scholarly journals Exceptional CO2capture in a hierarchically porous carbon with simultaneous high surface area and pore volume

2014 ◽  
Vol 7 (1) ◽  
pp. 335-342 ◽  
Author(s):  
Gadipelli Srinivas ◽  
Vaiva Krungleviciute ◽  
Zheng-Xiao Guo ◽  
Taner Yildirim
ACS Nano ◽  
2017 ◽  
Vol 11 (11) ◽  
pp. 11047-11055 ◽  
Author(s):  
Luis Estevez ◽  
Venkateshkumar Prabhakaran ◽  
Adam L. Garcia ◽  
Yongsoon Shin ◽  
Jinhui Tao ◽  
...  

RSC Advances ◽  
2014 ◽  
Vol 4 (18) ◽  
pp. 9126-9132 ◽  
Author(s):  
Wenzhong Shen ◽  
Tuoping Hu ◽  
Weibin Fan

Nanosheet porous carbon with high surface area and pore volume, unique compositional and structural features endow the nitrogen-doped porous carbon nanosheets with superior CO2 adsorption performance.


Nanomaterials ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 1220 ◽  
Author(s):  
Ranjith Thangavel ◽  
Aravindaraj G. Kannan ◽  
Rubha Ponraj ◽  
Karthikeyan Kaliyappan ◽  
Won-Sub Yoon ◽  
...  

Lithium–sulfur batteries are attractive candidates for next generation high energy applications, but more research works are needed to overcome their current challenges, namely: (a) the poor electronic conductivity of sulfur, and (b) the dissolution and migration of long-chain polysulfides. Inspired by eco-friendly and bio-derived materials, we synthesized highly porous carbon from cinnamon sticks. The bio-carbon had an ultra-high surface area and large pore volume, which serves the dual functions of making sulfur particles highly conductive and acting as a polysulfide reservoir. Sulfur was predominantly impregnated into pores of the carbon, and the inter-connected hierarchical pore structure facilitated a faster ionic transport. The strong carbon framework maintained structural integrity upon volume expansion, and the unoccupied pores served as polysulfide trapping sites, thereby retaining the polysulfide within the cathode and preventing sulfur loss. These mechanisms contributed to the superior performance of the lithium-sulfur cell, which delivered a discharge capacity of 1020 mAh g−1 at a 0.2C rate. Furthermore, the cell exhibited improved kinetics, with an excellent cycling stability for 150 cycles with a very low capacity decay of 0.10% per cycle. This strategy of combining all types of pores (micro, meso and macro) with a high pore volume and ultra-high surface area had a synergistic effect on improving the performance of the sulfur cathode.


2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Wan Nor Roslam Wan Isahak ◽  
Mohamed Wahab Mahamed Hisham ◽  
Mohd Ambar Yarmo

Porous carbon obtained by dehydrating agent, concentrated sulfuric acid (H2SO4), from biomass containing high cellulose (filter paper (FP), bamboo waste, and empty fruit bunches (EFB)) shows very high surface area and better thermal behavior. At room temperature (without heating), treatment of H2SO4removed all the water molecules in the biomass and left the porous carbon without emitting any gaseous byproducts. Brunauer-Emmett-Teller (BET) surface analysis has shown that bamboo-based carbon has good properties with higher surface area (507.8 m2/g), micropore area (393.3 m2/g), and better thermal behavior (compared to FP and EFB) without any activation or treatment process. By acid treatment of biomass, it was shown that higher carbon composition obtained from FP (85.30%), bamboo (77.72%), and EFB (76.55%) is compared to carbon from carbonization process. Under optimal sulfuric acid (20 wt.%) uses, high carbon yield has been achieved for FP (47.85 wt.%), bamboo (62.4 wt.%), and EFB (55.4 wt.%).


RSC Advances ◽  
2015 ◽  
Vol 5 (92) ◽  
pp. 75728-75734 ◽  
Author(s):  
Huishan Shang ◽  
Yanjie Lu ◽  
Feng Zhao ◽  
Cong Chao ◽  
Bing Zhang ◽  
...  

Peanut shells were transformed into porous carbon with a high surface area through a simple ZnCl2-molten salt synthesis process.


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