Graphene oxide grafted with Pd17Se15 nano-particles generated from a single source precursor as a recyclable and efficient catalyst for C–O coupling in O-arylation at room temperature

The Reaction of [HgCl2(tmeda)] with NaTeCH2CH2NMe2 gave a mercury tellurolate, [Hg(TeCH2CH2·NMe2)2] (1) as a yellow crystalline solid, which was characterized by elemental analysis, UV-vis, mass and NMR (1H, 13C, 125Te, 199Hg) spectroscopy. Thermolysis of 1 in hexadecylamine (HDA) at 90 °C in the absence and presence of Mn(OAc)2·4H2O gave undoped and Mn-doped HgTe nanoparticles which were characterized by XRD, EDAX, TEM, EPR and magnetic measurements. These particles could be synthesized with mean particle size of 6–7 nm (from TEM). Manganese substitution at Hg site in HgTe lead to a linear decrease in lattice parameter with increasing concentration of Mn. Magnetization measurements showed ferromagnetic ordering at room temperature with very small coercive field (Hc, 50 Oe) for Hg0.973Mn0.027 Te sample. This sample also exhibited distinct ferromagnetic resonance (FMR) in the EPR spectrum.

Download Full-text

Ultrafine cobalt nanoparticles supported on reduced graphene oxide: Efficient catalyst for fast reduction of hexavalent chromium at room temperature

Applied Surface Science ◽

10.1016/j.apsusc.2017.01.114 ◽

2017 ◽

Vol 402 ◽

pp. 294-300 ◽

Cited By ~ 30

Author(s):

Tingting Xu ◽

Jinjuan Xue ◽

Xiaolei Zhang ◽

Guangyu He ◽

Haiqun Chen

Keyword(s):

Graphene Oxide ◽

Reduced Graphene Oxide ◽

Hexavalent Chromium ◽

Room Temperature ◽

Cobalt Nanoparticles ◽

Efficient Catalyst ◽

Reduced Graphene

Download Full-text

Palladium nanoparticles decorated on reduced graphene oxide: An efficient catalyst for ligand- and copper-free Sonogashira reaction at room temperature

Applied Organometallic Chemistry ◽

10.1002/aoc.3679 ◽

2017 ◽

Vol 31 (8) ◽

pp. e3679 ◽

Cited By ~ 5

Author(s):

Abhijit Mahanta ◽

Najrul Hussain ◽

Manash R. Das ◽

Ashim J. Thakur ◽

Utpal Bora

Keyword(s):

Graphene Oxide ◽

Reduced Graphene Oxide ◽

Palladium Nanoparticles ◽

Room Temperature ◽

Sonogashira Reaction ◽

Efficient Catalyst ◽

Reduced Graphene

Download Full-text

Bimetallic single-source precursor for the synthesis of pure nanocrystalline room temperature-stabilized β-NiMoO 4

Ceramics International ◽

10.1016/j.ceramint.2015.09.076 ◽

2016 ◽

Vol 42 (1) ◽

pp. 1366-1372 ◽

Cited By ~ 3

Author(s):

Ahmed M. Moneeb ◽

Abdullah M. Alabdulrahman ◽

Abdulaziz A. Bagabas ◽

Cory K. Perkins ◽

Allen W. Apblett

Keyword(s):

Room Temperature ◽

Single Source ◽

Single Source Precursor

Download Full-text

A Facile Route for the Synthesis of Poly(N-vinylcarbazole)/Manganese Sulphide Quantum Dots Nanocomposites with Enhanced Optical Properties

Journal of Nanoscience and Nanotechnology ◽

10.1166/jnn.2008.485 ◽

2008 ◽

Vol 8 (11) ◽

pp. 6031-6037 ◽

Cited By ~ 2

Author(s):

Nosipho Moloto ◽

Suprakas Sinha Ray ◽

Makwena Justice Moloto

Keyword(s):

Quantum Dots ◽

Optical Properties ◽

Electron Microscope ◽

Elevated Temperature ◽

Room Temperature ◽

Single Source ◽

Precursor Method ◽

Tetramethylthiuram Disulfide ◽

Single Source Precursor ◽

Facile Route

This communication describes a facile route for the synthesis of manganese sulphide (MnS) quantum dots (QDs) contained in poly(N-vinyl carbazole) (PNVC) nanocomposites. MnS QDs were synthesized using the single-source precursor method by thermolysing tetramethylthiuram disulfide manganese complex in hexadecylamine (HDA). Two different methods were used for the synthesis of MnS QD incorporated PNVC nanocomposites. The first method entailed the stirring of a mixture of MnS QDs and PNVC in chloroform (CHCl3) at room temperature and the second method was the refluxing of MnS QDs and PNVC solution in CHCl3 at an elevated temperature. A field emission electron microscope (FESEM) study revealed that the dispersion of MnS QDs in a PNVC matrix was improved in the case of nanocomposites prepared by the second method. The optical properties of pure PNVC were significantly altered for the case of nanocomposite prepared by the second route.

Download Full-text

SiBCN-reduced graphene oxide (rGO) ceramic composites derived from single-source-precursor with enhanced and tunable microwave absorption performance

Carbon ◽

10.1016/j.carbon.2021.03.057 ◽

2021 ◽

Author(s):

Qingqing Chen ◽

Daxin Li ◽

Zhihua Yang ◽

Dechang Jia ◽

Yu Zhou ◽

...

Keyword(s):

Graphene Oxide ◽

Reduced Graphene Oxide ◽

Microwave Absorption ◽

Ceramic Composites ◽

Single Source ◽

Reduced Graphene ◽

Single Source Precursor ◽

Tunable Microwave ◽

Absorption Performance ◽

Microwave Absorption Performance

Download Full-text

Cu6Se4.5 Nanoparticles from a single source precursor: Recyclable and efficient catalyst for cross-dehydrogenative coupling of tertiary amines with terminal alkynes

Journal of Molecular Catalysis A Chemical ◽

10.1016/j.molcata.2016.06.005 ◽

2016 ◽

Vol 423 ◽

pp. 135-142 ◽

Cited By ~ 15

Author(s):

Sonu Gupta ◽

Hemant Joshi ◽

Nidhi Jain ◽

Ajai K. Singh

Keyword(s):

Terminal Alkynes ◽

Single Source ◽

Tertiary Amines ◽

Efficient Catalyst ◽

Dehydrogenative Coupling ◽

Single Source Precursor

Download Full-text

Fabrication of Prussian blue nanocubes through reducing a single-source precursor with graphene oxide and their electrocatalytic activity for H2O2

Journal of Nanoparticle Research ◽

10.1007/s11051-013-1806-z ◽

2013 ◽

Vol 15 (7) ◽

Cited By ~ 14

Author(s):

Lei Qian ◽

Run Zheng ◽

Lituo Zheng

Keyword(s):

Graphene Oxide ◽

Prussian Blue ◽

Electrocatalytic Activity ◽

Single Source ◽

Single Source Precursor

Download Full-text

Compositional Engineering of Metal-Xanthate Precursors toward (Bi1-xSbx)2S3 (0≤x≤0.05) Films with Enhanced Room-Temperature Thermoelectric Performance

Journal of Materials Chemistry C ◽

10.1039/d1tc04394c ◽

2022 ◽

Author(s):

Peng Gao ◽

Zhenyu Hu ◽

Longhui Deng ◽

Tingjun Wu ◽

Qikai Li ◽

...

Keyword(s):

Thin Films ◽

High Performance ◽

Room Temperature ◽

Thermoelectric Performance ◽

Single Source ◽

Bismuth Sulfide ◽

Single Source Precursor ◽

Metal Xanthate ◽

Thermoelectric Thin Films

The preparation of high-performance thermoelectric thin films can be challenging. Herein, we report the preparation, characterization, and thermoelectric performance of morphology-controlled bismuth sulfide (Bi2S3) thin films using a single-source precursor...

Download Full-text