized Carbon Nanotubes and Polyaniline Nanofibers

2012 ◽  
Vol 217-219 ◽  
pp. 540-545 ◽  
Author(s):  
Yao Zu Liao ◽  
Xia Wang ◽  
Ying Li ◽  
Wei Qian ◽  
Xiao Yan Li ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Protein Separation ◽  
High Performance ◽  
Composite Membranes ◽  
Coagulation Bath ◽  
Ultrafiltration Membranes ◽  
Pani Nanofibers ◽  
Multi Walled Carbon Nanotubes ◽  
New Type ◽  
Walled Carbon Nanotubes

High-performance membranes for protein separation are of great interest. In this study, new type of polysulfone (PSf) composite ultrafiltration membranes are created by blending PSf with polyaniline (PANi) nanofibers and functionalized multi-walled carbon nanotubes (MWNTs) and then casting the mixture solutions via a well-developed non-solvent/solvent induced phase separation technique, using deionized water as the coagulation bath. The compositions, morphologies and properties of as-formed membranes are fully investigated. We demonstrate that membrane characteristics such as porosity, hydrophilicity, conductivity and thermal stability for PSf can be significantly enhanced with the incorporation of hydrophilic and conductive compositions of functionalized-MWNTs and PANi nanofibers. The composite membranes exhibit comparable bovine serum albumin (BSA) selectivities (89-93 vs. 92%) but much improved water fluxes (31.5-88.9 vs. 9.2 gfd/psi) against pure PSf membranes.

Iono-molecular Separation with Composite Membranes VI. Nitro-phenol separation through sulfonated polyether ether ketone on capillary polypropylene membranes

2018 ◽  
Vol 69 (7) ◽  
pp. 1603-1607
Author(s):  
Ion Spiridon Din ◽  
Anca Maria Cimbru ◽  
Abbas Abdul Kadhim Klaif Rikabi ◽  
Szidonia Katalin Tanczos ◽  
Simona Ticu (Cotorcea) ◽  
...  
Keyword(s):  
Flow Rate ◽  
Water Solubility ◽  
Composite Membranes ◽  
Membrane System ◽  
Polyether Ether Ketone ◽  
Molecular Separation ◽  
Capillary Membrane ◽  
Sulfonated Polyether Ether Ketone ◽  
Source Phase ◽  
Receptor Phase

The importance of removing and / or separating nitro phenols from aqueous solutions through membranes is substantiated by the multitude of recent research in the field, which broadly justifies both the economic and ecological reasons of such an approach. The present paper outlines the results of the transfer of nitro phenols through a membrane system made up of PPET impregnated polypropylene capillaries (PP) impregnated with sulfonate polyetheretherketone (SPEEK). The experiments were carried out in a PP-SPEEK capillary membrane module, with a useful size of 1 m2. Determinations made by using a 4 L / min flow rate source at a 5 mg / l nitrophenol concentration and pH 5 or pH 7, and the pH 12 receiving phase and a flow rate of 0.3 L / min, revealed that o- and p-nitrophenol were transferred much faster than m-nitrophenol (the flux is nearly double); the source phase of the system is concentrated in m-nitrophenol, and the receptor phase in o- and p-nitro phenols; the transfer data correlates with the higher water solubility of m-nitrophenol; mono nitro phenols transfer much faster than di nitrophenol, but both the mono and di nitrophenol streams decrease over time; after 4-5 hours of work, the mono nitrophenol concentration triples in the receiving phase, while the 2,4-dinitrophenol concentration doubles in the source phase.

Comparison of UV- and Derivative-Spectrophotometric and HPTLC UVDensitometric Methods for the Determination of Amrinone and Milrinone in Bulk Drugs

2020 ◽  
Vol 16 (3) ◽  
pp. 246-253
Author(s):  
Marcin Gackowski ◽  
Marcin Koba ◽  
Stefan Kruszewski
Keyword(s):  
Thin Layer ◽  
Thin Layer Chromatography ◽  
High Performance ◽  
Low Cost ◽  
Uv Spectra ◽  
Derivative Spectrophotometry ◽  
Therapeutic Monitoring ◽  
Bulk Drug ◽  
Layer Chromatography ◽  
Standard Solutions

Background: Spectrophotometry and thin layer chromatography have been commonly applied in pharmaceutical analysis for many years due to low cost, simplicity and short time of execution. Moreover, the latest modifications including automation of those methods have made them very effective and easy to perform, therefore, the new UV- and derivative spectrophotometry as well as high performance thin layer chromatography UV-densitometric (HPTLC) methods for the routine estimation of amrinone and milrinone in pharmaceutical formulation have been developed and compared in this work since European Pharmacopoeia 9.0 has yet incorporated in an analytical monograph a method for quantification of those compounds. Methods: For the first method the best conditions for quantification were achieved by measuring the lengths between two extrema (peak-to-peak amplitudes) 252 and 277 nm in UV spectra of standard solutions of amrinone and a signal at 288 nm of the first derivative spectra of standard solutions of milrinone. The linearity between D252-277 signal and concentration of amironone and 1D288 signal of milrinone in the same range of 5.0-25.0 μg ml/ml in DMSO:methanol (1:3 v/v) solutions presents the square correlation coefficient (r2) of 0,9997 and 0.9991, respectively. The second method was founded on HPTLC on silica plates, 1,4-dioxane:hexane (100:1.5) as a mobile phase and densitometric scanning at 252 nm for amrinone and at 271 nm for milrinone. Results: The assays were linear over the concentration range of 0,25-5.0 μg per spot (r2=0,9959) and 0,25-10.0 μg per spot (r2=0,9970) for amrinone and milrinone, respectively. The mean recoveries percentage were 99.81 and 100,34 for amrinone as well as 99,58 and 99.46 for milrinone, obtained with spectrophotometry and HPTLC, respectively. Conclusion: The comparison between two elaborated methods leads to the conclusion that UV and derivative spectrophotometry is more precise and gives better recovery, and that is why it should be applied for routine estimation of amrinone and milrinone in bulk drug, pharmaceutical forms and for therapeutic monitoring of the drug.

Optimum HPLC Conditions for Determination of Dibucaine HCL, Fluocortolone Pivalate and Fluocortolone Caproate by Using Experimental Design

2018 ◽  
Vol 15 (1) ◽  
pp. 32-38 ◽  
Author(s):  
Bürge Aşçı ◽  
Mesut Koç
Keyword(s):  
Experimental Design ◽  
Flow Rate ◽  
Mobile Phase ◽  
High Performance ◽  
Limit Of Detection ◽  
Pharmaceutical Preparations ◽  
Acid Mixture ◽  
Solution Stability ◽  
Uv Detector

Introduction:This paper presents the development and validation of a novel, fast, sensitive and accurate high performance liquid chromatography (HPLC) method for the simultaneous quantitative determination of dibucaine HCl, fluocortolone pivalate and fluocortolone caproate in pharmaceutical preparations.Experiment:Development of the chromatographic method was based on an experimental design approach. A five-level-three-factor central composite design requiring 20 experiments in this optimization study was performed in order to evaluate the effects of three independent variances including mobile phase ratio, flow rate and amount of acid in the mobile phase.Conclusion:The optimum composition for mobile phase was found as a methanol:water:acetic acid mixture at 71.6 : 26.4 : 2 (v/v/v) ratio and optimum separation was acquired by isocratic elution with a flow rate of 1.3 mL/min. The analytes were detected using a UV detector at 240 nm. The developed method was validated in terms of linearity, precision, accuracy, limit of detection/quantitation and solution stability and successfully applied to the determination of dibucaine HCl, fluocortolone pivalate and fluocortolone caproate in pharmaceutical topical formulations such as suppositories and ointments.

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