Direct photolysis of the penta-1,3-dienes: recognition of wavelength-dependent behaviour in solution

1975 ◽  
pp. 932-933 ◽  
Author(s):  
Paul Vanderlinden ◽  
Stéphane Boué
Keyword(s):  
Direct Photolysis ◽  
Dependent Behaviour

Application of shotcrete constitutive model to the time dependent behavior of TBM tunnel lining

2018 ◽  
Vol 7 (3) ◽  
pp. 1826
Author(s):  
Heyam H. Shaalan ◽  
Mohd Ashraf Mohamad Ismail ◽  
Romziah Azit
Keyword(s):  
Constitutive Model ◽  
Steel Fibre ◽  
Tunnel Lining ◽  
Time Dependent ◽  
Elastic Behaviour ◽  
Elastic Analysis ◽  
Time Dependent Behaviour ◽  
Shotcrete Lining ◽  
Creep And Shrinkage ◽  
Dependent Behaviour

Shotcrete is ordinary concrete applied to the surface under high pressure. It demonstrates a highly time-dependent behaviour after few hours of application. Traditional approaches assume a simple linear elastic behaviour using a hypothetical young modulus to investigate the time-dependency and creep effects. In this paper, a new constitutive model of shotcrete is applied to evaluate the time-dependent behaviour of a TBM tunnel lining and investigate the parameters that can influence this behaviour. The Shotcrete model is based on the framework of Elasto-plasticity and designed to model shotcrete linings more realistically. The basic data of Pahang-Selangor Raw Water Transfer Project is used for the analysis study. An attempt is made to investigate the influence of some input parameters of the shotcrete model on the time-dependent behaviour of the shotcrete lining. These parameters include the time-dependent stiffness/strength parameters, creep and shrinkage parameters and steel fibre parameters. The variation in shotcrete strength classes causes a noticeable influence on the development of shotcrete compressive strength with time, particularly during the first days of application. The creep and shrinkage strain cause a considerable reduction in the development of the shotcrete stress with time. The impact of steel fibre content is determined, and the result indicated that the development of plain shotcrete stresses with time is lower than that of the reinforced shotcrete. In addition, a comparison study is performed to analyse the tunnel lining behaviour using both shotcrete model and an elastic analysis. Significant differences in shotcrete lining stresses are achieved when using the elastic analysis while the shotcrete model results in a reasonable result that can be used for the design requirements. 

scholarly journals UV/Vis-Based Persulphate Activation for p-Nitrophenol Degradation

Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 480
Author(s):  
Valentin Dubois ◽  
Carmen S. D. Rodrigues ◽  
Ana S. P. Alves ◽  
Luis M. Madeira
Keyword(s):  
Reaction Time ◽  
Oxidation Process ◽  
Activation Process ◽  
Direct Photolysis ◽  
Simulated Solar Light ◽  
Uv Visible ◽  
Oxidation Efficiency ◽  
Nitrophenol Degradation ◽  
Persulphate Oxidation ◽  
Radiation Type

In the present work, the degradation of p-nitrophenol (PNP) and its mineralization by a UV/Vis-based persulphate activation process was investigated. Firstly, a screening of processes as direct photolysis, persulphate alone and persulphate activated by radiation was performed. The incidence of radiation demonstrated to have an important role in the oxidant activation, allowing to achieve the highest PNP and total organic carbon (TOC) removals. The maximum PNP oxidation (100%) and mineralization (61.6%)—both after 2 h of reaction time—were reached when using T = 70 °C, (S2O82−) = 6.4 g/L and I = 500 W/m2. The influence of radiation type (ultraviolet/visible, visible or simulated solar light) was also evaluated, being found that the source with the highest emission of ultraviolet radiation (UV/visible) allowed to achieve the best oxidation efficiency; however, solar radiation also reached very-good performance. According to quenching experiments, the sulphate radical is key in the activated persulphate oxidation process, but the hydroxyl radical also plays an important role.

scholarly journals Application of micro-computer tomography and inverse finite element analysis for characterizing the visco-hyperelastic response of bulk liver tissue using indentation

2021 ◽  
Vol 3 (5) ◽  
Author(s):  
Rajeswara R. Resapu ◽  
Roger D. Bradshaw
Keyword(s):  
Finite Element ◽  
Liver Tissue ◽  
Loading Rate ◽  
Time Dependent ◽  
Nonlinear Material ◽  
Computational Time ◽  
List Type ◽  
Prony Series ◽  
Time Dependent Behaviour ◽  
Dependent Behaviour

Abstract In-vitro mechanical indentation experimentation is performed on bulk liver tissue of lamb to characterize its nonlinear material behaviour. The material response is characterized by a visco-hyperelastic material model by the use of 2-dimensional inverse finite element (FE) analysis. The time-dependent behaviour is characterized by the viscoelastic model represented by a 4-parameter Prony series, whereas the large deformations are modelled using the hyperelastic Neo-Hookean model. The shear response described by the initial and final shear moduli and the corresponding Prony series parameters are optimized using ANSYS with the Root Mean Square (RMS) error being the objective function. Optimized material properties are validated using experimental results obtained under different loading histories. To study the efficacy of a 2D model, a three dimensional (3D) model of the specimen is developed using Micro-CT of the specimen. The initial elastic modulus of the lamb liver obtained was found to 13.5 kPa for 5% indentation depth at a loading rate of 1 mm/sec for 1-cycle. These properties are able to predict the response at 8.33% depth and a loading rate of 5 mm/sec at multiple cycles with reasonable accuracy. Article highlights The visco-hyperelastic model accurately models the large displacement as well as the time-dependent behaviour of the bulk liver tissue. Mapped meshing of the 3D FE model saves computational time and captures localized displacement in an accurate manner. The 2D axisymmetric model while predicting the force response of the bulk tissue, cannot predict the localized deformations.

Photosensitization by Cd 3P1 atoms. I. Decomposition of acetone

1970 ◽  
Vol 48 (8) ◽  
pp. 1333-1334 ◽  
Author(s):  
B. L. Kalra ◽  
A. R. Knight
Keyword(s):  
Acetone Vapor ◽  
Direct Photolysis ◽  
Virtual Identity ◽  
Excited Species ◽  
Volatile Products ◽  
Acetone System

The photodecomposition of acetone vapor at 255 °C sensitized by Cd 3P1 atoms has been investigated. On irradiation of the Cd–acetone system at 3261 Å, both direct and sensitized reaction occur. CO and CH4 are the only significant volatile products, and their yield is decreased by addition of SF6 as inert quenching gas. The required participation of triplet acetone molecules in the sensitized reaction and the virtual identity of the direct and sensitized decompositions provide additional evidence for the importance of this excited species in direct photolysis.

scholarly journals Heart Rate Variability, Time Estimation and Internet-Dependent Behaviour in 16–17-Year-Old Adolescents: A Study in Russian Arctic

Life ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 497
Author(s):  
Olga Krivonogova ◽  
Elena Krivonogova ◽  
Liliya Poskotinova
Keyword(s):  
Heart Rate ◽  
Heart Rate Variability ◽  
Internet Addiction ◽  
Internet Use ◽  
Time Estimation ◽  
Vagal Activity ◽  
Russian Arctic ◽  
Severe Withdrawal ◽  
Dependent Behaviour ◽  
Nenets Autonomous

Internet-dependent behaviour in adolescents can contribute to a change in the function of the nervous system, which is reflected in the violation of time perception and autonomic regulation of the heart rate. The aim of the study was to determine groups of individuals with different risks of Internet addiction (IA) in relation to heart rate variability (HRV) parameters and the efficiency of time estimation in adolescents aged 16–17 years living in the Russian Arctic. Adolescents aged 16–17 years (n = 49–32 females, 17 males) living in Yamalo-Nenets Autonomous Okrug (Russia) were observed. Chen Scale Internet Addiction (CIAS) was used. The duration of an individual 1 min was determined. HRV parameters were determined using the "Varicard" equipment (Russia). In 16–17-year-old adolescents with different levels of risk of developing IA, including signs of IA, we revealed a high severity of symptoms of withdrawal from Internet use, difficulty in time estimation against the background of sympathicotonia and a decrease in vagal regulation of heart rate. In individuals with minimal symptoms of withdrawal from Internet use, the total HRV and vagal activity remain higher than in those with severe withdrawal symptoms, and their time estimation remains effective.

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