Energy transfer luminescence of Tb3+ ion complexed with calix[4]arenetetrasulfonate and the thia and sulfonyl analogue. The effect of bridging groupsElectronic supplementary information (ESI) available: emission spectra of Sm3+ and Dy3+ ions complexed with 2; emission spectra of Sm3+, Eu3+ and Dy3+ complexed with 3; continuous variation curves for the Tb3+ complexes with 2 and 3. See http://www.rsc.org/suppdata/p2/b0/b009151k/

2001 ◽  
pp. 2219-2225 ◽  
Author(s):  
Nobuhiko Iki ◽  
Takayuki Horiuchi ◽  
Hiromi Oka ◽  
Katsuyoshi Koyama ◽  
Naoya Morohashi ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Emission Spectra ◽  
Continuous Variation ◽  
Supplementary Information

scholarly journals Melt-Spun Photoluminescent Polymer Optical Fibers for Color-Tunable Textile Illumination

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1740
Author(s):  
Konrad Jakubowski ◽  
Manfred Heuberger ◽  
Rudolf Hufenus
Keyword(s):  
Energy Transfer ◽  
Optical Fibers ◽  
Color Space ◽  
Emission Spectra ◽  
Wide Range ◽  
Color Tunable ◽  
Melt Spun ◽  
Polymer Optical Fibers ◽  
Collective Emission ◽  
Down Conversion

The increasing interest in luminescent waveguides, applied as light concentrators, sensing elements, or decorative illuminating systems, is fostering efforts to further expand their functionality. Yarns and textiles based on a combination of distinct melt-spun polymer optical fibers (POFs), doped with individual luminescent dyes, can be beneficial for such applications since they enable easy tuning of the color of emitted light. Based on the energy transfer occurring between differently dyed filaments within a yarn or textile, the collective emission properties of such assemblies are adjustable over a wide range. The presented study demonstrates this effect using multicolor, meltspun, and photoluminescent POFs to measure their superimposed photoluminescent emission spectra. By varying the concentration of luminophores in yarn and fabric composition, the overall color of the resulting photoluminescent textiles can be tailored by the recapturing of light escaping from individual POFs. The ensuing color space is a mean to address the needs of specific applications, such as decorative elements and textile illumination by UV down-conversion.

scholarly journals Upconversion Luminescence of Silica–Calcia Nanoparticles Co-doped with Tm3+ and Yb3+ Ions

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 937
Author(s):  
Katarzyna Halubek-Gluchowska ◽  
Damian Szymański ◽  
Thi Ngoc Lam Tran ◽  
Maurizio Ferrari ◽  
Anna Lukowiak
Keyword(s):  
Energy Transfer ◽  
Near Infrared ◽  
Upconversion Luminescence ◽  
Sol Gel ◽  
Emission Spectra ◽  
Transmission Electron ◽  
Characteristic Emission ◽  
Diffraction Patterns ◽  
Size Of Particles ◽  
Average Size

Looking for upconverting biocompatible nanoparticles, we have prepared by the sol–gel method, silica–calcia glass nanopowders doped with different concentration of Tm3+ and Yb3+ ions (Tm3+ from 0.15 mol% up to 0.5 mol% and Yb3+ from 1 mol% up to 4 mol%) and characterized their structure, morphology, and optical properties. X-ray diffraction patterns indicated an amorphous phase of the silica-based glass with partial crystallization of samples with a higher content of lanthanides ions. Transmission electron microscopy images showed that the average size of particles decreased with increasing lanthanides content. The upconversion (UC) emission spectra and fluorescence lifetimes were registered under near infrared excitation (980 nm) at room temperature to study the energy transfer between Yb3+ and Tm3+ at various active ions concentrations. Characteristic emission bands of Tm3+ ions in the range of 350 nm to 850 nm were observed. To understand the mechanism of Yb3+–Tm3+ UC energy transfer in the SiO2–CaO powders, the kinetics of luminescence decays were studied.

Luminescence Linewidth Broadening and Nonradiative Energy Transfer Studies of Solid UO2+2-Datura

1992 ◽  
Vol 46 (9) ◽  
pp. 1376-1381 ◽  
Author(s):  
Huei-Yang D. Ke ◽  
Gary D. Rayson
Keyword(s):  
Energy Transfer ◽  
Emission Spectra ◽  
Blue Shift ◽  
Liquid Nitrogen Temperature ◽  
Peak Position ◽  
Nonradiative Energy Transfer ◽  
Wall Material ◽  
Transfer Model ◽  
Solution Ph ◽  
Linewidth Broadening

The emission spectra and fluorescence decay curves of solid UO2+2- Datura at liquid nitrogen temperature have been measured. The linewidth of the emission peaks of UO2+2 ions in UO2+2- Datura decreases with the UO2+2 concentration. This linewidth broadening phenomenon can be explained by the existence of resonance interactions between adjacent UO2+2- Datura species. The analysis of the emission peak position of the bound ions has been used to provide a measure of the electronic factors contributing to the interaction between the uranyl ion and phosphoryl and dicarboxyl moieties on the cell wall material. An observed blue shift of the uranyl fluorescence spectrum as a function of solution pH has been ascribed to a distortion of the normally linear O-U-O bond. An inter- and intra-molecular nonradiative energy transfer model has been successfully used to interpret the measured lifetime data of UO2+2- Datura.

Energy transfer in linear chain manganese salts: Emission spectra of CsMnBr3, RbMnBr3 and CsMnI3 crystals doped with Er3+

1984 ◽  
Vol 88 (2) ◽  
pp. 299-307 ◽  
Author(s):  
Katherine F. Talluto ◽  
Victor F. Trautmann ◽  
Gary L. McPherson
Keyword(s):  
Energy Transfer ◽  
Linear Chain ◽  
Emission Spectra ◽  
Manganese Salts

scholarly journals Процессы передачи энергии в эвлитите Sr-=SUB=-3-=/SUB=-Y(PO-=SUB=-4-=/SUB=-)-=SUB=-3-=/SUB=-, по отдельности и одновременно легированном ионами Tb-=SUP=-3+-=/SUP=- и Tm-=SUP=-3+-=/SUP=-

2022 ◽  
Vol 130 (1) ◽  
pp. 99
Author(s):  
Xiaowu Hu ◽  
Fabio Piccinelli ◽  
Marco Bettinelli
Keyword(s):  
Energy Transfer ◽  
Optical Spectroscopy ◽  
Emission Spectra ◽  
Cross Relaxation ◽  
Transfer Efficiency ◽  
Relaxation Processes ◽  
Donor Concentration ◽  
Acceptor Concentration ◽  
Transfer Processes ◽  
Double Phosphate

In this work the optical spectroscopy and the energy transfer processes involving the Tb3+and Tm3+ ions, have been studied in eulytite double phosphate hosts of the type Sr3Y(PO4)3 doped with various amounts of the two Ln ions. It has been found that several energy transfer and cross-relaxation processes are active in this class of materials, upon excitation in the 5D4 level of Tb, and in the 1G4 one of Tm. In particular, a Tb→Tm transfer of excitation has been found to quench strongly the 5D4 level of Tb. This process occurs with a transfer efficiency increasing from 0.08 to 0.62, for a donor concentration of 2 mol%, and an acceptor concentration increasing from 2 to 15 mol%. The emission spectra are strongly affected by the presence of Tb⟷Tm energy transfer, and Tm→Tm cross relaxation processes.

Synthesis and properties of diads based on tetra-aryl porphyrins and ruthenium bis-terpyridine-type complexes

2001 ◽  
Vol 05 (07) ◽  
pp. 600-607 ◽  
Author(s):  
ISABELLE M. DIXON ◽  
JEAN-PAUL COLLIN
Keyword(s):  
Energy Transfer ◽  
Excited State ◽  
Fluorescence Quenching ◽  
Emission Spectra ◽  
Spectroscopic Properties ◽  
Free Base ◽  
Strong Electron ◽  
Transfer Processes ◽  
C Complex

Four diads consisting of a free-base or zinc aryl-porphyrin associated with two ruthenium(II) bis(terdentate) complexes (non-cyclometallated Ru ( N 6) or cylometallated Ru ( N 5 C )) have been synthesized. The strong electron-withdrawing properties of the Ru ( N 6) as compared to the Ru ( N 5 C ) complex have been illustrated by their electrochemical and spectroscopic properties. Emission spectra of the diads and the reference compounds have shown that very efficient fluorescence quenching occurs, probably by energy transfer processes from the porphyrin to the 3MLCT excited state of the ruthenium unit.

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