A novel iron complex for highly efficient catalytic hydrogen generation from the hydrolysis of organosilanes

2014 ◽  
Vol 50 (54) ◽  
pp. 7191-7194 ◽  
Author(s):  
Alan Kay Liang Teo ◽  
Wai Yip Fan

Hydrolytic oxidation of silanes to dihydrogen and silanols catalyzed by an iron-based catalyst.


RSC Advances ◽  
2014 ◽  
Vol 4 (71) ◽  
pp. 37645-37648 ◽  
Author(s):  
Alan Kay Liang Teo ◽  
Wai Yip Fan

Highly efficient silver nitrate mediated hydrogen generation from the hydrolysis of organosilanes.





2018 ◽  
Vol 5 (4) ◽  
pp. 760-772 ◽  
Author(s):  
Hongming Sun ◽  
Jing Meng ◽  
Lifang Jiao ◽  
Fangyi Cheng ◽  
Jun Chen

Efficient hydrogen generation and storage is an essential prerequisite of a future hydrogen economy.



Nanomaterials ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 1612
Author(s):  
Zhaoyu Wen ◽  
Qiong Fu ◽  
Jie Wu ◽  
Guangyin Fan

Simple and efficient synthesis of a nano-catalyst with an excellent catalytic property for hydrogen generation from hydrolysis of dimethyl amine-borane (DMAB) is a missing piece. Herein, effective and recycled palladium (Pd) nanoparticles (NPs) supported on soft nitriding porous carbon (NPC) are fabricated and applied for DMAB hydrolysis. It is discovered that the soft nitriding via a low-temperature urea-pretreatment induces abundant nitrogen-containing species on the NPC support, thus promoting the affinity of the Pd precursor and hindering the agglomeration of formed Pd NPs onto the NPC surface during the preparation process. Surface-clean Pd NPs with a diameter of sub-2.0 nm deposited on the NPC support (Pd/NPC) exhibit an outstanding catalytic performance with a turnover frequency (TOF) of 2758 h−1 toward DMAB hydrolysis, better than many previous reported Pd-based catalysts. It should be emphasized that the Pd/NPC also possesses a good stability without an obvious decrease in catalytic activity for DMAB hydrolysis in five successive recycling runs. This study provides a facile but efficient way for preparing high-performance Pd catalysts for catalytic hydrogen productions.



2016 ◽  
Vol 6 (7) ◽  
pp. 2112-2119 ◽  
Author(s):  
Jiankang Zhang ◽  
Chaoqiu Chen ◽  
Wenjun Yan ◽  
Feifei Duan ◽  
Bin Zhang ◽  
...  

Highly efficient Ni nanoparticles deposited on CNTs were synthesized by atomic layer deposition used for hydrogen generation from AB hydrolysis.





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